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1. Effect of Nanocarbon on the Structural and Mechanical Properties of 6061 Aluminum Composites by Powder Metallurgy

   https://doi.org/10.3390/nano13222917  

   Rativa-Parada, Wilson; Sirikumara, Hansika I.; Karunanithy, Robinson; Sivakumar, Poopalasingam; Jayasekera, Thushari; Nilufar, Sabrina (November 2023, Nanomaterials)

   6061 aluminum composites with 0.5 and 1 vol. % graphene nanoplatelets as well as 1 and 2 vol. % activated nanocarbon were manufactured by a powder metallurgy method. Scanning electron microscopy and Raman spectroscopy were used to study the morphology, structure, and distribution of nanocarbon reinforcements in the composite samples. Density Functional Theory (DFT) calculations were performed to understand the aluminum-carbon bonding and the effects of hybridized networks of carbon atoms on nanocarbon aluminum matrix composites. Scanning electron microscopy showed the good distribution and low agglomeration tendencies of nanoparticles in the composites. The formation of secondary phases at the materials interface was not detected in the hot-pressed composites. Raman spectroscopy showed structural changes in the reinforced composites after the manufacturing process. The results from Density Functional Theory calculations suggest that it is thermodynamically possible to form carbon rings in the aluminum matrix, which may be responsible for the improved mechanical strength. Our results also suggest that these carbon networks are graphene-like, which also agrees with the Raman spectroscopy data. Micro-Vickers hardness and compressive tests were used to determine the mechanical properties of the samples. Composites presented enhanced hardness, yield and ultimate strength compared to the 6061 aluminum alloy with no nanocarbon reinforcement. Ductility was also affected, as shown by the reduction in elongation and by the number of dimples in the fractured surfaces of the materials. 

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2. Structure-Property Relationships of Differently Heat-Treated Binder Jet Printed Co-Cr-Mo Biomaterial

   https://doi.org/10.1016/j.mtcomm.2023.107716  

   Khademitab, M; Rodriguez_de_Vecchis, P; Staszel, P; Vaicik, M_K; Chmielus, M; Mostafaei, A (November 2023, Materials Today Communications)

   This investigation systematically examines the influence of sintering temperature and aging treatment on the density, microstructure evolution, phase formation, and mechanical properties of a binder jet printed Co-Cr-Mo biomedical alloy. Sintering at 1380 °C for 2 h yielded a near-fully dense part (99.1%) with favorable mechanical properties (up to 325 HV0.1 hardness and up to 693 MPa ultimate tensile strength). The grain size remained unchanged after aging at 800 °C for 24 h (89 ± 21 µm). Aging resulted in increased microhardness and tensile strength due to phase formation (Cr23C6, CrMo, and ε phase), but a significant decrease in ductility. Consequently, the sintered and aged specimen exhibited higher hardness (522 HV0.1), yield strength (641 MPa), and ultimate tensile strength (854 MPa) compared to cast Co-Cr-Mo alloy. Biocompatibility testing with fibroblasts showed a cell viability of 95 ± 2%, indicating that binder jet printing did not affect the biocompatibility of the Co-Cr-Mo alloy. Exemplary printed parts including hip-joint, partial denture, and small-scale knee joint were successfully demonstrated. This study highlights the comparable properties of binder jet Co-Cr-Mo alloy to the cast alloy, affirming its potential for biomedical applications. 

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3. Tensile Properties of Unidirectional Polymer Composites Reinforced By Aligned Carbon Nanotube Yarns

   https://doi.org/10.12783/asc38/36612  

   Naderi, Ali; Tarafdar, Amirreza; Lin, Wenhua; Wang, Yeqing (September 2023, Destech Publications, Inc.)

