skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: An Isotope Mass Balance Analysis of Evaporative Loss From Lake Turkana, Kenya Using δ 18 O and δD of Natural Waters
Abstract Measurements of oxygen and hydrogen stable isotope ratios (δ18O and δD) in meteoric waters provide insight to overlapping effects of evaporation, precipitation, and mixing on basin scale hydrology. This study of waters collected between 2016 and 2021 in the Turkana Basin, northern Kenya, uses δ18O and δD to understand water balance in Lake Turkana, a large, low‐latitude, alkaline desert lake. The Omo River, a major river system in the Ethiopian Highlands, is historically understood to provide approximately 90% of the water input to Lake Turkana. Discharge of the Omo is prohibitively difficult to measure, but stable isotope ratios in the lake may provide a meaningful method for monitoring the lake's response to changes in input. Precipitation in the Turkana Basin is low (<200 mm/year) with negligible rainfall on the lake's surface, and all water loss from the lake is evaporative. We compare new measurements with previous data from the region and records of lake height and precipitation from the same time period. We show that a Bayesian approach to modeling evaporation using atmospheric conditions and river δ18O and δD yields results consistent with published water balance models. Continued sampling of lake and meteoric waters in the Turkana Basin will be a useful way to monitor the lake's response to regional and global climate change.  more » « less
Award ID(s):
2325048 2021579
PAR ID:
10557167
Author(s) / Creator(s):
; ; ; ;
Publisher / Repository:
American Geophysical Union
Date Published:
Journal Name:
Water Resources Research
Volume:
60
Issue:
6
ISSN:
0043-1397
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Abstract Freshwater lakes are vital water resources, especially in the context of a changing climate. Supplementing existing hydrological methods to monitor lake levels may greatly improve resource management, particularly in drought‐prone regions. In this study, we performed dual‐isotope (δ18O and δ2H) calculations to model the hydrological balance of Bear Lake, Utah‐Idaho. The lake is a critical water resource and site for paleoclimate studies of the latest Pleistocene. Using the Craig‐Gordon isotopic mass balance model, we simultaneously constrained unknown fluxes, including groundwater discharge and particularly evaporation, which is typically under‐constrained due to inconsistencies across existing methods. Data from community databases and sampling campaigns in 2022 and 2023 were utilized to derive an evaporation rate of 2.18 × 108 m3/yr (±4.94 × 106 m3/yr, 1σ using δ18O; ±3.47 × 106 m3/yr, 1σ using δ2H) at a calculated relative humidity of 0.62 above the lake. Detailed analysis of the sensitivity of the model revealed that parameters related to atmospheric moisture, particularly humidity and its isotopic composition, significantly influence evaporation estimates. Using carbonate‐based isotope data, we leveraged this sensitivity to provide insights in the evaporation and humidity at Bear Lake during different time periods. This study shows the potential of using modern water isotopic composition to aid with interpreting carbonate‐based paleoclimate data sets and informing current and future water resource management practices. 
    more » « less
  2. Abstract Global climate during the Holocene was relatively stable compared to the late Pleistocene. However, evidence from lacustrine records in South America suggests that tropical latitudes experienced significant water balance variability during the Holocene, rather than quiescence. For example, a tight coupling between insolation and carbonate δ18O records from central Andean lakes (e.g., Lakes Junín, Pumacocha) suggest water balance is tied directly to South American summer monsoon (SASM) strength. However, lake carbonate δ18O records also incorporate information about temperature and evaporation. To overcome this ambiguity, clumped and triple oxygen isotope records can provide independent constraints on temperature and evaporation. Here, we use clumped and triple oxygen isotopes to develop Holocene temperature and evaporation records from three central Andean lakes, Lakes Junín, Pumacocha, and Mehcocha, to build a more complete picture of regional water balance (P–E). We find that Holocene water temperatures at all three lakes were stable and slightly warmer than during the latest Pleistocene. These results are consistent with global data assimilations and records from the foothills and Amazon basin. In contrast, evaporation was highly variable and tracks SASM intensity. The hydrologic response of each lake to SASM depends greatly on the physical characteristics of the lake basin, but they all record peak evaporation in the early to mid‐Holocene (11,700 to 4,200 years BP) when regional insolation was relatively low and the SASM was weak. These results corroborate other central Andean records and suggest synchronous, widespread water stress tracks insolation‐paced variability in SASM strength. 
