skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: Cathodoluminescence investigation of defect states in n- and p-type AlN
State-of-the-art semiconducting aluminum nitride (AlN) films were characterized by cathodoluminescence (CL) spectroscopy in the range of 200–500 nm in an attempt to identify the energy levels within the bandgap and their associated defects. Near-band edge emission (around 206 nm) and high-intensity peaks centered in the near UV range (around 325 nm) are observed for both n- and p-type AlN films. The near UV peaks are potentially associated with oxygen contamination in the films. The p-type AlN films contain at least two unidentified peaks above 400 nm. Assuming that the dopant concentration is independent of compensation (i.e., in the perfect doping limit), three effective donor states are found from Fermi–Dirac statistics for Si-doped AlN, at ∼0.035, ∼0.05, and ∼0.11 eV. Similarly, a single effective acceptor energy of ∼0.03–0.05 eV (depending on the degeneracy factory considered) was found for Be doped AlN. CL investigation of doped AlN films supports claims that AlN may be a promising optoelectronic material, but also points to contaminant mitigation and defect theory as major areas for future study.  more » « less
Award ID(s):
2246582
PAR ID:
10539628
Author(s) / Creator(s):
; ; ; ; ;
Publisher / Repository:
AIP
Date Published:
Journal Name:
Applied Physics Letters
Volume:
124
Issue:
5
ISSN:
0003-6951
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. null (Ed.)
    Charge transport mechanisms governing DC resistance degradation in ferroelectric films are influenced by defects, particularly oxygen vacancies. This paper demonstrates that oxygen vacancies migrate in lead zirconate titanate (PZT) films under a DC bias field and contribute to resistance degradation. Model PZT thin films were developed in which the concentration and distribution of oxygen vacancies were controlled via (a) changing the dopant type and concentration from 1%–4% Mn (acceptor) to 1%–4% Nb (donor) or (b) annealing undoped PZT films at varying partial pressures of PbO. The presence of associated (immobile) and dissociated (mobile) oxygen vacancies was distinguished by thermally stimulated depolarization current (TSDC) measurements. The impact of mobile oxygen vacancies on local defect chemistry and associated charge transport mechanisms was explored by electron energy loss spectroscopy (EELS). For Mn-doped PZT films, following resistance degradation, TSDC studies revealed only one depolarization peak with an activation energy of 0.6–0.8 eV; this peak was associated with ionic space charge presumably due to migration of oxygen vacancies. The magnitude of the depolarization current peak increased with increasing degradation times. A similar depolarization current peak attributed to the existence of mobile oxygen vacancies was also observed for undoped and Nb-doped PZT films; the magnitude of this peak decreased as the Nb or PbO contents in PZT films increased. An additional TSDC peak associated with polaron hopping between Ti3+ and Ti4+ was found in both Nb-doped PZT films and undoped PZT films annealed under low PbO partial pressure. Degraded Nb-doped samples exhibited a chemical shift in the TiL2,3 peak to lower energy losses and the appearance of shoulders on the t2g and eg peaks, implying a reduction of Ti cations in regions near the cathode. 
    more » « less
  2. Near-ideal behavior in Schottky contacts to Si-doped AlN was observed as evidenced by a low ideality factor of 1.5 at room temperature. A temperature-independent Schottky barrier height of 1.9 eV was extracted from temperature-dependent I–V measurements. An activation energy of ∼300 meV was observed in the series resistance, which corresponded to the ionization energy of the deep Si donor state. Both Ohmic and Schottky contacts were stable up to 650 °C, with around four orders of magnitude rectification at this elevated temperature. These results demonstrate the potential of AlN as a platform for power devices capable of operating in extreme environments. 