   Carbon nanotubes (CNTs), as they possess outstanding mechanical properties and low density, are considered as one of the most promising reinforcements in composite structures. Due to their capability of transferring loads, CNTs in long continuous forms such as yarns and tapes can withstand 20 times as much load as steel can do at the same weight. In this research, carbon nanotube yarns were wound onto an aluminum plate using a custom-built fixture to fabricate a unidirectional strip. Then, by brushing epoxy resin on the strip and laminating four layers, the unidirectional CNT reinforced epoxy resin composite beam specimens were produced. The mechanical properties of the unidirectional CNT-reinforced composite (CNTRC) were determined using standard tensile tests. This study presents a method for manufacturing CNTRC out of CNT yarns, determining the CNTRC’s Young’s modulus as well as the tensile strength, and obtaining its strain field via digital image correlation (DIC) method. It is observed that the pressure due to sandwiching of the aluminum plates during the manufacturing process leads to nonuniformity of the specimen in the width along midspan of the longitudinal direction which results in the specimen’s not being perfectly unidirectional. This phenomenon can cause the matrix cracking in tensile test and reduce the ultimate tensile strength up to 78% in comparison with perfectly unidirectional specimens. However, the Young’s modulus of such composites is comparable with those obtained from previously existing research. Also, Results from DIC showed the possible failure prone areas in the specimens, as it presents a up to 64% difference between the highest and lowest strain in the tensile loading direction through the specimens. This study will serve as a foundation for future research involving CNT composites, particularly the use of their high anisotropy to produce auxetic composites with large negative Poisson’s ratios. 

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4. An as-cast high-entropy alloy with remarkable mechanical properties strengthened by nanometer precipitates

   https://doi.org/10.1039/C9NR08338C  

   Qin, Gang; Chen, Ruirun; Liaw, Peter K.; Gao, Yanfei; Wang, Liang; Su, Yanqing; Ding, Hongsheng; Guo, Jingjie; Li, Xiaoqing (February 2020, Nanoscale)

   High-entropy alloys (HEAs) with good ductility and high strength are usually prepared by a combination of forging and heat-treatment processes. In comparison, the as-cast HEAs typically do not reach strengths similar to those of HEAs produced by the forging and heat-treatment processes. Here we report a novel equiatomic-ratio CoCrCuMnNi HEA prepared by vacuum arc melting. We observe that this HEA has excellent mechanical properties, i.e. , a yield strength of 458 MPa, and an ultimate tensile strength of 742 MPa with an elongation of 40%. Many nanometer precipitates (5–50 nm in size) and domains (5–10 nm in size) are found in the inter-dendrite and dendrite zones of the produced HEA, which is the key factor for its excellent mechanical properties. The enthalpy of mixing between Cu and Mn, Cr, Co, or Ni is higher than those of mixing between any two of Cr, Co, Ni and Mn, which leads to the separation of Cu from the CoCrCuMnNi HEA. Furthermore, we reveal the nanoscale-precipitate-phase-forming mechanism in the proposed HEA. 

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5. Hybrid Metal-Organic Frameworks/Carbon Fibers Reinforcements for Additively Manufactured Composites

   https://doi.org/10.3390/nano13050944  

   Al-Haik, Marwan; Ayyagari, Suma; Ren, Yixin; Abbott, Andrew; Zheng, Bing Qian; Koerner, Hilmar (March 2023, Nanomaterials)

   Additively manufactured (AM) composites based on short carbon fibers possess strength and stiffness far less than their continuous fiber counterparts due to the fiber’s small aspect ratio and inadequate interfaces with the epoxy matrix. This investigation presents a route for preparing hybrid reinforcements for AM that comprise short carbon fibers and nickel-based metal-organic frameworks (Ni-MOFs). The porous MOFs furnish the fibers with tremendous surface area. Additionally, the MOFs growth process is non-destructive to the fibers and easily scalable. This investigation also demonstrates the viability of using Ni-based MOFs as a catalyst for growing multi-walled carbon nanotubes (MWCNTs) on carbon fibers. The changes to the fiber were examined via electron microscopy, X-ray scattering techniques, and Fourier-transform infrared spectroscopy (FTIR). The thermal stabilities were probed by thermogravimetric analysis (TGA). Tensile and dynamic mechanical analysis (DMA) tests were utilized to explore the effect of MOFs on the mechanical properties of 3D-printed composites. Composites with MOFs exhibited improvements in stiffness and strength by 30.2% and 19.0%, respectively. The MOFs enhanced the damping parameter by 700%. 

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