To estimate the calcium carbonate (CaCO3) content in the Site U1543 sediment core samples retrieved during International Ocean Discovery Program (IODP) Expedition 383 at high downcore resolution, the X-ray fluorescence (XRF) scanning Ca data, at a spacing of every 10 mm downcore, were calibrated using a total of 118 coulometry-based discrete CaCO3 analyses from the upper 30 meters composite depth (mcd) along the splice. To remove the volume measurement problems of XRF and estimating CaCO3 contents quantitatively, first, raw XRF peak areas were scaled to reduce the effect resulting from the differences in efficiency at absorbing X-rays. Then, the scaled XRF scanning data were normalized to adjust the variability of the amount of XRF peak areas due to porosity and calibrated to properly estimate CaCO3 content. Based on the quality assessment, the calibrated XRF CaCO3 estimates are within ±4.50 wt% of the discrete measurements (1 standard deviation). This data report presents a discrete CaCO3 measurement data set, a normalized median-scaled XRF data set, and XRF CaCO3 estimates on the core depth below seafloor, Method A (CSF-A), and core composite depth below seafloor, Method A (CCSF-A), depth scales.
more »
« less
Data report: X-ray fluorescence core scanning of IODP Site U1474 sediments, Natal Valley, Southwest Indian Ocean, Expedition 361
X-ray fluorescence (XRF) core scanning was conducted on core sections from International Ocean Discovery Program Site U1474, located in the Natal Valley off the coast of South Africa. The data were collected at 2 mm resolution along the 255 m length of the splice, but this setting resulted in noisy data. This problem was addressed by applying a 10 point running sum on the XRF data prior to converting peak area to element intensities. This effectively integrates 10 measurements into 1, representing an average over 2 cm resolution, and significantly improves noise in the data. With 25 calibration samples, whose element concentrations were derived using inductively coupled plasma–optical emission spectrometry, the XRF measurements were converted to concentrations using a univariate log-ratio calibration method. The resulting concentrations of terrigenously derived major elements (Al, Si, K, Ti, and Fe) are anticorrelated with Ca concentrations, indicating the main control on sediment chemistry is the variable proportion of terrigenous to in situ produced carbonate material.
more »
« less
- Award ID(s):
- 1326927
- PAR ID:
- 10229627
- Date Published:
- Journal Name:
- Proceedings of the International Ocean Discovery Program
- Volume:
- 361
- ISSN:
- 2377-3189
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
null (Ed.)Bulk sediment chemistry was measured at 2 cm resolution along cores from International Ocean Discovery Program (IODP) Site U1457 using the X-ray fluorescence (XRF) core scanner at the IODP Gulf Coast Repository. The Pleistocene splice section assembled from Holes U1457A and U1457B was scanned in its entirety, and nearly continuous sediment bulk chemistry profiles were constructed to a depth of 125 m core composite depth below seafloor (CCSF). Some sections of Hole U1457C were also scanned: (1) an upper Miocene hemipelagic section and (2) a 30 m lower Paleocene section directly overlying basalt. In the Pleistocene spliced sections, 2 cm spacing represents a sampling resolution of 150–300 y, whereas in the upper Miocene section this spacing represents about 500 y between samples. We report data and acquisition conditions for major and many minor elements. We find large variability in CaCO3 content in the Pleistocene section, from around 14 to 89 wt%. We used discrete shipboard CaCO3 measurements to calibrate the XRF Ca data. CaCO3 has cyclic variability and correlates with light sediment colors. Variation in aluminosilicate elements is largely caused by changes in dilution by CaCO3. The lower part of the spliced section, presumably representing distal Indus Fan deposits, has a distinctive but more uniform composition than the upper part.more » « less
-
Past bottom current velocities are usually determined from the sortable silt (SS) fraction of sediments. This method yields precise results, but the work associated with the preparation for and analysis of SS is very time consuming. Using data and samples from Site U1537, which was drilled during International Ocean Discovery Program (IODP) Expedition 382 (Iceberg Alley and Subantarctic Ice and Ocean Dynamics), we followed a method that allows for the reconstruction of bottom current velocities on long and highly resolved sediment records, as typically recovered during an IODP expedition. Here, we present discrete measurements of SS from Site U1537 that were used to convert X-ray fluorescence (XRF) core scanner Zr/Rb data into SS and ultimately into bottom current velocities. The use of XRF-derived SS data and current speeds allows us to generate a near-continuous high-resolution record for the past 200 ky. Because Site U1537 is located close to the Southern Antarctic Circumpolar Current Front (SACCF), this long-term reconstruction allows us to analyze and understand changes in the location of the SACCF.more » « less
-
Semiquantitative elemental results from X-ray fluorescence (XRF) scanning of sediment cores from International Ocean Discovery Program (IODP) Site U1574 in the Vøring Plateau, Norwegian Margin, are presented in this report. XRF elemental data were collected every 1 cm from a stratigraphically complete and continuous cored section with 102% recovery from the sea bottom to ~170 meters below seafloor in Hole U1574C. We report raw element intensities (counts) for Al, Si, K, Ca, Ti, Fe, Br, Sr, and Zr and identify covariation patterns consistent with lithofacies variations. Our high-resolution XRF scanning was conducted to better characterize the sediment depositional history at Site U1574 and to aid interpretation of past environmental and oceanographic conditions in the Norwegian Margin, targeting the earliest incursion of deep water into the young North Atlantic Ocean during the Early to Middle Eocene. The high-resolution XRF data also may help improve the age-depth model for the sediment succession at Site U1574.more » « less
-
The continuous underway fluorescence, induced by in vivo chlorophyll-a (Chl-a), of surface waters of the Northeast U.S. shelf is compared to discrete Chl-a samples for post-calibration, collected ship-board as part of the Northeast U.S. Shelf Long-Term Ecological Research (NES LTER). Chl-a values derived from the manufacturer-calibrated sensors (hereafter, “continuous fluorescence”) and collected continuously are often different from the precise Chl-a concentrations obtained from discrete, extracted samples. Moreover, underway fluorometers and manufacturer calibrations differ per cruise. Thus, post-calibration of the continuous fluorescence signals using discrete Chl-a measurements is essential to standardize and compare the high-resolution underway Chl-a data along cruise tracks. For six cruises aboard the R/V Endeavor between summer 2019 and summer 2021, 12 to 22 discrete samples were collected from the underway system to measure Chl-a concentrations. These discrete Chl-a concentrations were then compared, using simple linear regressions (Model I least square fit), to corresponding continuous fluorescence values recorded by the two independent fluorometers installed with the underway system. For each cruise a preferred fluorometer was identified based on the best fit of the linear regression between discrete Chl-a concentrations and continuous fluorescence values. The slope and the intercept of the linear regression were used to post-calibrate continuous fluorescence values into standardized and intercomparable Chl-a concentration. This data package includes a table for the underway discrete Chl-a values and a table for the 1-min post-calibrated continuous fluorescence values for the preferred underway fluorometer per cruise.more » « less
An official website of the United States government

