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1. Age of Skarn Formation and Meteoric Water Infiltration in the Willsboro–Lewis Wollastonite District (Adirondack Highlands, New York)

   https://doi.org/10.1093/petrology/egaf024  

   Peck, William H; Regan, Sean P; Blum, Tyler B; Valley, John W; Timothy, Samuel C (April 2025, Journal of Petrology)

   Abstract The Willsboro–Lewis wollastonite district occurs along the margin of the 1.15-Ga Marcy anorthosite massif in the Adirondack Highlands (New York) and records mineralogical and isotopic evidence for formation in the anorthosite’s low-pressure metamorphic contact aureole. Wollastonite–garnet–pyroxene gneisses in the ~25-km-long, 1.5-km-thick skarn belt are mined for wollastonite and are intercalated with massive garnetite and pyroxene ± garnet skarns, all of which have low oxygen isotope ratios indicating circulation of heated meteoric water and relatively shallow depths above the brittle–ductile transition during their formation. Anorthosite, skarns, and country rocks were all variably deformed and recrystallized at depths of 25 to 30 km during the 1.09- to 1.02-Ga Ottawan phase, and locally altered during the 1.01- to 0.98-Ga Rigolet phase, of the Grenvillian orogeny. This study examined rare zircon in low-δ18O skarn rocks to constrain the timing of surface-derived meteoric water infiltration. Zircon was dated, and trace elements were measured by laser-ablation ICPMS, and oxygen isotopes were measured by ion microprobe, yielding a spectrum of ages and oxygen isotope ratios reflecting the polymetamorphic history of these rocks. Most samples are dominated by metamorphic zircon having Ottawan or Rigolet 207Pb/206Pb ages and are in high-temperature oxygen isotopic equilibrium with host wollastonite, garnet and/or pyroxene. Several samples contain igneous zircon with disturbed U–Pb isotope systematics, reflecting some combination of new zircon growth and recrystallization during subsequent metamorphism. Relict 1150–1140 Ma ages are preserved in some zircon cores, which are taken as the ages of igneous zircon incorporated during skarn formation or from protoliths. Some of these 1150 to 1140 Ma cores preserve the low-δ18O record of interaction with meteoric water. Ages seen in the Willsboro–Lewis skarns reproduce the span of igneous, disturbed and metamorphic ages in Adirondack anorthosite, and point to contemporaneous anorthosite emplacement, meteoric water circulation and skarn formation at ca. 1150 Ma. This result is consistent with shallow emplacement of the Marcy anorthosite massif during crustal thinning related to the collapse of the 1.19- to 1.14-Ga Shawinigan orogeny, and that granulite facies overprinting was a later tectonic event. 

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2. Understanding Oxygen Isotopes in Cordilleran Batholiths: A 190 Million Year, Top-to-Bottom Perspective from the Sierra Nevada

   Lackey, Jade_Star (September 2023, 10th Hutton Symposium on Granites and Related Rocks)

