This content will become publicly available on October 11, 2025
- Award ID(s):
- 1326927
- PAR ID:
- 10548375
- Publisher / Repository:
- International Ocean Discovery Program
- Date Published:
- Journal Name:
- Proceedings of the International Ocean Discovery Program Expedition reports
- Volume:
- 396
- Issue:
- 201
- ISSN:
- 2377-3189
- Subject(s) / Keyword(s):
- International Ocean Discovery Program IODP JOIDES Resolution Expedition 396 Mid-Norwegian Margin Magmatism and Paleoclimate Implications Site U1574 Eldhø XRF scanning
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
During International Ocean Discovery Program (IODP) Expeditions 390C, 395E, 390, and 393, deepwater sediments were recovered from the western flank of the southern Mid-Atlantic Ridge along a crustal flow line at ~31°S. This multidisciplinary experiment allowed the recovery of data fundamental to reconstructing past climate changes as well as variations in ocean circulation, productivity, and chemistry (i.e., fluctuations in the carbonate compensation depth) in the South Atlantic Ocean. Here, we report semiquantitative elemental results from X-ray fluorescence (XRF) scanning of the sediment package cored at IODP Site U1559 in the South Atlantic Ocean. Located at 15°02.0941′W, Site U1559 is the easternmost site of the South Atlantic Transect and the closest to the Mid-Atlantic Ridge, located on ~6.6. Ma ocean crust. The XRF data are also compared with magnetic susceptibility and natural gamma radiation measured on the R/V JOIDES Resolution to assess correlations with the different lithologic units/subunits. At Site U1559, sediments are predominantly nannofossil ooze with varying amounts of foraminifera, which is reflected by the dominant Ca counts. Trends in elemental counts reflect the slight variations in siliciclastic materials within the Pleistocene. Major shifts in elemental counts were observed at the sharp contact between Pliocene–Pleistocene Subunits IC and ID, as well as the Miocene–Pliocene transition.more » « less
-
International Ocean Discovery Program (IODP) Expeditions 390C, 395E, 390, and 393 recovered deepwater sediments from the western flank of the Mid-Atlantic Ridge in the South Atlantic Ocean along the South Atlantic Transect (SAT) at ~31°S. Collectively, these expeditions recovered ~2 km of sediment cores that have the potential to capture key features of Cenozoic climate change. In this report, we show semiquantitative bulk elemental results from X-ray fluorescence (XRF) scanning of the sediment cores from IODP Site U1560 recovered during Expeditions 395E and 393. The oceanic basement at this site is ~15 My old, making it the second youngest of the SAT sites located west of the Mid-Atlantic Ridge. Here, XRF data are compared with pass-through magnetic susceptibility and natural gamma radiation of the sediment cores, measured aboard JOIDES Resolution. The resulting trends and correlations highlight elemental variations through time, mainly reflecting lithologic and compositional differences. At Site U1560, Ca counts reflect the occurrence of nannofossil ooze, which is the dominant lithology for the whole site. In the Miocene-aged Lithologic Units IE–IA from 140 to 50 m core composite depth below seafloor (CCSF), several high-intensity spikes of detrital elements (i.e., Fe, Ti, Al, Si, and Zr) correspond to intervals of clay-rich nannofossil ooze. Detrital elemental counts in the entire Pliocene record (50 to ~25 m CCSF) are the lowest. A sharp shift is observed at the Pliocene/Pleistocene boundary at ~25 m CCSF, with the uppermost Pleistocene record showing high-frequency and high-intensity variations in siliciclastic elements, which correlates well with the pass-through magnetic susceptibility.more » « less
-
We report semiquantitative elemental data from X-ray fluorescence (XRF) scanning of Site U1558 sediment cores drilled during International Ocean Discovery Program Expeditions 390C and 393. These expeditions, together with Expeditions 395E and 390, form the South Atlantic Transect, which collected sediment and basement cores from the western flank of the southern Mid-Atlantic Ridge. XRF scanning of the continuous splice of Site U1558, using Holes U1558A and U1558F, was conducted at three acceleration voltages to capture a range of major, minor, and trace elements. At Site U1558, positive correlations exist between terrigenous-sourced elements (Al, Si, Ti, and Fe) and a negative correlation exists between the terrigenous-sourced elements and Ca. XRF geochemistry is correlated with lithologic changes, most notably at the boundary of Lithologic Units I and II, where Unit I is brown and reddish brown nannofossil-rich clay and Unit II is pink, pinkish white, pinkish gray, and light brown nannofossil ooze and chalk with varying amounts of clay and foraminifera. Peaks in XRF data align with the boundaries of Lithologic Subunits IIA and IIB and Subunits IIB and IIC.more » « less
-
To estimate the calcium carbonate (CaCO3) content in the Site U1543 sediment core samples retrieved during International Ocean Discovery Program (IODP) Expedition 383 at high downcore resolution, the X-ray fluorescence (XRF) scanning Ca data, at a spacing of every 10 mm downcore, were calibrated using a total of 118 coulometry-based discrete CaCO3 analyses from the upper 30 meters composite depth (mcd) along the splice. To remove the volume measurement problems of XRF and estimating CaCO3 contents quantitatively, first, raw XRF peak areas were scaled to reduce the effect resulting from the differences in efficiency at absorbing X-rays. Then, the scaled XRF scanning data were normalized to adjust the variability of the amount of XRF peak areas due to porosity and calibrated to properly estimate CaCO3 content. Based on the quality assessment, the calibrated XRF CaCO3 estimates are within ±4.50 wt% of the discrete measurements (1 standard deviation). This data report presents a discrete CaCO3 measurement data set, a normalized median-scaled XRF data set, and XRF CaCO3 estimates on the core depth below seafloor, Method A (CSF-A), and core composite depth below seafloor, Method A (CCSF-A), depth scales.more » « less
-
Intercomparison of XRF Core Scanning Results From Seven Labs and Approaches to Practical Calibration
Abstract X‐ray fluorescence (XRF) scanning of marine sediment has the potential to yield near‐continuous and high‐resolution records of elemental abundances, which are often interpreted as proxies for paleoceanographic processes over different time scales. However, many other variables also affect scanning XRF measurements and convolute the quantitative calibrations of element abundances and comparisons of data from different labs. Extensive interlab comparisons of XRF scanning results and calibrations are essential to resolve ambiguities and to understand the best way to interpret the data produced. For this study, we sent a set of seven marine sediment sections (1.5 m each) to be scanned by seven XRF facilities around the world to compare the outcomes amidst a myriad of factors influencing the results. Results of raw element counts per second (cps) were different between labs, but element ratios were more comparable. Four of the labs also scanned a set of homogenized sediment pellets with compositions determined by inductively coupled plasma‐optical emission spectrometry (ICP‐OES) and ICP‐mass spectrometry (MS) to convert the raw XRF element cps to concentrations in two ways: a linear calibration and a log‐ratio calibration. Although both calibration curves are well fit, the results show that the log‐ratio calibrated data are significantly more comparable between labs than the linearly calibrated data. Smaller‐scale (higher‐resolution) features are often not reproducible between the different scans and should be interpreted with caution. Along with guidance on practical calibrations, our study recommends best practices to increase the quality of information that can be derived from scanning XRF to benefit the field of paleoceanography.