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Abstract Permafrost influences 25% of land in the Northern Hemisphere, where it stabilizes the ground beneath communities and infrastructure and sequesters carbon. However, the coevolution of permafrost, river dynamics, and vegetation in Arctic environments remains poorly understood. As rivers meander, they erode the floodplain at cutbanks and build new land through bar deposition, creating sequences of landforms with distinct formation ages. Here we mapped these sequences along the Koyukuk River floodplain, Alaska, analyzing permafrost occurrence, and landform and vegetation types. We used radiocarbon and optically stimulated luminescence (OSL) dating to develop a floodplain age map. Deposit ages ranged from modern to 10 ka, with more younger deposits near the modern channel. Permafrost rapidly reached 50% areal extent in all deposits older than 200 years then gradually increased up to ∼85% extent for deposits greater than 4 Kyr old. Permafrost extent correlated with increases in black spruce and wetland abundance, as well as increases in permafrost extent within wetland, and shrub and scrub vegetation classes. We developed an inverse model to constrain permafrost formation rate as a function of air temperature. Permafrost extent initially increased by ∼25% per century, in pace with vegetation succession, before decelerating to <10% per millennia as insulating overbank mud and moss slowly accumulated. Modern permafrost extent on the Koyukuk floodplain therefore reflects a dynamic balance between widespread, time‐varying permafrost formation and rapid, localized degradation due to cutbank erosion that might trigger a rapid loss of permafrost with climatic warming. 

Abstract Rapid warming in the Arctic threatens to destabilize mercury (Hg) deposits contained within soils in permafrost regions. Yet current estimates of the amount of Hg in permafrost vary by ∼4 times. Moreover, how Hg will be released to the environment as permafrost thaws remains poorly known, despite threats to water quality, human health, and the environment. Here we present new measurements of total mercury (THg) contents in discontinuous permafrost in the Yukon River Basin in Alaska. We collected riverbank and floodplain sediments from exposed banks and bars near the villages of Huslia and Beaver. Median THg contents were 49⁺¹³/₋₂₁ng THg g sediment⁻¹and 39⁺¹⁶/₋₁₈ng THg g sediment⁻¹for Huslia and Beaver, respectively (uncertainties as 15th and 85th percentiles). Corresponding THg:organic carbon ratios were 5.4^+2.0/_−2.4Gg THg Pg C⁻¹and 4.2^+2.4/_−2.9Gg THg Pg C⁻¹. To constrain floodplain THg stocks, we combined measured THg contents with floodplain stratigraphy. Trends of THg increasing with smaller sediment size and calculated stocks in the upper 1 m and 3 m are similar to those suggested for this region by prior pan-Arctic studies. We combined THg stocks and river migration rates derived from remote sensing to estimate particulate THg erosional and depositional fluxes as river channels migrate across the floodplain. Results show similar fluxes within uncertainty into the river from erosion at both sites (95⁺¹²/₋₄₇kg THg yr⁻¹and 26⁺¹⁵⁴/₋₁₃kg THg yr⁻¹at Huslia and Beaver, respectively), but different fluxes out of the river via deposition in aggrading bars (60⁺⁴⁰/₋₂₉kg THg yr⁻¹and 10^+5.3/_−1.7kg THg yr⁻¹). Thus, a significant amount of THg is liberated from permafrost during bank erosion, while a variable but generally lesser portion is subsequently redeposited by migrating rivers. 

Abstract Permafrost degradation is altering biogeochemical processes throughout the Arctic. Thaw‐induced changes in organic matter transformations and mineral weathering reactions are impacting fluxes of inorganic carbon (IC) and alkalinity (ALK) in Arctic rivers. However, the net impact of these changing fluxes on the concentration of carbon dioxide in the atmosphere (pCO₂) is relatively unconstrained. Resolving this uncertainty is important as thaw‐driven changes in the fluxes of IC and ALK could produce feedbacks in the global carbon cycle. Enhanced production of sulfuric acid through sulfide oxidation is particularly poorly quantified despite its potential to remove ALK from the ocean‐atmosphere system and increasepCO₂, producing a positive feedback leading to more warming and permafrost degradation. In this work, we quantified weathering in the Koyukuk River, a major tributary of the Yukon River draining discontinuous permafrost in central Alaska, based on water and sediment samples collected near the village of Huslia in summer 2018. Using measurements of major ion abundances and sulfate () sulfur (³⁴S/³²S) and oxygen (¹⁸O/¹⁶O) isotope ratios, we employed the MEANDIR inversion model to quantify the relative importance of a suite of weathering processes and their net impact onpCO₂. Calculations found that approximately 80% of in mainstem samples derived from sulfide oxidation with the remainder from evaporite dissolution. Moreover,³⁴S/³²S ratios,¹³C/¹²C ratios of dissolved IC, and sulfur X‐ray absorption spectra of mainstem, secondary channel, and floodplain pore fluid and sediment samples revealed modest degrees of microbial sulfate reduction within the floodplain. Weathering fluxes of ALK and IC result in lower values ofpCO₂over timescales shorter than carbonate compensation (∼10⁴ yr) and, for mainstem samples, higher values ofpCO₂over timescales longer than carbonate compensation but shorter than the residence time of marine (∼10⁷ yr). Furthermore, the absolute concentrations of and Mg²⁺in the Koyukuk River, as well as the ratios of and Mg²⁺to other dissolved weathering products, have increased over the past 50 years. Through analogy to similar trends in the Yukon River, we interpret these changes as reflecting enhanced sulfide oxidation due to ongoing exposure of previously frozen sediment and changes in the contributions of shallow and deep flow paths to the active channel. Overall, these findings confirm that sulfide oxidation is a substantial outcome of permafrost degradation and that the sulfur cycle responds to permafrost thaw with a timescale‐dependent feedback on warming. 

