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Abstract The decay of the primordial isotopes238U,235U,232Th, and40K has contributed to the terrestrial heat budget throughout the Earth's history. Hence, the individual abundance of those isotopes are key parameters in reconstructing contemporary Earth models. The geoneutrinos produced by the radioactive decays of uranium and thorium have been observed with the Kamioka Liquid‐Scintillator Antineutrino Detector (KamLAND). Those measurements have been improved with more than 18‐year observation time, and improvement in detector background levels mainly with an 8‐year nearly reactor‐free period, which now permit spectroscopy with geoneutrinos. Our results yield the first constraint on both uranium and thorium heat contributions. The KamLAND result is consistent with geochemical estimations based on elemental abundances of chondritic meteorites and mantle peridotites. The High‐Q model is disfavored at 99.76% C.L. and a fully radiogenic model is excluded at 5.2σassuming a homogeneous heat producing element distribution in the mantle.
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Mass spectrometry developments of 232Th and 238U radiopurity measurements for LEGEND
Abstract The LEGEND collaboration has been developing a76Ge-based double-beta decay experimental program where precise radiopurity measurements of ultraclean materials are crucial. Ultralow concentrations of thorium and uranium, the main contributors to the detector background via their decay products, can be determined by inductively coupled plasma mass spectrometry (ICPMS) and accelerator mass spectrometry (AMS). Here we shall present recent developments in thorium and uranium mass spectrometry methods, together with basics of separation chemistry applied to process different samples. The new possibilities to measure232Th and238U by ICPMS and AMS at the Comenius University in Bratislava are discussed as well.
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- Award ID(s):
- 1812374
- PAR ID:
- 10546527
- Publisher / Repository:
- J. Radioanal. Nucl. Chem.
- Date Published:
- Journal Name:
- Journal of Radioanalytical and Nuclear Chemistry
- Volume:
- 333
- Issue:
- 7
- ISSN:
- 0236-5731
- Page Range / eLocation ID:
- 3431 to 3437
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1007/s10967-024-09352-6
