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1. Characterizing the fundamental bending vibration of a linear polyatomic molecule for symmetry violation searches

   https://doi.org/10.1088/1367-2630/ace471  

   Jadbabaie, Arian; Takahashi, Yuiki; Pilgram, Nickolas H; Conn, Chandler J; Zeng, Yi; Zhang, Chi; Hutzler, Nicholas R (July 2023, New Journal of Physics)

   Abstract Polyatomic molecules have been identified as sensitive probes of charge-parity violating and parity violating physics beyond the Standard Model (BSM). For example, many linear triatomic molecules are both laser-coolable and have parity doublets in the ground electronic $\tilde{X}{}^2{\mathrm{\Sigma }}^{+}\left(010\right)$state arising from the bending vibration, both features that can greatly aid BSM searches. Understanding the $\tilde{X}{}^2{\mathrm{\Sigma }}^{+}\left(010\right)$state is a crucial prerequisite to precision measurements with linear polyatomic molecules. Here, we characterize the fundamental bending vibration of ${}^{174}$YbOH using high-resolution optical spectroscopy on the nominally forbidden $\tilde{X}{}^2{\mathrm{\Sigma }}^{+}\left(010\right)$ $\to \tilde{A}{}^2{\mathrm{\Pi }}_{1/2}\left(000\right)$transition at 588 nm. We assign 39 transitions originating from the lowest rotational levels of the $\tilde{X}{}^2{\mathrm{\Sigma }}^{+}\left(010\right)$state, and accurately model the state’s structure with an effective Hamiltonian using best-fit parameters. Additionally, we perform Stark and Zeeman spectroscopy on the $\tilde{X}{}^2{\mathrm{\Sigma }}^{+}\left(010\right)$state and fit the molecule-frame dipole moment to $D_{\mathrm{m}\mathrm{o}\mathrm{l}}=2.16\left(1\right)$Dand the effective electrong-factor to $g_S=2.07\left(2\right)$. Further, we use an empirical model to explain observed anomalous line intensities in terms of interference from spin–orbit and vibronic perturbations in the excited $\tilde{A}{}^2{\mathrm{\Pi }}_{1/2}\left(000\right)$state. Our work is an essential step toward searches for BSM physics in YbOH and other linear polyatomic molecules. 

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2. The metastable Q ³ Δ ₂ state of ThO: a new resource for the ACME electron EDM search

   https://doi.org/10.1088/1367-2630/ab6a3a  

   Wu, X.; Han, Z.; Chow, J.; Ang, D. G.; Meisenhelder, C.; Panda, C. D.; West, E. P.; Gabrielse, G.; Doyle, J. M.; DeMille, D. (February 2020, New Journal of Physics)

   Abstract The best upper limit for the electron electric dipole moment was recently set by the ACME collaboration. This experiment measures an electron spin-precession in a cold beam of ThO molecules in their metastable $H{(}^3{\mathrm{\Delta }}_1)$state. Improvement in the statistical and systematic uncertainties is possible with more efficient use of molecules from the source and better magnetometry in the experiment, respectively. Here, we report measurements of several relevant properties of the long-lived $Q{(}^3{\mathrm{\Delta }}_2)$state of ThO, and show that this state is a very useful resource for both these purposes. TheQstate lifetime is long enough that its decay during the time of flight in the ACME beam experiment is negligible. The large electric dipole moment measured for theQstate, giving rise to a large linear Stark shift, is ideal for an electrostatic lens that increases the fraction of molecules detected downstream. The measured magnetic moment of theQstate is also large enough to be used as a sensitive co-magnetometer in ACME. Finally, we show that theQstate has a large transition dipole moment to the $C{(}^1{\mathrm{\Pi }}_1)$state, which allows for efficient population transfer between the ground state $X{(}^1{\mathrm{\Sigma }}^{+})$and theQstate via $X-C-Q$Stimulated Raman Adiabatic Passage (STIRAP). We demonstrate 90 % STIRAP transfer efficiency. In the course of these measurements, we also determine the magnetic moment ofCstate, the $X\to C$transition dipole moment, and branching ratios of decays from theCstate. 

