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  • ND70 Series Basaltic Glass Reference Materials for Volatile Element ( H2O , CO2 , S, Cl, F) Measurement and the C Ionisation Efficiency Suppression Effect of Water in Silicate Glasses in SIMS
Title: ND70 Series Basaltic Glass Reference Materials for Volatile Element ( H2O , CO2 , S, Cl, F) Measurement and the C Ionisation Efficiency Suppression Effect of Water in Silicate Glasses in SIMS
We present a new set of reference materials, the ND70‐series, forin situmeasurement of volatile elements (H2O, CO2, S, Cl, F) in silicate glass of basaltic composition. The materials were synthesised in piston cylinders at pressures of 1 to 1.5 GPa under volatile‐undersaturated conditions. They span mass fractions from 0 to 6%m/mH2O, from 0 to 1.6%m/mCO2and from 0 to 1%m/mS, Cl and F. The materials were characterised by elastic recoil detection analysis for H2O, by nuclear reaction analysis for CO2, by elemental analyser for CO2, by Fourier transform infrared spectroscopy for H2O and CO2, by secondary ion mass spectrometry for H2O, CO2, S, Cl and F, and by electron probe microanalysis for CO2, S, Cl and major elements. Comparison between expected and measured volatile amounts across techniques and institutions is excellent. It was found however that SIMS measurements of CO2mass fractions using either Cs+or O−primary beams are strongly affected by the glass H2O content. Reference materials have been made available to users at ion probe facilities in the US, Europe and Japan. Remaining reference materials are preserved at the Smithsonian National Museum of Natural History where they are freely available on loan to any researcher.  more » « less
Award ID(s):
2128822 2216262
PAR ID:
10546196
Author(s) / Creator(s):
; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ;
Publisher / Repository:
International Association of Geoanalysts
Date Published:
Journal Name:
Geostandards and Geoanalytical Research
ISSN:
1639-4488
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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