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Abstract An empirical model was developed to predict organic solvophobic effects usingN‐phenylimide molecular balances functionalized with non‐polar alkyl groups. Solution studies and X‐ray crystallography confirmed intramolecular alkyl‐alkyl interactions in theirfoldedconformers. The structural modularity of the balances allowed systematic variation of alkyl group lengths. Control balances were instrumental in isolating weak organic solvophobic effects by eliminating framework solvent‐solute effects. A19F NMR label enabled analysis across 46 deuterated and non‐deuterated solvent systems. Linear correlations were observed between organic solvophobic effects and solvent cohesive energy density (ced) as well as changes in solvent‐accessible surface areas (SASA). Using these empirical relationships, a model was constructed to predict organic solvophobic interaction energy per unit area for any organic solvent with knowncedvalues. The predicted interaction energies aligned with recent organic solvophobic measurements and literature values for the hydrophobic effect on non‐polar surfaces confirmed the model‘s accuracy and utility.
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A strategy to build high-performance thick electrodes for lithium-ion batteries with enhanced compressive modulus and regulated tortuosity in the phase-inversion process
By tuning the composition of the non-solvent bath used in the non-solvent induced phase inversion process for fabricating thick and low-tortuosity battery electrodes, optimal electrochemical performances and compressive modulus were achieved.
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- Award ID(s):
- 1752378
- PAR ID:
- 10566131
- Publisher / Repository:
- The Royal Society of Chemistry
- Date Published:
- Journal Name:
- Journal of Materials Chemistry A
- Volume:
- 12
- Issue:
- 27
- ISSN:
- 2050-7488
- Page Range / eLocation ID:
- 16537 to 16545
- Subject(s) / Keyword(s):
- Thick electrodes lithium-ion batteries phase inversion tortuosity compressive modulus
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
-
Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1039/D4TA00589A