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3. Instantons and the large $N=4$ algebra

   https://doi.org/10.1088/1751-8121/ada64d  

   Witten, Edward (January 2025, Journal of Physics A: Mathematical and Theoretical)

   Abstract We investigate the differential geometry of the moduli space of instantons on ${\mathrm{S}}^3\times {\mathrm{S}}^1$. Extending previous results, we show that a sigma-model with this target space can be expected to possess a large $N=4$superconformal symmetry, supporting speculations that this sigma-model may be dual to Type IIB superstring theory on ${\mathrm{AdS}}_3\times {\mathrm{S}}^3\times {\mathrm{S}}^3\times {\mathrm{S}}^1$. The sigma-model is parametrized by three integers—the rank of the gauge group, the instanton number, and a ‘level’ (the integer coefficient of a topologically nontrivialB-field, analogous to a WZW level). These integers are expected to correspond to two five-brane charges and a one-brane charge. The sigma-model is weakly coupled when the level, conjecturally corresponding to one of the five-brane changes, becomes very large, keeping the other parameters fixed. The central charges of the large $N=4$algebra agree, at least semiclassically, with expectations from the duality. 

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4. Sharp decay rate for eigenfunctions of perturbed periodic Schrödinger operators

   https://doi.org/10.1088/1361-6544/adc653  

   Liu, Wencai; Matos, Rodrigo; Treuer, John N (April 2025, Nonlinearity)

   Abstract This paper investigates uniqueness results for perturbed periodic Schrödinger operators on ${\mathbb{Z}}^d$. Specifically, we consider operators of the form $H=-\mathrm{\Delta }+V+v$, where Δ is the discrete Laplacian, $V:{\mathbb{Z}}^d\to \mathbb{R}$is a periodic potential, and $v:{\mathbb{Z}}^d\to \mathbb{C}$represents a decaying impurity. We establish quantitative conditions under which the equation $-\mathrm{\Delta }u+Vu+vu=\lambda u$, for $\lambda \in \mathbb{C}$, admits only the trivial solution $u\equiv 0$. Key applications include the absence of embedded eigenvalues for operators with impurities decaying faster than any exponential function and the determination of sharp decay rates for eigenfunctions. Our findings extend previous works by providing precise decay conditions for impurities and analyzing different spectral regimes ofλ. 

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5. Efficient pathway to NaCs ground state molecules

   https://doi.org/10.1088/1367-2630/acd411  

   Warner, Claire; Bigagli, Niccolò; Lam, Aden Z.; Yuan, Weijun; Zhang, Siwei; Stevenson, Ian; Will, Sebastian (June 2023, New Journal of Physics)

   Abstract We present a study of two-photon pathways for the transfer of NaCs molecules to their rovibrational ground state. Starting from NaCs Feshbach molecules, we perform bound-bound excited state spectroscopy in the wavelength range from 900 nm to 940 nm, covering more than 30 vibrational states of the $c^3{\mathrm{\Sigma }}^{+}$, $b^3\mathrm{\Pi }$, and $B^1\mathrm{\Pi }$electronic states. Analyzing the rotational substructure, we identify the highly mixed $c^3{\mathrm{\Sigma }}_1^{+}|v=22⟩\sim b^3{\mathrm{\Pi }}_1|v=54⟩$state as an efficient bridge for stimulated Raman adiabatic passage. We demonstrate transfer into the NaCs ground state with an efficiency of up to 88(4)%. Highly efficient transfer is critical for the realization of many-body quantum phases of strongly dipolar NaCs molecules and high fidelity detection of single molecules, for example, in spin physics experiments in optical lattices and quantum information experiments in optical tweezer arrays. 

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