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1. Theoretical Analysis of Critical Conditions for Crack Formation and Propagation, and Optimal Operation of SOECs

   https://doi.org/10.1149/1945-7111/ac5fee  

   Wang, Yudong; Virkar, Anil V.; Khonsari, M. M.; Zhou, Xiao-Dong (April 2022, Journal of The Electrochemical Society)

   A theoretical analysis on crack formation and propagation was performed based on the coupling between the electrochemical process, classical elasticity, and fracture mechanics. The chemical potential of oxygen, thus oxygen partial pressure, at the oxygen electrode-electrolyte interface ( ${\mu }_{O_2}^{\mathit{OE\mid El}}$) was investigated as a function of transport properties, electrolyte thickness and operating conditions (e.g., steam concentration, constant current, and constant voltage). Our analysis shows that: a lower ionic area specific resistance (ASR), $r_i^{OE},$and a higher electronic ASR ( $r_e^{OE}$) of the oxygen electrode/electrolyte interface are in favor of suppressing crack formation. The ${\mu }_{O_2}^{OE\mid El},$thus local pO₂, are sensitive towards the operating parameters under galvanostatic or potentiostatic electrolysis. Constant current density electrolysis provides better robustness, especially at a high current density with a high steam content. While constant voltage electrolysis leads to greater variations of ${\mu }_{O_2}^{OE\mid El}.$Constant current electrolysis, however, is not suitable for an unstable oxygen electrode because ${\mu }_{O_2}^{OE\mid El}$can reach a very high value with a gradually increased $r_i^{OE}.$A crack may only occur under certain conditions when $p_{O_2}^{TPB}>p_{cr}.$ 

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2. What Does the Geometry of the Hβ BLR Depend On?

   https://doi.org/10.3847/1538-4357/accc84  

   Villafaña, Lizvette; Williams, Peter R.; Treu, Tommaso; Brewer, Brendon J.; Barth, Aaron J.; U, Vivian; Bennert, Vardha N.; Guo, Hengxiao; Bentz, Misty C.; Canalizo, Gabriela; et al (May 2023, The Astrophysical Journal)

   Abstract We combine our dynamical modeling black-hole mass measurements from the Lick AGN Monitoring Project 2016 sample with measured cross-correlation time lags and line widths to recover individual scale factors,f, used in traditional reverberation-mapping analyses. We extend our sample by including prior results from Code for AGN Reverberation and Modeling of Emission Lines (caramel) studies that have utilized our methods. Aiming to improve the precision of black-hole mass estimates, as well as uncover any regularities in the behavior of the broad-line region (BLR), we search for correlations betweenfand other AGN/BLR parameters. We find (i) evidence for a correlation between the virial coefficient ${\log }_{10}\left(f_{\mathrm{mean},\sigma }\right)$and black-hole mass, (ii) marginal evidence for a similar correlation between ${\log }_{10}\left(f_{\mathrm{rms},\sigma }\right)$and black-hole mass, (iii) marginal evidence for an anticorrelation of BLR disk thickness with ${\log }_{10}\left(f_{\mathrm{mean},\mathrm{FWHM}}\right)$and ${\log }_{10}\left(f_{\mathrm{rms},\mathrm{FWHM}}\right)$, and (iv) marginal evidence for an anticorrelation of inclination angle with ${\log }_{10}\left(f_{\mathrm{mean},\mathrm{FWHM}}\right)$, ${\log }_{10}\left(f_{\mathrm{rms},\sigma }\right)$, and ${\log }_{10}\left(f_{\mathrm{mean},\sigma }\right)$. Last, we find marginal evidence for a correlation between line-profile shape, when using the root-mean-square spectrum, ${\log }_{10}{\left(\mathrm{FWHM}/\sigma \right)}_{\mathrm{rms}}$, and the virial coefficient, ${\log }_{10}\left(f_{\mathrm{rms},\sigma }\right)$, and investigate how BLR properties might be related to line-profile shape usingcaramelmodels. 

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3. The EDGE-CALIFA Survey: Spatially Resolved ¹³ CO(1–0) Observations and Variations in ¹² CO(1–0)/ ¹³ CO(1–0) in Nearby Galaxies on Kiloparsec Scales

   https://doi.org/10.3847/1538-4365/acd840  

   Cao, Yixian; Wong, Tony; Bolatto, Alberto D.; Leroy, Adam K.; Rosolowsky, Erik; Utomo, Dyas; Sánchez, Sebastián F.; Barrera-Ballesteros, Jorge K.; Levy, Rebecca C.; Colombo, Dario; et al (August 2023, The Astrophysical Journal Supplement Series)