    more » « less
  3. We report on growth and electrical properties of α-Ga2O3films prepared by halide vapor phase epitaxy (HVPE) at 500 °C on α-Cr2O3buffers predeposited on sapphire by magnetron sputtering. The α-Cr2O3buffers showed a wide microcathodoluminescence (MCL) peak near 350 nm corresponding to the α-Cr2O3bandgap and a sharp MCL line near 700 nm due to the Cr+intracenter transition. Ohmic contacts to Cr2O3were made with both Ti/Au or Ni, producing linear current–voltage ( I– V) characteristics over a wide temperature range with an activation energy of conductivity of ∼75 meV. The sign of thermoelectric power indicated p-type conductivity of the buffers. Sn-doped, 2- μm-thick α-Ga2O3films prepared on this buffer by HVPE showed donor ionization energies of 0.2–0.25 eV, while undoped films were resistive with the Fermi level pinned at ECof 0.3 eV. The I– V and capacitance–voltage ( C– V) characteristics of Ni Schottky diodes on Sn-doped samples using a Cr2O3buffer indicated the presence of two face-to-face junctions, one between n-Ga2O3and p-Cr2O3, the other due to the Ni Schottky diode with n-Ga2O3. The spectral dependence of the photocurrent measured on the structure showed the presence of three major deep traps with optical ionization thresholds near 1.3, 2, and 2.8 eV. Photoinduced current transient spectroscopy spectra of the structures were dominated by deep traps with an ionization energy of 0.95 eV. These experiments suggest another pathway to obtain p–n heterojunctions in the α-Ga2O3system. 
    more » « less
  4. Chromium-doped SrTiO 3 nanocrystals of perovskite structure type and 45 nm (±15 nm) edge lengths were obtained by hydrothermal synthesis in water from titanium oxide, strontium hydroxide, and chromium( iii ) nitrate. According to XPS, the majority of the surface chromium (68.3%) is present in the 3+ state and the remainder (32.2%) in the 6+ state. Optical spectroscopy confirms a broad absorption at 2.3–2.9 eV from Cr(3+) dopant states, in addition to the 3.2 eV band edge of the SrTiO 3 host. After modification with Pt nanoparticles, Cr-doped SrTiO 3 nanocrystals catalyze photochemical H 2 evolution from aqueous methanol under visible light illumination (>400 nm) and with an apparent quantum yield of 0.66% at 435 nm. According to surface photovoltage spectroscopy (SPS), Cr-doped SrTiO 3 nanocrystals deposited onto gold substrates are n-type and have an effective band gap of 1.75 eV. SPS and transient illumination experiments at 2.50 eV reveal an anomalous surface photovoltage that increases with prior light exposure to values of up to −6.3 V. This photovoltage is assigned to ferroelectric polarization of the material in the space charge layer at the Au/SrTiO 3 :Cr interface. The polarization is stable for 24 h in vacuum but disappears after 12 h when samples are stored in air. The electric polarizability of SrTiO 3 :Cr is confirmed when films are exposed to static electric fields (1.20 MV m −1 ) in a fixed capacitor configuration. The discovery of a ferroelectric effect in Cr-doped SrTiO 3 could be significant for the development of improved photocatalysts for the conversion of solar energy into fuel. 
    more » « less
  5. A series of atomic-like photoluminescence (PL) emission peaks in UV region near 4.0 eV were created by thermal annealing hexagonal boron nitride (h-BN) single crystals in air. The pristine h-BN did not have these peaks, emitting strong phonon-assisted band edge PL with peaks at 5.78 and 5.89 eV. After annealing the h-BN crystals in ambient air, a new atomic-like sharp emission in UV region at 4.09 eV with a line width of 0.2 nm appeared along with its phonon replicas at 3.89 and 3.69 eV in the low temperature (8 K) PL measurement. Further testing demonstrated that annealing the h-BN samples in the temperature window of 700–950 °C for 60 min generated the atomic-like emission. The peak position of the emission line is stable with the temperature and PL excitation power. Our study also suggests that the defect responsible for the atomic-like emission resides in the surface region. 
    more » « less