skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: Temperature-dependent Li-ion transport in lithium lanthanum titanate electrolytes
A shift of the Li+ion hopping mechanism with temperature in solid-state lithium lanthanum titanate (LLTO) electrolytes was discovered usingab initiometadynamics simulations.  more » « less
Award ID(s):
2144360
PAR ID:
10542399
Author(s) / Creator(s):
; ;
Publisher / Repository:
Royal Society of Chemistry
Date Published:
Journal Name:
Chemical Communications
Volume:
60
Issue:
67
ISSN:
1359-7345
Page Range / eLocation ID:
8844 to 8847
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Abstract Accurate nuclear reaction rates for26P(p,γ)27S are pivotal for a comprehensive understanding of therp-process nucleosynthesis path in the region of proton-rich sulfur and phosphorus isotopes. However, large uncertainties still exist in the current rate of26P(p,γ)27S because of the lack of nuclear mass and energy level structure information for27S. We reevaluate this reaction rate using the experimentally constrained27S mass, together with the shell model predicted level structure. It is found that the26P(p,γ)27S reaction rate is dominated by a direct capture reaction mechanism despite the presence of three resonances atE= 1.104, 1.597, and 1.777 MeV above the proton threshold in27S. The new rate is overall smaller than the other previous rates from the Hauser–Feshbach statistical model by at least 1 order of magnitude in the temperature range of X-ray burst interest. In addition, we consistently update the photodisintegration rate using the new27S mass. The influence of new rates of forward and reverse reaction in the abundances of isotopes produced in therp-process is explored by postprocessing nucleosynthesis calculations. The final abundance ratio of27S/26P obtained using the new rates is only 10% of that from the old rate. The abundance flow calculations show that the reaction path26P(p,γ)27S(β+,ν)27P is not as important as previously thought for producing27P. The adoption of the new reaction rates for26P(p,γ)27S only reduces the final production of aluminum by 7.1% and has no discernible impact on the yield of other elements. 
    more » « less
  2. We report on spectroscopic measurements on the 4f76s28S7/2−4f7(8S)6s6p(1P)8P5/2,7/2transitions at 466.32 nm and 462.85 nm, respectively, in neutral europium-151 and europium-153. The center of gravity frequencies for the 151 and 153 isotopes for both transitions are reported for the first time using saturated absorption spectroscopy. For the 6s6p(1P)8P5/2state, the center of gravity frequencies were found to be 642,894,493.3(4) MHz and 642,891,693.3(9) MHz for the 151 and 153 isotopes, respectively. The hyperfine constants for the upper state were found to beA(151)=−157.01(3)MHz,B(151)=74.5(4)MHz andA(153)=−69.43(14)MHz,B(153)=191.0(26)MHz. These hyperfine values are all consistent with previously published results except forB(151) that has a small discrepancy. The isotope shift was found to be 2799.54(20) MHz, a small discrepancy with previously published results. For the 6s6p(1P)8P7/2state, the center of gravity frequencies were found to be 647,708,930.6(6) MHz and 647,705,958.4(26) MHz for the 151 and 153 isotopes, respectively. The hyperfine constants for the upper state were found to beA(151)=−218.66(4)MHz,B(151)=−293.4(8)MHz andA(153)=−97.15(13)MHz,B(153)=−750(3)MHz. These values are all consistent with previously published results except forA(151) that has a small discrepancy. The isotope shift was found to be 2972.8(5) MHz, a small discrepancy with previously measured results. 
    more » « less
  3. Abstract Cadmium is laser-cooled and trapped with excitations to triplet states with UVA light, first using only the 67 kHz wide 326 nm intercombination line and subsequently, for large loading rates, the 25 MHz wide 361 nm3P23D3transition. Eschewing the hard UV 229 nm1S01P1transition, only small magnetic fields gradients, less than 6 G cm−1, are required enabling a 100% transfer of atoms from the 361 nm trap to the 326 nm narrow-line trap. All 8 stable cadmium isotopes are straightforwardly trapped, including two nuclear-spin- 1 2 fermions that require no additional repumping. We observe evidence of3P2collisions limiting the number of trapped metastable atoms, report isotope shifts for111Cd and113Cd of the 326 nm1S03P1, 480nm3P13S1, and 361 nm3P23D3transitions, and measure the114Cd 5s5p3P2→ 5s5d3D3transition frequency to be 830 096 573(15) MHz. 
