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1. Generalized T _e ([O iii ])– T _e (He i ) Discrepancies in Ionized Nebulae: Possible Evidence of Case B Deviations and Temperature Inhomogeneities

   https://doi.org/10.3847/1538-4357/adc67a  

   Méndez-Delgado, J E; Skillman, E D; Aver, E; Morisset, C; Esteban, C; García-Rojas, J; Kreckel, K; Rogers, N_S J; Rosales-Ortega, F F; Arellano-Córdova, K Z; et al (June 2025, The Astrophysical Journal)

   Abstract The physics of recombination lines in the Heisinglet system is expected to be relatively simple, supported by accurate atomic models. We examine the intensities of Heisingletsλ3614, λ3965, λ5016, λ6678, and λ7281 and the triplet Heiλ5876 in various types of ionized nebulae and compare them with theoretical predictions to test the validity of the “Case B” recombination scenario and the assumption of thermal homogeneity. Our analysis includes 85 spectra from Galactic and extragalactic Hiiregions, 90 from star-forming galaxies, and 218 from planetary nebulae, all compiled by the Deep Spectra of Ionized Regions Database Extended (DESIRED-E) project. By evaluating the ratios Heiλ7281/λ6678 and Heiλ7281/λ5876, we determineT_e(Hei) and compare it with direct measurements ofT_e([Oiii]λ4363/λ5007). We find thatT_e(Hei) is systematically lower thanT_e([Oiii]) across most objects and nebula types. Additionally, we identify a correlation between the abundance discrepancy factor (ADF(O²⁺)) and the differenceT_e([Oiii]) –T_e(Hei) for planetary nebulae. We explore two potential explanations: photon loss fromn¹P → 1¹Stransitions and temperature inhomogeneities. Deviations from “Case B” may indicate photon absorption by Hirather than Heiand/or generalized ionizing photon escape, highlighting the need for detailed consideration of radiative transfer effects. If temperature inhomogeneities are widespread, identifying a common physical phenomenon affecting all ionized nebulae is crucial. Our results suggest that both scenarios can contribute to the observed discrepancies. 

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2. Identifying charge-transfer and trip–multiplet states in Co( i ), Co( ii ), and Co( iii ) phthalocyanines using (magneto)optical spectroscopy and (TD)DFT calculations

   https://doi.org/10.1039/d5dt00628g  

   Muldowney, Breanna E; Nevonen, Dustin E; Jeaydi, Towhidi Illius; Ziegler, Christopher J; McNicholas, Brendon J; Nemykin, Victor N (January 2025, Dalton Transactions)

   The electronic structures, charge-transfer, and triplet–multiplet transitions in cobalt(i), cobalt(ii), and cobalt(iii) phthalocyanines were investigated in detail by UV-vis-NIR, MCD, DFT, and TDDFT methods. 

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3. H i Properties of Field Galaxies at z  ≈ 0.2–0.6: Insights into Declining Cosmic Star Formation

   https://doi.org/10.3847/2041-8213/ae0d8b  

   DePalma, David; Gupta, Neeraj; Chen, Hsiao-Wen; Simcoe, Robert A; Balashev, Sergei; Boettcher, Erin; Cantalupo, Sebastiano; Chen, Mandy C; Combes, Françoise; Faucher-Giguère, Claude-André; et al (October 2025, The Astrophysical Journal Letters)