   Abstract We present¹³CO(J= 1 → 0) observations for the EDGE-CALIFA survey, which is a mapping survey of 126 nearby galaxies at a typical spatial resolution of 1.5 kpc. Using detected¹²CO emission as a prior, we detect¹³CO in 41 galaxies via integrated line flux over the entire galaxy and in 30 galaxies via integrated line intensity in resolved synthesized beams. Incorporating our CO observations and optical IFU spectroscopy, we perform a systematic comparison between the line ratio ${\mathit{}}_{12/13}\equiv I{[}^{12}\mathrm{CO}(J=1\to 0)\left]/I{[}^{13}\mathrm{CO}\right(J=1\to 0\left)\right]$and the properties of the stars and ionized gas. Higher ${\mathit{}}_{12/13}$values are found in interacting galaxies compared to those in noninteracting galaxies. The global ${\mathit{}}_{12/13}$slightly increases with infrared colorF₆₀/F₁₀₀but appears insensitive to other host-galaxy properties such as morphology, stellar mass, or galaxy size. We also present azimuthally averaged ${\mathit{}}_{12/13}$profiles for our sample up to a galactocentric radius of 0.4r₂₅(∼6 kpc), taking into account the¹³CO nondetections by spectral stacking. The radial profiles of ${\mathit{}}_{12/13}$are quite flat across our sample. Within galactocentric distances of 0.2r₂₅, the azimuthally averaged ${\mathit{}}_{12/13}$increases with the star formation rate. However, Spearman rank correlation tests show the azimuthally averaged ${\mathit{}}_{12/13}$does not strongly correlate with any other gas or stellar properties in general, especially beyond 0.2r₂₅from the galaxy centers. Our findings suggest that in the complex environments in galaxy disks, ${\mathit{}}_{12/13}$is not a sensitive tracer for ISM properties. Dynamical disturbances, like galaxy interactions or the presence of a bar, also have an overall impact on ${\mathit{}}_{12/13}$, which further complicates the interpretations of ${\mathit{}}_{12/13}$variations. 

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4. Characterizing the fundamental bending vibration of a linear polyatomic molecule for symmetry violation searches

   https://doi.org/10.1088/1367-2630/ace471  

   Jadbabaie, Arian; Takahashi, Yuiki; Pilgram, Nickolas H; Conn, Chandler J; Zeng, Yi; Zhang, Chi; Hutzler, Nicholas R (July 2023, New Journal of Physics)

   Abstract Polyatomic molecules have been identified as sensitive probes of charge-parity violating and parity violating physics beyond the Standard Model (BSM). For example, many linear triatomic molecules are both laser-coolable and have parity doublets in the ground electronic $\tilde{X}{}^2{\mathrm{\Sigma }}^{+}\left(010\right)$state arising from the bending vibration, both features that can greatly aid BSM searches. Understanding the $\tilde{X}{}^2{\mathrm{\Sigma }}^{+}\left(010\right)$state is a crucial prerequisite to precision measurements with linear polyatomic molecules. Here, we characterize the fundamental bending vibration of ${}^{174}$YbOH using high-resolution optical spectroscopy on the nominally forbidden $\tilde{X}{}^2{\mathrm{\Sigma }}^{+}\left(010\right)$ $\to \tilde{A}{}^2{\mathrm{\Pi }}_{1/2}\left(000\right)$transition at 588 nm. We assign 39 transitions originating from the lowest rotational levels of the $\tilde{X}{}^2{\mathrm{\Sigma }}^{+}\left(010\right)$state, and accurately model the state’s structure with an effective Hamiltonian using best-fit parameters. Additionally, we perform Stark and Zeeman spectroscopy on the $\tilde{X}{}^2{\mathrm{\Sigma }}^{+}\left(010\right)$state and fit the molecule-frame dipole moment to $D_{\mathrm{m}\mathrm{o}\mathrm{l}}=2.16\left(1\right)$Dand the effective electrong-factor to $g_S=2.07\left(2\right)$. Further, we use an empirical model to explain observed anomalous line intensities in terms of interference from spin–orbit and vibronic perturbations in the excited $\tilde{A}{}^2{\mathrm{\Pi }}_{1/2}\left(000\right)$state. Our work is an essential step toward searches for BSM physics in YbOH and other linear polyatomic molecules. 

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5. Deciphering the sensitivity of urban canopy air temperature to anthropogenic heat flux with a forcing-feedback framework

   https://doi.org/10.1088/1748-9326/ace7e0  

   Wang, Linying; Sun, Ting; Zhou, Wenyu; Liu, Maofeng; Li, Dan (August 2023, Environmental Research Letters)

   Abstract The sensitivity of urban canopy air temperature ( $T_a$) to anthropogenic heat flux ( $Q_{AH}$) is known to vary with space and time, but the key factors controlling such spatiotemporal variabilities remain elusive. To quantify the contributions of different physical processes to the magnitude and variability of $\mathrm{\Delta }{T}_a/\mathrm{\Delta }{Q}_{AH}$(where $\mathrm{\Delta }$represents a change), we develop a forcing-feedback framework based on the energy budget of air within the urban canopy layer and apply it to diagnosing $\mathrm{\Delta }{T}_a/\mathrm{\Delta }{Q}_{AH}$simulated by the Community Land Model Urban over the contiguous United States (CONUS). In summer, the median $\mathrm{\Delta }{T}_a/\mathrm{\Delta }{Q}_{AH}$is around 0.01 $\text{K\hspace{0.17em}}{\left(\text{W\hspace{0.17em}}{\text{m}}^{-\text{2}}\right)}^{-1}$over the CONUS. Besides the direct effect of $Q_{AH}$on $T_a$, there are important feedbacks through changes in the surface temperature, the atmosphere–canopy air heat conductance ( $c_a$), and the surface–canopy air heat conductance. The positive and negative feedbacks nearly cancel each other out and $\mathrm{\Delta }{T}_a/\mathrm{\Delta }{Q}_{AH}$is mostly controlled by the direct effect in summer. In winter, $\mathrm{\Delta }{T}_a/\mathrm{\Delta }{Q}_{AH}$becomes stronger, with the median value increased by about 20% due to weakened negative feedback associated with $c_a$. The spatial and temporal (both seasonal and diurnal) variability of $\mathrm{\Delta }{T}_a/\mathrm{\Delta }{Q}_{AH}$as well as the nonlinear response of $\mathrm{\Delta }{T}_a$to $\mathrm{\Delta }{Q}_{AH}$are strongly related to the variability of $c_a$, highlighting the importance of correctly parameterizing convective heat transfer in urban canopy models. 

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