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1. Generalized T _e ([O iii ])– T _e (He i ) Discrepancies in Ionized Nebulae: Possible Evidence of Case B Deviations and Temperature Inhomogeneities

   https://doi.org/10.3847/1538-4357/adc67a  

   Méndez-Delgado, J E; Skillman, E D; Aver, E; Morisset, C; Esteban, C; García-Rojas, J; Kreckel, K; Rogers, N_S J; Rosales-Ortega, F F; Arellano-Córdova, K Z; et al (June 2025, The Astrophysical Journal)

   Abstract The physics of recombination lines in the Heisinglet system is expected to be relatively simple, supported by accurate atomic models. We examine the intensities of Heisingletsλ3614, λ3965, λ5016, λ6678, and λ7281 and the triplet Heiλ5876 in various types of ionized nebulae and compare them with theoretical predictions to test the validity of the “Case B” recombination scenario and the assumption of thermal homogeneity. Our analysis includes 85 spectra from Galactic and extragalactic Hiiregions, 90 from star-forming galaxies, and 218 from planetary nebulae, all compiled by the Deep Spectra of Ionized Regions Database Extended (DESIRED-E) project. By evaluating the ratios Heiλ7281/λ6678 and Heiλ7281/λ5876, we determineT_e(Hei) and compare it with direct measurements ofT_e([Oiii]λ4363/λ5007). We find thatT_e(Hei) is systematically lower thanT_e([Oiii]) across most objects and nebula types. Additionally, we identify a correlation between the abundance discrepancy factor (ADF(O²⁺)) and the differenceT_e([Oiii]) –T_e(Hei) for planetary nebulae. We explore two potential explanations: photon loss fromn¹P → 1¹Stransitions and temperature inhomogeneities. Deviations from “Case B” may indicate photon absorption by Hirather than Heiand/or generalized ionizing photon escape, highlighting the need for detailed consideration of radiative transfer effects. If temperature inhomogeneities are widespread, identifying a common physical phenomenon affecting all ionized nebulae is crucial. Our results suggest that both scenarios can contribute to the observed discrepancies. 

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2. Identifying charge-transfer and trip–multiplet states in Co( i ), Co( ii ), and Co( iii ) phthalocyanines using (magneto)optical spectroscopy and (TD)DFT calculations

   https://doi.org/10.1039/d5dt00628g  

   Muldowney, Breanna E; Nevonen, Dustin E; Jeaydi, Towhidi Illius; Ziegler, Christopher J; McNicholas, Brendon J; Nemykin, Victor N (January 2025, Dalton Transactions)

   The electronic structures, charge-transfer, and triplet–multiplet transitions in cobalt(i), cobalt(ii), and cobalt(iii) phthalocyanines were investigated in detail by UV-vis-NIR, MCD, DFT, and TDDFT methods. 

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3. The Qz5 Survey. I. How the H i Mass Density of the Universe Evolves with Cosmic Time

   https://doi.org/10.3847/1538-4357/adb430  

   Oyarzún, Grecco A; Rafelski, Marc; Christensen, Lise; Ozyurt, Fiona; Jorgenson, Regina A; Neeleman, M; Fumagalli, Michele; Prochaska, J Xavier; Worseck, G; Wisz, M E; et al (April 2025, The Astrophysical Journal)

   Abstract We report that the neutral hydrogen (Hi) mass density of the Universe (ρ_Hi) increases with cosmic time sincez ∼ 5, peaks atz ∼ 3, and then decreases towardz ∼ 0. This is the first result of Qz5, our spectroscopic survey of 63 quasars atz ≳ 5 with VLT/X-SHOOTER and Keck/ESI aimed at characterizing intervening Higas absorbers atz ∼ 5. The main feature of Qz5 is the high resolution (R ∼ 7000–9000) of the spectra, which allows us to (1) accurately detect high column density Higas absorbers in an increasingly neutral intergalactic medium atz ∼ 5 and (2) determine the reliability of previousρ_Himeasurements derived with lower resolution spectroscopy. We find five intervening damped Lyαabsorbers (DLAs) atz > 4.5, which corresponds to the lowest DLA incidence rate ( $0.034_{0.02}^{0.05}$) atz ≳ 2. We also measure the lowestρ_Hiatz ≳ 2 from our sample of DLAs and subDLAs, corresponding toρ_Hi $=0.56_{0.31}^{0.82}\times 10^8{M}_{\odot }$Mpc⁻³atz ∼ 5. Taking into account our measurements atz ∼ 5 and systematic biases in the DLA detection rate at lower spectral resolutions, we conclude thatρ_Hidoubles fromz ∼ 5 toz ∼ 3. From these results emerges a qualitative agreement between how the cosmic densities of Higas mass, molecular gas mass, and star formation rate build up with cosmic time. 

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4. “This or that” – light emission from hybrid organic–inorganic vs. coordination Cu( i ) halides

   https://doi.org/10.1039/D4TC04153D  

   Popy, Dilruba A; Saparov, Bayram (January 2025, Journal of Materials Chemistry C)

   This review clarifies the confusion regarding similarities and differences between the photoluminescent hybrid organic–inorganic and coordination Cu(i) halides, including their crystal and electronic structures, and optical properties. 

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5. Toward Robustness across Cosmological Simulation Models I llustris TNG, SIMBA, A strid , and S wift -E agle

   https://doi.org/10.3847/1538-4357/adec78  

   Jo, Yongseok; Genel, Shy; Sengupta, Anirvan; Wandelt, Benjamin; Somerville, Rachel; Villaescusa-Navarro, Francisco (September 2025, The Astrophysical Journal)

   Abstract The rapid advancement of large-scale cosmological simulations has opened new avenues for cosmological and astrophysical research. However, the increasing diversity among cosmological simulation models presents a challenge to therobustness. In this work, we develop the Model-Insensitive ESTimator (Miest), a machine that canrobustlyestimate the cosmological parameters, Ω_mandσ₈, from neural hydrogen maps of simulation models in the Cosmology and Astrophysics with MachinE Learning Simulations project—IllustrisTNG,SIMBA, Astrid, and SWIFT-Eagle. An estimator is consideredrobustif it possesses a consistent predictive power across all simulations, including those used during the training phase. We train our machine using multiple simulation models and ensure that it only extracts common features between the models while disregarding the model-specific features. This allows us to develop a novel model that is capable of accurately estimating parameters across a range of simulation models, without being biased toward any particular model. Upon the investigation of the latent space—a set of summary statistics, we find that the implementation ofrobustnessleads to the blending of latent variables across different models, demonstrating the removal of model-specific features. In comparison to a standard machine lackingrobustness, the average performance of Mieston the unseen simulations during the training phase has been improved by ∼17% for Ω_mand 38% forσ₈. By using a machine learning approach that can extractrobust, yet physical features, we hope to improve our understanding of galaxy formation and evolution in a (subgrid) model-insensitive manner, and ultimately, gain insight into the underlying physical processes responsible forrobustness. 

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