    more » « less
  3. Oxygen and hydrogen stable isotope analyses of quartz and muscovite veins from the footwall of the Raft River detachment shear zone (Utah) provide insight into the hydrology and fluid‐rock interactions during ductile deformation. Samples were collected from veins containing 90%–100% quartz with orientations either at a high angle or sub‐parallel to the surrounding quartzite mylonite foliation. Stable isotope analysis was performed on 10 samples and compared with previous quartzite mylonite isotope data sets. The results indicate that the fluid present during deformation of the shear zone was meteoric in origin, with a δ2H value of approximately −100‰ and a δ18O value of approximately −13.7‰. Oxygen stable isotope O18O depletion correlates with the muscovite content of the analyzed rocks. Many of the analyzed samples in this and other studies show an apparent lack of equilibrium between the oxygen and hydrogen isotope systems, which can be explained by hydrogen and oxygen isotope exchange at varying fluid‐rock ratios. Our results suggest that the Raft River detachment shear zone had a low static fluid‐rock ratio (<0.1), yet experienced episodic influxes of fluids through semi‐brittle structures. This fluid was then expelled out into the surrounding mylonite following progressive shearing, causing further18O‐depletion and fluid‐related embrittlement. 
    more » « less
  4. The past elevation of the land surface provides a unique constraint on the underlying lithospheric structure during mountain and plateau formation. Development of new paleoaltimetry techniques that can be applied to a wide variety of sample types is therefore of continuing importance. This study evaluates organic substrates that preserve the δD ratio of surface waters as a new approach to reconstruct paleoaltimetry. We measured the hydrogen isotope composition of n-alkanes from epicuticular plant waxes preserved in lacustrine deposits to reconstruct the δD of precipitation in Cenozoic basins that have been elevated as part of the Tibetan Plateau. n-Alkane δD- and carbonate δ18O-inferred water compositions from the Eocene–Miocene Lunpola Basin and Miocene Hoh-Xil Basin plot near or at enriched values relative to the global meteoric water line, as expected for evaporative lakewater and leafwater systems that have the same precipitation source. n-Alkane δD-based water compositions are nearly identical to the minimum carbonate δ18O-based values, demonstrating that plant-wax δD is minimally affected by evaporation compared to lacustrine calcite δ18O. This agreement strongly supports the presence of similar precipitation isotopic compositions in both archives despite different isotope systems, source water reservoirs, archive materials, modes of incorporation, and diagenetic processes. Paleoelevations for each basin and time period were calculated from precipitation isotope ratios using the isotope–altitude relationship derived from both a simple thermodynamic model and modern precipitation sampling from the Plateau region. Our new results from the Hoh-Xil Basin suggest 1700 to 2600 m of uplift may have occurred some time between the late Eocene and early Miocene. The timing of this uplift is consistent with late-Oligocene compressional deformation of the Hoh-Xil Basin and northward growth of the Tibetan Plateau however, the calculated uplift is not a unique solution from the paleoisotope data because of uncertainties in Eocene and Miocene moisture sources and isotope gradients for the northern plateau. Our results demonstrate the utility of lipid-based estimates of paleoelevation and expand the types of deposits amenable to paleoaltimetry analysis. 
    more » « less
  5. Abstract Tropical Pacific seawater and precipitation stable oxygen isotope data aid in understanding modern oceanic and atmospheric interactions, and these data are particularly valuable as they are archived in isotope‐based paleoclimate records. However, the absence of modern seawater isotope time series limits the ability to identify the atmospheric influences on these data, precluding robust paleoclimate interpretations. We present a new 10 year sub‐monthly record of seawater and precipitation stable oxygen isotope values (δ18Oswand δ18Op) from Koror, Palau. Our dataset indicates that temporally, δ18Oswis strongly influenced by local δ18Op.Both monthly δ18Oswand δ18Opare highly correlated with outgoing longwave radiation across the tropical Pacific, reflecting a Walker Circulation imprint on the surface ocean. Changes in the Palau δ18Osw—salinity relationship correspond to NINO3.4 variability, indicating a difference in how these variables record El Niño Southern Oscillation (ENSO) information, but demonstrating the utility of δ18Oswto reconstruct ENSO variability in the western tropical Pacific. 
    more » « less