   Nearly two decades since the first oxygen isotope (δ18O) studies of zircon in the Sierra Nevada Batholith, California, USA, a far more extensive picture of spatial and temporal patterns of magmatic δ18O has emerged in parallel with a tenfold increase in geochronologic coverage, and many new radiogenic isotope (Sr, Nd, Hf) analyses. Over this time, models of Cordilleran-type arc systems have sought to elucidate flare-ups of magmatism as cyclic, with radiogenic isotope “excursions” tracing variable input of crust and mantle into arc magmas [e.g., 1]. Such models haven't incorporated oxygen isotopes to full advantage because of apparent complexity in the signals they record [2]. New, single zircon δ18O analyses—of plutonic, volcanic, and detrital zircon—from the Sierra amplifiing the findings of previous studies [e.g., 3], that δ18O records are well-suited for detecting relatively fast (<10 million year) recycling of subducted supracrustal rock and accreted terranes in forearc settings. Such recycling is not resolved by radiogenic isotope systems. A wealth of new volcanic δ18O zircon data from the Sierra, along with δ18O of hydrothermal minerals like skarn garnet, also records periods of significant δ18O “pull-downs” as lower-δ18O hydrothermal waters alter surface rocks whose assimilation subsequently embeds these surface signals in silicic volcanic systems. Such re-melting and volcanic episodes are often brief (< 5 million years) and small volume, so have often been overlooked, however such, δ18O values may be key to detecting plutonic from volcanic zircon in detrital records when used in conjunction with trace elements. Low-δ18O domains are becoming recognized in other arcs and to be useful to detect episodic resampling of crustal domains [4]. Morover, discovery of fossil low-δ18O systems in screens of wallrock in mid-crustal levels [e.g., 5] documents wholesale rapid burial of these domains in arcs, during transitions to episodes of shortening or transpression. All together, zircon δ18O uniquely traces surface- to-source transport and recycling in Cordilleran arcs as it relates to changing arc stress regime, at periods that may fail to be recorded in excursions of radiogenic isotopes, such as relaxation of stress regimes in upper plate domains. [1] DeCelles, P. G. et al. Nature Geoscience 2, 251-257 (2009) ; [2] Chapman, J. B. et al. Lithos 398- 299, (2021); [3] Lackey, J. S., et. al. J. Petrology 49, 1397–1426 (2008); [4] Turnbull, R. E. et al. Gondwana Res. 121, 436-471; [5] Ryan-Davis, J. et al. Contributions to Min. and Pet 174, 19 (2019) 

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3. Triple Oxygen (δ18O, Δ17O), Hydrogen (δ2H), and Iron (δ56Fe) Stable Isotope Signatures Indicate a Silicate Magma Source and Magmatic-Hydrothermal Genesis for Magnetite Orebodies at El Laco, Chile

   https://doi.org/10.5382/econgeo.4760  

   Childress, T. (November 2020, Economic geology)

   null (Ed.)