   Abstract We report statistically significant detection of Hi21 cm emission from intermediate-redshift (z ≈ 0.2–0.6) galaxies. By leveraging multisightline galaxy survey data from the Cosmic Ultraviolet Baryon Survey and deep radio observations from the MeerKAT Absorption Line Survey, we have established a sample of ≈6000 spectroscopically identified galaxies in 11 distinct fields to constrain the neutral gas content at intermediate redshifts. The galaxies sample a broad range in stellar mass, from $\log M_{\mathrm{star}}/M_{\odot }\approx 8$to $\log M_{\mathrm{star}}/M_{\odot }\approx 11$, with a median of ${〈\log M_{\mathrm{star}}/M_{\odot }〉}_{\mathrm{med}}\approx 10$and a wide range in redshift fromz ≈ 0.24 toz ≈ 0.63 with a median of 〈z〉_med = 0.44. While no individual galaxies show detectable Hiemission, the emission line signal is detected in the stacked spectra of all subsamples at greater than 4σsignificance. The observed total Hi21 cm line flux translates to a Himass,M_{H I}≈10¹⁰M_⊙. We find a high Hi-to-stellar-mass ratio ofM_HI/M_star ≈ 6 for low-mass galaxies with $〈\log M_{\mathrm{star}}/M_{\odot }〉\approx 9.3$(>3.7σ). For galaxies with $〈\log M_{\mathrm{star}}/M_{\odot }〉\approx 10.6$, we findM_HI/M_star ≈ 0.3 (>4.7σ). In addition, the redshift evolution of Himass, 〈M_{H I}〉, in both low- and high-mass field galaxies, inferred from the stacked emission-line signal, aligns well with the expectation from the cosmic star formation history. This suggests that the overall decline in the cosmic star formation activity across the general galaxy population may be connected to a decreasing supply of neutral hydrogen. Finally, our analysis has revealed significant 21 cm signals at distances greater than 75 kpc from these intermediate-redshift galaxies, indicating a substantial reservoir of Higas in their extended surroundings. 

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4. Selective hydrosilylation of olefins by a two-dimensional Rh( i ) low-valent metal–organic framework

   https://doi.org/10.1039/D5CC02201K  

   Mandal, Dipendu; Esposito, Madison R; Griffin, Samuel E; Domecus, Grant P; Cohen, Seth M (July 2025, Chemical Communications)

   Multitopic phosphine ligands combined with Rh(i) or Ir(i) nodes assemble into low-valent metal–organic frameworks (LVMOFs) with a two-dimensional (2D) topology and catalytic activity. 

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5. The Qz5 Survey. I. How the H i Mass Density of the Universe Evolves with Cosmic Time

   https://doi.org/10.3847/1538-4357/adb430  

   Oyarzún, Grecco A; Rafelski, Marc; Christensen, Lise; Ozyurt, Fiona; Jorgenson, Regina A; Neeleman, M; Fumagalli, Michele; Prochaska, J Xavier; Worseck, G; Wisz, M E; et al (April 2025, The Astrophysical Journal)

   Abstract We report that the neutral hydrogen (Hi) mass density of the Universe (ρ_Hi) increases with cosmic time sincez ∼ 5, peaks atz ∼ 3, and then decreases towardz ∼ 0. This is the first result of Qz5, our spectroscopic survey of 63 quasars atz ≳ 5 with VLT/X-SHOOTER and Keck/ESI aimed at characterizing intervening Higas absorbers atz ∼ 5. The main feature of Qz5 is the high resolution (R ∼ 7000–9000) of the spectra, which allows us to (1) accurately detect high column density Higas absorbers in an increasingly neutral intergalactic medium atz ∼ 5 and (2) determine the reliability of previousρ_Himeasurements derived with lower resolution spectroscopy. We find five intervening damped Lyαabsorbers (DLAs) atz > 4.5, which corresponds to the lowest DLA incidence rate ( $0.034_{0.02}^{0.05}$) atz ≳ 2. We also measure the lowestρ_Hiatz ≳ 2 from our sample of DLAs and subDLAs, corresponding toρ_Hi $=0.56_{0.31}^{0.82}\times 10^8{M}_{\odot }$Mpc⁻³atz ∼ 5. Taking into account our measurements atz ∼ 5 and systematic biases in the DLA detection rate at lower spectral resolutions, we conclude thatρ_Hidoubles fromz ∼ 5 toz ∼ 3. From these results emerges a qualitative agreement between how the cosmic densities of Higas mass, molecular gas mass, and star formation rate build up with cosmic time. 

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