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1. Early Release Science of the exoplanet WASP-39b with JWST NIRSpec G395H

   https://doi.org/10.1038/s41586-022-05591-3  

   Alderson, Lili ; Wakeford, Hannah R ; Alam, Munazza K ; Batalha, Natasha E ; Lothringer, Joshua D ; Adams_Redai, Jea ; Barat, Saugata ; Brande, Jonathan ; Damiano, Mario ; Daylan, Tansu ; et al ( February 2023 , Nature)

   Measuring the abundances of carbon and oxygen in exoplanet atmospheres is considered a crucial avenue for unlocking the formation and evolution of exoplanetary systems^1,2. Access to the chemical inventory of an exoplanet requires high-precision observations, often inferred from individual molecular detections with low-resolution space-based^3–5and high-resolution ground-based^6–8facilities. Here we report the medium-resolution (R ≈ 600) transmission spectrum of an exoplanet atmosphere between 3 and 5 μm covering several absorption features for the Saturn-mass exoplanet WASP-39b (ref. ⁹), obtained with the Near Infrared Spectrograph (NIRSpec) G395H grating of JWST. Our observations achieve 1.46 times photon precision, providing an average transit depth uncertainty of 221 ppm per spectroscopic bin, and present minimal impacts from systematic effects. We detect significant absorption from CO₂(28.5σ) and H₂O (21.5σ), and identify SO₂as the source of absorption at 4.1 μm (4.8σ). Best-fit atmospheric models range between 3 and 10 times solar metallicity, with sub-solar to solar C/O ratios. These results, including the detection of SO₂, underscore the importance of characterizing the chemistry in exoplanet atmospheres and showcase NIRSpec G395H as an excellent mode for time-series observations over this critical wavelength range¹⁰.

    

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2. Photochemically produced SO2 in the atmosphere of WASP-39b

   https://doi.org/10.1038/s41586-023-05902-2  

   Tsai, Shang-Min ; Lee, Elspeth K. ; Powell, Diana ; Gao, Peter ; Zhang, Xi ; Moses, Julianne ; Hébrard, Eric ; Venot, Olivia ; Parmentier, Vivien ; Jordan, Sean ; et al ( May 2023 , Nature)

   Photochemistry is a fundamental process of planetary atmospheres that regulates the atmospheric composition and stability¹. However, no unambiguous photochemical products have been detected in exoplanet atmospheres so far. Recent observations from the JWST Transiting Exoplanet Community Early Release Science Program^2,3found a spectral absorption feature at 4.05 μm arising from sulfur dioxide (SO₂) in the atmosphere of WASP-39b. WASP-39b is a 1.27-Jupiter-radii, Saturn-mass (0.28 M_J) gas giant exoplanet orbiting a Sun-like star with an equilibrium temperature of around 1,100 K (ref. ⁴). The most plausible way of generating SO₂in such an atmosphere is through photochemical processes^5,6. Here we show that the SO₂distribution computed by a suite of photochemical models robustly explains the 4.05-μm spectral feature identified by JWST transmission observations⁷with NIRSpec PRISM (2.7σ)⁸and G395H (4.5σ)⁹. SO₂is produced by successive oxidation of sulfur radicals freed when hydrogen sulfide (H₂S) is destroyed. The sensitivity of the SO₂feature to the enrichment of the atmosphere by heavy elements (metallicity) suggests that it can be used as a tracer of atmospheric properties, with WASP-39b exhibiting an inferred metallicity of about 10× solar. We further point out that SO₂also shows observable features at ultraviolet and thermal infrared wavelengths not available from the existing observations.

    

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3. Identification of carbon dioxide in an exoplanet atmosphere

   https://doi.org/10.1038/s41586-022-05269-w  

   Ahrer, Eva-Maria ; Alderson, Lili ; Batalha, Natalie M ; Batalha, Natasha E ; Bean, Jacob L ; Beatty, Thomas G ; Bell, Taylor J ; Benneke, Björn ; Berta-Thompson, Zachory K ; Carter, Aarynn L ; et al ( February 2023 , Nature)

   Carbon dioxide (CO₂) is a key chemical species that is found in a wide range of planetary atmospheres. In the context of exoplanets, CO₂is an indicator of the metal enrichment (that is, elements heavier than helium, also called ‘metallicity’)^1–3, and thus the formation processes of the primary atmospheres of hot gas giants^4–6. It is also one of the most promising species to detect in the secondary atmospheres of terrestrial exoplanets^7–9. Previous photometric measurements of transiting planets with the Spitzer Space Telescope have given hints of the presence of CO₂, but have not yielded definitive detections owing to the lack of unambiguous spectroscopic identification^10–12. Here we present the detection of CO₂in the atmosphere of the gas giant exoplanet WASP-39b from transmission spectroscopy observations obtained with JWST as part of the Early Release Science programme^13,14. The data used in this study span 3.0–5.5 micrometres in wavelength and show a prominent CO₂absorption feature at 4.3 micrometres (26-sigma significance). The overall spectrum is well matched by one-dimensional, ten-times solar metallicity models that assume radiative–convective–thermochemical equilibrium and have moderate cloud opacity. These models predict that the atmosphere should have water, carbon monoxide and hydrogen sulfide in addition to CO₂, but little methane. Furthermore, we also tentatively detect a small absorption feature near 4.0 micrometres that is not reproduced by these models.

