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The noncentrosymmetric Weyl semimetal PtBi2−x (t-PtBi2−x) exhibits various interesting technologically important physical properties. We report the experimental investigation of PtBi1.6 via second harmonic generation (SHG), single-crystal x-ray diffraction, magnetic susceptibility, and electrical resistivity measurements. While bulk structural, magnetic, and electrical properties show no phase transitions below room temperature, the temperature dependence of the SHG intensity reveals two anomalies: one at T ∗ ∼ 60 K and another at Tx ∼ 200 K. Quantitative analysis indicates that the SHG signal results from both the buckled Bi1 surface termination with the 3m symmetry and flat Bi2 surface termination with the m symmetry. However, the anomalies are mainly driven by Bi1 on the surface: (1) T ∗ marks the onset of surface states which is also manifested in the c-axis resistivity drop and (2) Tx corresponds to the lowest thermal contraction of the structure and enhanced magnetic susceptibility. This study demonstrates that SHG is a powerful technique for probing surface properties even for noncentrosymmetric materials.
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This content will become publicly available on December 1, 2025
Evolution of the surface phase transitions in IrTe2
The phase transitions in IrTe2 have been extensively studied but the symmetry at each phase is yet to be settled. Employing second harmonic generation (SHG) measurements over a temperature range of 4 –300 K, we probe the evolution of the symmetry of IrTe2. Our results indicate shifts in two distinct transition temperatures (Ts1 and Ts2 with Ts1 > Ts2) through thermal cycling, providing an explanation for the variations of reported values in literature. The SHG polarimetry measurements identify symmetries in different temperature ranges, confirming the trigonal symmetry above Ts1, the triclinic symmetry between Ts1 and Ts2, and the coexistence of multiple stripe phases below Ts2. The most striking feature is the reemergence of a trigonal phase as reflected by six-fold symmetry below ~ 10 K which is likely responsible for phenomena observed at low temperatures.
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- Award ID(s):
- 1652720
- PAR ID:
- 10560386
- Publisher / Repository:
- Nature Portfolio
- Date Published:
- Journal Name:
- Scientific Reports
- Volume:
- 14
- Issue:
- 1
- ISSN:
- 2045-2322
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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