This document describes geomorphic relative age mapping and radiocarbon (14C) measurements used to construct floodplain age models for three locations within the Yukon River Watershed: Huslia, Alaska (65.700 N, 156.387 W), Alakanuk, Alaska (62.685 N, 164.644 W), and Beaver, Alaska (66.362 N, 147.398 W). We describe the field sampling protocols, geomorphic mapping of cross-cutting relationships (aided by digital elevation models (DEMs) and high-resolution satellite imagery), 14C and optically stimulated luminescence (OSL) lab analyses, Markov Chain Monte Carlo (MCMC) interpolation through the geomorphic–radiogenic age constraints, and the resulting floodplain terrain age models. 

Due to atmospheric circulation and preservation of organic matter, large amounts of mercury (Hg) are stored in permafrost regions. Due to rapid warming and thawing permafrost in the Arctic, this Hg may be released, potentially degrading water quality and impacting human health. River bank erosion in particular has the ability to quickly mobilize large amounts of Hg-rich floodplain sediments. As part of a National Science Foundation (NSF) funded project to better understand the effects of erosion in the Yukon River Basin, floodplain sediments were collected between June and September 2022 at two locations underlain by discontinuous permafrost within the Yukon River Basin: Beaver, Alaska (AK) (65.700 N, 156.387 W) and Huslia, AK (66.362N, 147.398 W). This dataset contains mercury contents for collected floodplain sediments measured by direct thermal decomposition. Sample metadata also includes information recorded in the field (location, visual grain size description, and sample collection depth) and collected post sample processing (water content and dry density). 

The carbon stored in permafrost deposits represents the single largest soil carbon reservoir on Earth. Concerns about the instability and dynamics of this carbon reservoir during permafrost thaw associated with polar amplification of climate warming contribute a large part of the uncertainty in forecasting future climate. We have been studying the carbon dynamics of permafrost deposits contained in the floodplains of large Arctic rivers. Across Arctic floodplains, accelerating bank erosion can liberate permafrost organic carbon (OC) as carbon dioxide (CO2) or methane (CH4), and/or redeposit it in fluvial units. These different fates have very different implications for climate feedback. Determining OC stocks and their dynamics in Arctic floodplain cutbanks and point bars, as well as the OC load in fluvial transport, is essential to better understand the recycling and export of permafrost carbon. As part of a National Science Foundation (NSF) funded project to better understand the effects of erosion in the Yukon River Basin, floodplain sediments were collected between June and September 2022 at two locations underlain by discontinuous permafrost within the Yukon River Basin in Alaska: Beaver (65.700° North (N), 156.387° West (W)) and Huslia (66.362° N, 147.398° W). This dataset mainly reports OC contents for collected subsurface sediments in floodplains measured by elemental analyzer. The coupled mercury content can be found in Isabel et al., 2024 (https://doi.org/10.18739/A2RF5KH5J). 

This dataset describes measurements of river migration rates (averaged over the period 2016-2022) in three locations within the Yukon River Watershed: Huslia, Alaska (AK) (65.700 N, 156.387 W), Beaver, AK (66.362 N, 147.398 W), and Alakanuk, AK (62.685 N, 164.644 W). Huslia is located on the Koyukuk River and Beaver and Alakanuk are located on the Yukon River. The river migration rates are quantified from sub-pixel correlation of optical satellite imagery (Sentinel-2 imagery, 10 meter (m) spatial resolution), following the methodology of Geyman et al. (2024). The methodology allows for the detection of riverbank erosion at scales approximately 5-10 times smaller than the pixel size, so the detection threshold is 1-2 m over the approximately 7-year interval, corresponding to a migration rate of 0.1 to 0.3 m/year. The motion of the eroding and accreting sides of the river are quantified separately. The river migration rate datasets are made available as georeferenced shapefiles. 

This dataset includes field measurements of above-ground biomass made between May and October, 2023 in three locations within the Yukon River Watershed: Huslia, Alaska(AK) (65.700 N, 156.387W), Beaver, AK (66.362 N, 147.398W), and Alakanuk, AK (62.685N, 164.644W). We measured a total of 11,335 trees, distributed in 190 field plots (approximately 10 meter (m) x 10 m). We apply allometric scaling relations to convert measurements of tree diameter to kilograms of dry biomass. We then link these filed measurements of above-ground biomass density to the mean forest canopy height (MCH), derived from airborne Light Detection and Ranging (LiDAR) data. We derive empirical regressions linking MCH to above-ground biomass in each of the field sites, and then apply these empirical relationships to the LiDAR datasets to obtain maps of above-ground biomass density. This dataset includes both the field observations (coordinates, tree type, and tree diameter of the 11,335 inventoried trees) and the processed above-ground biomass maps (georeferenced TIFF files, with a spatial resolution of 10 m).