   The Plio-Pleistocene El Laco iron oxide-apatite (IOA) orebodies in northern Chile are some of the most enigmatic mineral deposits on Earth, interpreted to have formed as lava flows or by hydrothermal replacement, two radically different processes. Field observations provide some support for both processes, but ultimately fail to explain all observations. Previously proposed genetic models based on observations and study of outcrop samples include (1) magnetite crystallization from an erupting immiscible Fe- and P-rich (Si-poor) melt and (2) metasomatic replacement of andesitic lava flows by a hypogene hydrothermal fluid. A more recent investigation of outcrop and drill core samples at El Laco generated data that were used to develop a new genetic model that invokes shallow emplacement and surface venting of a magnetite-bearing magmatic-hydrothermal fluid suspension. This fluid, with rheological properties similar to basaltic lava, would have been mobilized by decompression- induced collapse of the volcanic edifice. In this study, we report oxygen, including 17O, hydrogen, and iron stable isotope ratios in magnetite and bulk iron oxide (magnetite with minor secondary hematite and minor goethite) from five of seven orebodies around the El Laco volcano, excluding San Vicente Bajo and the minor Laquito deposits. Calculated values of δ18O, Δ17O, δD, and δ56Fe fingerprint the source of the ore-forming fluid(s): Δ17Osample = δ17Osample – δ18Osample * 0.5305. Magnetite and bulk iron oxide (magnetite variably altered to goethite and hematite) from Laco Sur, Cristales Grandes, and San Vicente Alto yield δ18O values that range from 4.3 to 4.5‰ (n = 5), 3.0 to 3.9‰ (n = 5), and –8.5 to –0.5‰ (n = 5), respectively. Magnetite samples from Rodados Negros are the least altered samples and were also analyzed for 17O as well as conventional 16O and 18O, yielding calculated δ18O values that range from 2.6 to 3.8‰ (n = 9) and Δ17O values that range from –0.13 to –0.07‰ (n = 5). Bulk iron oxide from Laco Norte yielded δ18O values that range from –10.2 to +4.5‰ (avg = 0.8‰, n = 18). The δ2H values of magnetite and bulk iron oxide from all five orebodies range from –192.8 to –79.9‰ (n = 28); hydrogen is present in fluid inclusions in magnetite and iron oxide, and in minor goethite. Values of δ56Fe for magnetite and bulk iron oxide from all five orebodies range from 0.04 to 0.70‰ (avg = 0.29‰, σ = 0.15‰, n = 26). The iron and oxygen isotope data are consistent with a silicate magma source for iron and oxygen in magnetite from all sampled El Laco orebodies. Oxygen (δ18O Δ +4.4 to –10.2‰) and hydrogen (δ 2H ≃ –79.9 to –192.8‰) stable isotope data for bulk iron oxide samples that contain minor goethite from Laco Norte and San Vicente Alto reveal that magnetite has been variably altered to meteoric values, consistent with goethite in equilibrium with local δ18O and δ2H meteoric values of ≃ –15.4 and –211‰, respectively. The H2O contents of iron oxide samples from Laco Norte and San Vicente Alto systematically increase with increasing abundance of goethite and decreasing values of δ18O and δ2H. The values of δ2H (≃ –88 to –140‰) and δ18O (3.0–4.5‰) for magnetite samples from Cristales Grandes, Laco Sur, and Rodados Negros are consistent with growth of magnetite from a degassing silicate melt and/or a boiling magmatic-hydrothermal fluid; the latter is also consistent with δ18O values for quartz, and salinities and homogenization temperatures for fluid inclusions trapped in apatite and clinopyroxene coeval with magnetite. The sum of the data unequivocally fingerprint a silicate magma as the source of the ore fluids responsible for mineralization at El Laco and are consistent with a model that explains mineralization as the synergistic result of common magmatic and magmatic-hydrothermal processes during the evolution of a caldera-related explosive volcanic system. 

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4. Origin of Au-Rich Carbonate-Hosted Replacement Deposits of the Kassandra Mining District, Northern Greece: Evidence for Late Oligocene, Structurally Controlled, and Zoned Hydrothermal Systems

   https://doi.org/10.5382/econgeo.4664  

   Siron, Chris R.; Thompson, John F.H.; Baker, Tim; Darling, Robert; Dipple, Gregory (November 2019, Economic Geology)

   Abstract The Au-rich polymetallic massive sulfide orebodies of the Kassandra mining district belong to the intrusion-related carbonate-hosted replacement deposit class. Marble lenses contained within the Stratoni fault zone host the Madem Lakkos and Mavres Petres deposits at the eastern end of the fault system, where paragenetically early skarn and massive sulfide are spatially associated with late Oligocene aplitic and porphyritic dikes. Skarn transitions into predominant massive and banded replacement sulfide bodies, which are overprinted by a younger assemblage of boulangerite-bearing, quartz-rich sulfide and late quartz-rhodochrosite vein breccias. The latter style of mineralization is most abundant at the Piavitsa prospect at the western end of the exposed fault system. The sulfide orebodies at the Olympias deposit are hosted by marble in association with the Kassandra fault, where textural and mineralogical similarities to the sulfide bodies within the Stratoni fault zone suggest a genetic relationship. Estimated trapping temperatures and pressures based on fluid inclusion data indicate that carbonate replacement mineralization took place at depths less than about 5.9 km. Carbon and oxygen isotope patterns in carbonate from the Stratoni fault zone support isotopic exchange principally through fluid–wall-rock interaction, whereas decarbonation and fluid-rock exchange reactions were important at the Olympias deposit. Carbonate minerals associated with skarn and replacement sulfide throughout the district have isotopic compositions that are consistent with formation from a hydrothermal fluid of magmatic origin. Lower homogenization temperatures and salinities in the younger quartz-rich sulfide assemblage and quartz-rhodochrosite vein breccias, together with low δ18O values of gangue carbonate, suggest dilution of a primary magmatic fluid with meteoric water late in the evolution of the hydrothermal system in both the Olympias area and the Stratoni fault zone. The replacement sulfide orebodies in the district likely inherited their uniform Pb isotope composition from a late Oligocene igneous source and the isotopically heterogeneous metamorphic basement units. Metal distribution patterns at the scale of the Stratoni fault zone show diminishing Cu concentration with decreasing Pb/Zn and Ag/Au ratios from Madem Lakkos to Mavres Petres and the Piavitsa prospect in the west. The sulfide orebodies at the Olympias deposit exhibit elevated Cu values in the east with increasing Pb/Zn and Ag/Au ratios down-plunge to the south-southwest. Metal concentration and ratios support zoning related to temperature and solubility changes with increasing distance from a probable magmatic source. Structural and igneous relationships, together with fluid inclusion microthermometric and carbon-oxygen isotope data and metal distribution patterns, are supportive of a zoned hydrothermal system that exceeded 12 km along the Stratoni fault zone, sourced by an igneous intrusion to the southeast of the Madem Lakkos deposit. The Olympias replacement sulfide orebodies, associated with the Kassandra fault, resulted from a local hydrothermal system that was likely derived from a concealed igneous intrusion to the east of the deposit. 

