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1. Mercury stocks in discontinuous permafrost and their mobilization by river migration in the Yukon River Basin

   https://doi.org/10.1088/1748-9326/ad536e  

   Smith, Magdalene I; Ke, Yutian; Geyman, Emily C; Reahl, Jocelyn N; Douglas, Madison M; Seelen, Emily A; Magyar, John S; Dunne, Kieran BJ; Mutter, Edda; Fischer, Woodward W; et al (June 2024, Environmental Research Letters)

   Rapid warming in the Arctic threatens to destabilize mercury (Hg) deposits contained within soils in permafrost regions. Yet current estimates of the amount of Hg in permafrost vary by ~4 times. Moreover, how Hg will be released to the environment as permafrost thaws remains poorly known, despite threats to water quality, human health, and the environment. Here we present new measurements of total mercury (THg) contents in discontinuous permafrost in the Yukon River Basin in Alaska. We collected riverbank and floodplain sediments from exposed banks and bars near the villages of Huslia and Beaver. Median THg contents were 49+13/-21 ng THg g sediment−1 and 39 +16 /-18 ng THg g sediment−1 for Huslia and Beaver, respectively (uncertainties as 15th and 85th percentiles). Corresponding THg:organic carbon ratios were 5.4+2 /-2.4 Gg THg Pg C-1 and 4.2+2.4 /-2.9 Gg THg Pg C-1. To constrain floodplain THg stocks, we combined measured THg contents with floodplain stratigraphy. Trends of THg increasing with smaller sediment size and calculated stocks in the upper 1 m and 3 m are similar to those suggested for this region by prior pan-Arctic studies. We combined THg stocks and river migration rates derived from remote sensing to estimate particulate THg erosional and depositional fluxes as river channels migrate across the floodplain. Results show similar fluxes within uncertainty into the river from erosion at both sites (95 +12 /-47 kg THg yr-1 and 26 +154/-13 kg THg yr-1 at Huslia and Beaver, respectively), but very different fluxes out of the river via deposition in aggrading bars (60 +40/-29 kg THg yr-1 and 10+5.3/-1.7 kg THg yr-1). Thus, a significant amount of THg is liberated from permafrost during bank erosion, while a variable but generally lesser portion is subsequently redeposited by migrating rivers. 

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2. Increasing Alaskan river discharge during the cold season is driven by recent warming

   https://doi.org/10.1088/1748-9326/acb661  

   Blaskey, Dylan; Koch, Joshua C; Gooseff, Michael N; Newman, Andrew J; Cheng, Yifan; O’Donnell, Jonathan A; Musselman, Keith N (February 2023, Environmental Research Letters)

   Abstract Arctic hydrology is experiencing rapid changes including earlier snow melt, permafrost degradation, increasing active layer depth, and reduced river ice, all of which are expected to lead to changes in stream flow regimes. Recently, long-term (>60 years) climate reanalysis and river discharge observation data have become available. We utilized these data to assess long-term changes in discharge and their hydroclimatic drivers. River discharge during the cold season (October–April) increased by 10% per decade. The most widespread discharge increase occurred in April (15% per decade), the month of ice break-up for the majority of basins. In October, when river ice formation generally begins, average monthly discharge increased by 7% per decade. Long-term air temperature increases in October and April increased the number of days above freezing (+1.1 d per decade) resulting in increased snow ablation (20% per decade) and decreased snow water equivalent (−12% per decade). Compared to the historical period (1960–1989), mean April and October air temperature in the recent period (1990–2019) have greater correlation with monthly discharge from 0.33 to 0.68 and 0.0–0.48, respectively. This indicates that the recent increases in air temperature are directly related to these discharge changes. Ubiquitous increases in cold and shoulder-season discharge demonstrate the scale at which hydrologic and biogeochemical fluxes are being altered in the Arctic. 

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3. Arctic Permafrost Thawing Enhances Sulfide Oxidation

   https://doi.org/10.1029/2022GB007644  

   Kemeny, Preston Cosslett; Li, Gen K.; Douglas, Madison; Berelson, William; Chadwick, Austin J.; Dalleska, Nathan F.; Lamb, Michael P.; Larsen, William; Magyar, John S.; Rollins, Nick E.; et al (November 2023, Global Biogeochemical Cycles)

   Abstract Permafrost degradation is altering biogeochemical processes throughout the Arctic. Thaw‐induced changes in organic matter transformations and mineral weathering reactions are impacting fluxes of inorganic carbon (IC) and alkalinity (ALK) in Arctic rivers. However, the net impact of these changing fluxes on the concentration of carbon dioxide in the atmosphere (pCO₂) is relatively unconstrained. Resolving this uncertainty is important as thaw‐driven changes in the fluxes of IC and ALK could produce feedbacks in the global carbon cycle. Enhanced production of sulfuric acid through sulfide oxidation is particularly poorly quantified despite its potential to remove ALK from the ocean‐atmosphere system and increasepCO₂, producing a positive feedback leading to more warming and permafrost degradation. In this work, we quantified weathering in the Koyukuk River, a major tributary of the Yukon River draining discontinuous permafrost in central Alaska, based on water and sediment samples collected near the village of Huslia in summer 2018. Using measurements of major ion abundances and sulfate () sulfur (³⁴S/³²S) and oxygen (¹⁸O/¹⁶O) isotope ratios, we employed the MEANDIR inversion model to quantify the relative importance of a suite of weathering processes and their net impact onpCO₂. Calculations found that approximately 80% of in mainstem samples derived from sulfide oxidation with the remainder from evaporite dissolution. Moreover,³⁴S/³²S ratios,¹³C/¹²C ratios of dissolved IC, and sulfur X‐ray absorption spectra of mainstem, secondary channel, and floodplain pore fluid and sediment samples revealed modest degrees of microbial sulfate reduction within the floodplain. Weathering fluxes of ALK and IC result in lower values ofpCO₂over timescales shorter than carbonate compensation (∼10⁴ yr) and, for mainstem samples, higher values ofpCO₂over timescales longer than carbonate compensation but shorter than the residence time of marine (∼10⁷ yr). Furthermore, the absolute concentrations of and Mg²⁺in the Koyukuk River, as well as the ratios of and Mg²⁺to other dissolved weathering products, have increased over the past 50 years. Through analogy to similar trends in the Yukon River, we interpret these changes as reflecting enhanced sulfide oxidation due to ongoing exposure of previously frozen sediment and changes in the contributions of shallow and deep flow paths to the active channel. Overall, these findings confirm that sulfide oxidation is a substantial outcome of permafrost degradation and that the sulfur cycle responds to permafrost thaw with a timescale‐dependent feedback on warming. 