    more » « less
  4. Context.An accurate28P(p,γ)29S reaction rate is crucial to defining the nucleosynthesis products of explosive hydrogen burning in ONe novae. Using the recently released nuclear mass of29S, together with a shell model and a direct capture calculation, we reanalyzed the28P(p,γ)29S thermonuclear reaction rate and its astrophysical implication. Aims.We focus on improving the astrophysical rate for28P(p,γ)29S based on the newest nuclear mass data. Our goal is to explore the impact of the new rate and associated uncertainties on the nova nucleosynthesis. Methods.We evaluated this reaction rate via the sum of the isolated resonance contribution instead of the previously used Hauser-Feshbach statistical model. The corresponding rate uncertainty at different energies was derived using a Monte Carlo method. Nova nucleosynthesis is computed with the 1D hydrodynamic code SHIVA. Results.The contribution from the capture on the first excited state at 105.64 keV in28P is taken into account for the first time. We find that the capture rate on the first excited state in28P is up to more than 12 times larger than the ground-state capture rate in the temperature region of 2.5 × 107K to 4 × 108K, resulting in the total28P(p,γ)29S reaction rate being enhanced by a factor of up to 1.4 at ~1 × 109K. In addition, the rate uncertainty has been quantified for the first time. It is found that the new rate is smaller than the previous statistical model rates, but it still agrees with them within uncertainties for nova temperatures. The statistical model appears to be roughly valid for the rate estimation of this reaction in the nova nucleosynthesis scenario. Using the 1D hydrodynamic code SHIVA, we performed the nucleosynthesis calculations in a nova explosion to investigate the impact of the new rates of28P(p,γ)29S. Our calculations show that the nova abundance pattern is only marginally affected if we use our new rates with respect to the same simulations but statistical model rates. Finally, the isotopes whose abundance is most influenced by the present28P(p,γ)29S uncertainty are28Si,33,34S,35,37Cl, and36Ar, with relative abundance changes at the level of only 3% to 4%. 
    more » « less
  5. Context.Accurate42Ti(p,γ)43V reaction rates are crucial for understanding the nucleosynthesis path of the rapid capture process (rpprocess) that occurs in X-ray bursts. Aims.We aim to improve the thermonuclear rates of42Ti(p,γ)43V based on more complete resonance information and a more accurate direct component, together with the recently released nuclear masses data. We also explore the impact of the newly obtained rates on therpprocess. Methods.We reevaluated the reaction rate of42Ti(p,γ)43V by the sum of the isolated resonance contribution instead of the Hauser-Feshbach statistical model. We used a Monte Carlo method to derive the associated uncertainties of new rates. The nucleosynthesis simulations were performed via the NuGrid post-processing code ppn. Results.The new rates differ from previous estimations due to the use of a series of updated resonance parameters and a direct S factor. Compared with the previous results from the Hauser-Feshbach statistical model, which assumes compound nucleus43V with a sufficiently high-level density in the energy region of astrophysical interest, large differences exist over the entire temperature region ofrp-process interest, up to two orders of magnitude. We consistently calculated the photodisintegration rate using our new nuclear masses via the detailed balance principle, and found the discrepancies among the different reverse rates are much larger than those for the forward rate, up to ten orders of magnitude at the temperature of 108K. Using a trajectory with a peak temperature of 1.95×109K, we performed therp-process nucleosynthesis simulations to investigate the impact of the new rates. Our calculations show that the adoption of the new forward and reverse rates result in abundance variations for Sc and Ca of 128% and 49%, respectively, compared to the variations for the statistical model rates. On the other hand, the overall abundance pattern is not significantly affected. The results of using new rates also confirm that therp-process path does not bypass the isotope43V. Conclusions.Our study found that the Hauser-Feshbach statistical model is inappropriate to the reaction rate evaluation for42Ti(p,γ)43V. The adoption of the new rates confirms that the reaction path of42Ti(p,γ)43V(p,γ)44Cr(β+)44V is a key branch of therpprocess in X-ray bursts. 
    more » « less