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Abstract Polarimetric infrared (IR) detection bolsters IR thermography by leveraging the polarization of light. Optical anisotropy, i.e., birefringence and dichroism, can be leveraged to achieve polarimetric detection. Recently, giant optical anisotropy is discovered in quasi‐1D narrow‐bandgap hexagonal perovskite sulfides, A1+xTiS3, specifically BaTiS3and Sr9/8TiS3. In these materials, the critical role of atomic‐scale structure modulations in the unconventional electrical, optical, and thermal properties raises the broader question of the nature of other materials that belong to this family. To address this issue, for the first time, high‐quality single crystals of a largely unexplored member of the A1+xTiX3(X = S, Se) family, BaTiSe3are synthesized. Single‐crystal X‐ray diffraction determined the room‐temperature structure with theP31cspace group, which is a superstructure of the earlier reportedP63/mmcstructure. The crystal structure of BaTiSe3features antiparallelc‐axis displacements similar to but of lower symmetry than BaTiS3, verified by the polarization dependent Raman spectroscopy. Fourier transform infrared (FTIR) spectroscopy is used to characterize the optical anisotropy of BaTiSe3, whose refractive index along the ordinary (E⊥c) and extraordinary (E‖c) optical axes is quantitatively determined by combining ellipsometry studies with FTIR. With a giant birefringence Δn∼ 0.9, BaTiSe3emerges as a new candidate for miniaturized birefringent optics for mid‐wave infrared to long‐wave infrared imaging.
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Achromatic correction for birefringent interferometers that improve Fourier transform spectrometers and hyperspectral imaging
Spectroscopy and hyperspectral imaging are widely used tools for identifying compounds and materials. One optical design is a polarization interferometer that uses birefringent wedges, like a Babinet-Soleil compensator, to create the interferograms that are Fourier transformed to give the spectra. Such designs have lateral spatial offset between thenoandneoptical beams, which reduces the interferogram intensity and creates a spatially dependent phase that is problematic for hyperspectral imaging. The lateral separation between the beams is wavelength dependent, created by the achromatic nature of Babinet-Soleil compensators. We introduce a birefringent wedge design for Fourier transform spectroscopy that creates collinearnoandneoptical beams for optimal interference and no spatial dependent phase. Our 3-wedge design, which we call a Wisconsin interferometer, improves the signal strength of polarization spectrometers, and eliminates phase shifts in hyperspectral imaging. We anticipate that it will find use in analytical, remote sensing, and ultrafast spectroscopy applications.
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- PAR ID:
- 10549402
- Publisher / Repository:
- Optical Society of America
- Date Published:
- Journal Name:
- Optics Express
- Volume:
- 32
- Issue:
- 22
- ISSN:
- 1094-4087; OPEXFF
- Format(s):
- Medium: X Size: Article No. 39446
- Size(s):
- Article No. 39446
- Sponsoring Org:
- National Science Foundation
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