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4. Interpreting depositional environments from modern floodplain sediments using optically stimulated luminescence

   https://doi.org/10.1111/bor.12679  

   Langston, Abigail L; Marcotte, Abbey L; Neudorf, Christina M; Rodrigues, Kathleen; Keen‐Zebert, Amanda (January 2025, Boreas)

   We investigate how luminescence signals imprinted on fluvial sediments vary depending on the depositional environment and vary through time in the same river. We collected sediment samples from four geomorphically distinct locations on the modern floodplain and modern point bar on the Buffalo River in northwest Arkansas, USA, in order to determine if different depositional environments are associated with distinct bleaching characteristics in the sediments. Our analysis revealed that all samples from different depositional environments yielded ages consistent with modern deposition. The samples collected from the floodplain and bar head contained a higher proportion of grains with residual doses, indicative of incomplete bleaching during transport, while samples from the mid‐bar and bar tail appeared well bleached. Our results are particularly intriguing for two significant reasons. First, they highlight distinct equivalent dose distributions in different depositional environments. Second, they shed light on an intriguing relationship: despite generally well‐bleached modern floodplain samples, ancient sediments from corresponding terraces displayed equivalent dose (D_e) distributions that suggest partial bleaching in some cases. This research contributes to the growing body of work that seeks to establish a relationship between luminescence properties and sediment transport processes and offers valuable insight into how luminescence signals vary locally in modern fluvial deposits, which can help guide the interpretation of older fluvial deposits. 

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5. The Boreal–Arctic Wetland and Lake Dataset (BAWLD)

   https://doi.org/10.5194/essd-13-5127-2021  

   Olefeldt, David; Hovemyr, Mikael; Kuhn, McKenzie A.; Bastviken, David; Bohn, Theodore J.; Connolly, John; Crill, Patrick; Euskirchen, Eugénie S.; Finkelstein, Sarah A.; Genet, Hélène; et al (January 2021, Earth System Science Data)

   Abstract. Methane emissions from boreal and arctic wetlands, lakes, and rivers areexpected to increase in response to warming and associated permafrost thaw.However, the lack of appropriate land cover datasets for scalingfield-measured methane emissions to circumpolar scales has contributed to alarge uncertainty for our understanding of present-day and future methaneemissions. Here we present the Boreal–Arctic Wetland and Lake Dataset(BAWLD), a land cover dataset based on an expert assessment, extrapolatedusing random forest modelling from available spatial datasets of climate,topography, soils, permafrost conditions, vegetation, wetlands, and surfacewater extents and dynamics. In BAWLD, we estimate the fractional coverage offive wetland, seven lake, and three river classes within 0.5 × 0.5∘ grid cells that cover the northern boreal and tundra biomes(17 % of the global land surface). Land cover classes were defined usingcriteria that ensured distinct methane emissions among classes, as indicatedby a co-developed comprehensive dataset of methane flux observations. InBAWLD, wetlands occupied 3.2 × 106 km2 (14 % of domain)with a 95 % confidence interval between 2.8 and 3.8 × 106 km2. Bog, fen, and permafrost bog were the most abundant wetlandclasses, covering ∼ 28 % each of the total wetland area,while the highest-methane-emitting marsh and tundra wetland classes occupied5 % and 12 %, respectively. Lakes, defined to include all lentic open-waterecosystems regardless of size, covered 1.4 × 106 km2(6 % of domain). Low-methane-emitting large lakes (>10 km2) and glacial lakes jointly represented 78 % of the total lakearea, while high-emitting peatland and yedoma lakes covered 18 % and 4 %,respectively. Small (<0.1 km2) glacial, peatland, and yedomalakes combined covered 17 % of the total lake area but contributeddisproportionally to the overall spatial uncertainty in lake area with a95 % confidence interval between 0.15 and 0.38 × 106 km2. Rivers and streams were estimated to cover 0.12  × 106 km2 (0.5 % of domain), of which 8 % was associated withhigh-methane-emitting headwaters that drain organic-rich landscapes.Distinct combinations of spatially co-occurring wetland and lake classeswere identified across the BAWLD domain, allowing for the mapping of“wetscapes” that have characteristic methane emission magnitudes andsensitivities to climate change at regional scales. With BAWLD, we provide adataset which avoids double-accounting of wetland, lake, and river extentsand which includes confidence intervals for each land cover class. As such,BAWLD will be suitable for many hydrological and biogeochemical modellingand upscaling efforts for the northern boreal and arctic region, inparticular those aimed at improving assessments of current and futuremethane emissions. Data are freely available athttps://doi.org/10.18739/A2C824F9X (Olefeldt et al., 2021). 

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