    

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4. Early Release Science of the exoplanet WASP-39b with JWST NIRCam

   https://doi.org/10.1038/s41586-022-05590-4  

   Ahrer, Eva-Maria ; Stevenson, Kevin B ; Mansfield, Megan ; Moran, Sarah E ; Brande, Jonathan ; Morello, Giuseppe ; Murray, Catriona A ; Nikolov, Nikolay K ; Petit_dit_de_la_Roche, Dominique_J M ; Schlawin, Everett ; et al ( February 2023 , Nature)

   Measuring the metallicity and carbon-to-oxygen (C/O) ratio in exoplanet atmospheres is a fundamental step towards constraining the dominant chemical processes at work and, if in equilibrium, revealing planet formation histories. Transmission spectroscopy (for example, refs.^1,2) provides the necessary means by constraining the abundances of oxygen- and carbon-bearing species; however, this requires broad wavelength coverage, moderate spectral resolution and high precision, which, together, are not achievable with previous observatories. Now that JWST has commenced science operations, we are able to observe exoplanets at previously uncharted wavelengths and spectral resolutions. Here we report time-series observations of the transiting exoplanet WASP-39b using JWST’s Near InfraRed Camera (NIRCam). The long-wavelength spectroscopic and short-wavelength photometric light curves span 2.0–4.0 micrometres, exhibit minimal systematics and reveal well defined molecular absorption features in the planet’s spectrum. Specifically, we detect gaseous water in the atmosphere and place an upper limit on the abundance of methane. The otherwise prominent carbon dioxide feature at 2.8 micrometres is largely masked by water. The best-fit chemical equilibrium models favour an atmospheric metallicity of 1–100-times solar (that is, an enrichment of elements heavier than helium relative to the Sun) and a substellar C/O ratio. The inferred high metallicity and low C/O ratio may indicate significant accretion of solid materials during planet formation (for example, refs.^3,4,) or disequilibrium processes in the upper atmosphere (for example, refs.^5,6).

    

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5. The JWST Early Release Science Program for Direct Observations of Exoplanetary Systems I: High-contrast Imaging of the Exoplanet HIP 65426 b from 2 to 16 μm

   https://doi.org/10.3847/2041-8213/acd93e  

   Carter, Aarynn L. ; Hinkley, Sasha ; Kammerer, Jens ; Skemer, Andrew ; Biller, Beth A. ; Leisenring, Jarron M. ; Millar-Blanchaer, Maxwell A. ; Petrus, Simon ; Stone, Jordan M. ; Ward-Duong, Kimberly ; et al ( July 2023 , The Astrophysical Journal Letters)

   We present JWST Early Release Science coronagraphic observations of the super-Jupiter exoplanet, HIP 65426b, with the Near-Infrared Camera (NIRCam) from 2 to 5μm, and with the Mid-Infrared Instrument (MIRI) from 11 to 16μm. At a separation of ∼0.″82 (87${}_{-31}^{+108}$au), HIP 65426b is clearly detected in all seven of our observational filters, representing the first images of an exoplanet to be obtained by JWST, and the first-ever direct detection of an exoplanet beyond 5μm. These observations demonstrate that JWST is exceeding its nominal predicted performance by up to a factor of 10, depending on separation and subtraction method, with measured 5σcontrast limits of ∼1 × 10⁻⁵and ∼2 × 10⁻⁴at 1″ for NIRCam at 4.4μm and MIRI at 11.3μm, respectively. These contrast limits provide sensitivity to sub-Jupiter companions with masses as low as 0.3M_Jupbeyond separations of ∼100 au. Together with existing ground-based near-infrared data, the JWST photometry are fit well by aBT-SETTLatmospheric model from 1 to 16μm, and they span ∼97% of HIP 65426b's luminous range. Independent of the choice of model atmosphere, we measure an empirical bolometric luminosity that is tightly constrained between$\log \left(L_{\mathrm{bol}}/L_{\odot }\right)$= −4.31 and −4.14, which in turn provides a robust mass constraint of 7.1 ± 1.2M_Jup. In totality, these observations confirm that JWST presents a powerful and exciting opportunity to characterize the population of exoplanets amenable to high-contrast imaging in greater detail.

    

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