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5. Oxygen isotope ratios in zircon and garnet: A record of assimilation and fractional crystallization in the Dinkey Dome peraluminous granite, Sierra Nevada, California

   https://doi.org/10.2138/am-2021-7472  

   Quintero, Raiza R.; Kitajima, Kouki; Lackey, Jade Star; Kozdon, Reinhard; Strickland, Ariel; Valley, John W. (May 2021, American Mineralogist)

   null (Ed.)

   Abstract The 119 Ma Dinkey Dome pluton in the central Sierra Nevada Batholith is a peraluminous granite and contains magmatic garnet and zircon that are complexly zoned with respect to oxygen isotope ratios. Intracrystalline SIMS analysis tests the relative importance of magmatic differentiation processes vs. partial melting of metasedimentary rocks. Whereas δ18O values of bulk zircon concentrates are uniform across the entire pluton (7.7‰ VSMOW), zircon crystals are zoned in δ18O by up to 1.8‰, and when compared to late garnet, show evidence of changing magma chemistry during multiple interactions of the magma with wall rock during crustal transit. The evolution from an early high-δ18O magma [δ18O(WR) = 9.8‰] toward lower values is shown by high-δ18O zircon cores (7.8‰) and lower δ 18O rims (6.8‰). Garnets from the northwest side of the pluton show a final increase in δ18O with rims reaching 8.1‰. In situ REE measurements show zircon is magmatic and grew before garnets. Additionally, δ18O in garnets from the western side of the pluton are consistently higher (avg = 7.3‰) relative to the west (avg = 5.9‰). These δ18O variations in zircon and garnet record different stages of assimilation and fractional crystallization whereby an initially high-δ18O magma partially melted low-δ18O wallrock and was subsequently contaminated near the current level of emplacement by higher δ18O melts. Collectively, the comparison of δ18O zoning in garnet and zircon shows how a peraluminous pluton can be constructed from multiple batches of variably contaminated melts, especially in early stages of arc magmatism where magmas encounter significant heterogeneity of wall-rock assemblages. Collectively, peraluminous magmas in the Sierran arc are limited to small <100 km2 plutons that are intimately associated with metasedimentary wall rocks and often surrounded by later and larger metaluminous tonalite and granodiorite plutons. The general associations suggest that early-stage arc magmas sample crustal heterogeneities in small melt batches, but that with progressive invigoration of the arc, such compositions are more effectively blended with mantle melts in source regions. Thus, peraluminous magmas provide important details of the nascent Sierran arc and pre-batholithic crustal structure. 

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