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Rigidochromism of tetranuclear Cu( i )–pyrazolate macrocycles: steric crowding with trifluoromethyl groups
Introducing CF3between twotBu groups creates steric crowding that destabilizes the conformations of copper–pyrazolate tetramers. The impact of conformational behavior on luminescence is examined by low-temperature X-ray and photophysical studies.
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- Award ID(s):
- 2102639
- PAR ID:
- 10547564
- Publisher / Repository:
- Royal Society of Chemistry
- Date Published:
- Journal Name:
- Chemical Communications
- Volume:
- 60
- Issue:
- 80
- ISSN:
- 1359-7345
- Page Range / eLocation ID:
- 11307 to 11310
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1039/d4cc04259j
