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ABSTRACT Determining the level of chemical complexity within dense starless and gravitationally bound pre-stellar cores is crucial for constructing chemical models, which subsequently constrain the initial chemical conditions of star formation. We have searched for complex organic molecules (COMs) in the young starless core L1521E, and report the first clear detection of dimethyl ether (CH3OCH3), methyl formate (HCOOCH3), and vinyl cyanide (CH2CHCN). Eight transitions of acetaldehyde (CH3CHO) were also detected, five of which (A states) were used to determine an excitation temperature to then calculate column densities for the other oxygen-bearing COMs. If source size was not taken into account (i.e. if filling fraction was assumed to be one), column density was underestimated, and thus we stress the need for higher resolution mapping data. We calculated L1521E COM abundances and compared them to other stages of low-mass star formation, also finding similarities to other starless/pre-stellar cores, suggesting related chemical evolution. The scenario that assumes formation of COMs in gas-phase reactions between precursors formed on grains and then ejected to the cold gas via reactive desorption was tested and was unable to reproduce observed COM abundances, with the exception of CH3CHO. These results suggest that COMs observed in cold gas are formed not by gas-phase reactions alone, but also through surface reactions on interstellar grains. Our observations present a new, unique challenge for existing theoretical astrochemical models.
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Survey of complex organic molecules in starless and pre-stellar cores in the Perseus molecular cloud
ABSTRACT Cold ($$\sim$$10 K) and dense ($$\sim 10^{5}$$ cm$$^{-3}$$) cores of gas and dust within molecular clouds, known as starless and dynamically evolved pre-stellar cores, are the birthplaces of low-mass (M$$\le$$ few M$$_\odot$$) stars. As detections of interstellar complex organic molecules, or COMs, in starless cores has increased, abundance comparisons suggest that some COMs might be seeded early in the star formation process and inherited to later stages (i.e. protostellar discs and eventually comets). To date observations of COMs in starless cores have been limited, with most detections reported solely in the Taurus molecular cloud. It is therefore still a question whether different environments affect abundances. We have surveyed 35 starless and pre-stellar cores in the Perseus molecular cloud with the Arizona Radio Observatory (ARO) 12 m telescope detecting both methanol, CH$$_3$$OH, and acetaldehyde, CH$$_3$$CHO, in 100 per cent and 49 per cent of the sample, respectively. In the sub-sample of 15 cores where CH$$_3$$CHO was detected at $$\gt 3\sigma$$ ($$\sim$$18 mK) with the ARO 12 m, follow-up observations with the Yebes 40 m telescope were carried out. Detections of formic acid, t-HCOOH, ketene, H$$_2$$CCO, methyl cyanide, CH$$_3$$CN, vinyl cyanide, CH$$_2$$CHCN, methyl formate, HCOOCH$$_3$$, and dimethyl ether, CH$$_3$$OCH$$_3$$, are seen in at least 20 per cent of the cores. We discuss detection statistics, calculate column densities, and compare abundances across various stages of low-mass star formation. Our findings have more than doubled COM detection statistics in cold cores and show COMs are prevalent in the gas before star and planet formation in the Perseus molecular cloud.
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- PAR ID:
- 10556524
- Publisher / Repository:
- RAS
- Date Published:
- Journal Name:
- Monthly Notices of the Royal Astronomical Society
- Volume:
- 533
- Issue:
- 4
- ISSN:
- 0035-8711
- Page Range / eLocation ID:
- 4104 to 4149
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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ABSTRACT Two closely related isomeric pairs of cyanides, CH3[CN/NC] and H2C[CN/NC], are studied in cold, dark interstellar cloud conditions. In contrast to the diverse detections of methyl cyanide (CH3CN) in space, methyl isocyanide (CH3NC) has previously only been observed in warm and hot star-forming regions. We report the detection of CH3NC in the cold pre-stellar core Taurus Molecular Cloud (TMC-1) using the Green Bank Telescope with a detection significance of 13.4σ. Hyperfine transitions in H2CCN and quadrupole interactions in CH3CN and CH3NC were matched to a spectral line survey from the Green Bank Telescope Observations of TMC-1: Hunting for Aromatic Molecules large project on the Green Bank Telescope, resulting in abundances with respect to hydrogen of $$1.92^{+0.13}_{-0.07} \times 10^{-9}$$ for the cyanomethyl radical (H2CCN), $$5.02^{+3.08}_{-2.06} \times 10^{-10}$$ for CH3CN, and $$2.97^{+2.10}_{-1.37} \times 10^{-11}$$ for CH3NC. Efforts to model these molecules with the three-phase gas-grain code nautilus in TMC-1 conditions overproduce both CH3CN and CH3NC, though the ratio of ∼5.9 per cent is consistent across observations and models of these species. This may point to missing destruction routes in the model. The models capture the larger abundance of H2CCN well. Dissociative recombination is found to be the primary production route for these molecules, and reactions with abundant ions are found to be the primary destruction routes. H + CH3NC is investigated with transition state theory as a potential destruction route, but found to be too slow in cold cloud conditions to account for the discrepancy in modelled and observed abundances of CH3NC.more » « less
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- Free Publicly Accessible Full Text
-
Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1093/mnras/stae2017
