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Abstract Paper, an inexpensive material with natural biocompatibility, non‐toxicity, and biodegradability, allows for affordable and cost‐effective substrates for unconventional advanced electronics, often called papertronics. On the other hand, polymeric elastomers have shown to be an excellent success for substrates of soft bioelectronics, providing stretchability in skin wearable technology for continuous sensing applications. Although both materials hold their unique advantageous characteristics, merging both material properties into a single electronic substrate reimagines paper‐based bioelectronics for wearable and patchable applications in biosensing, energy generation and storage, soft actuators, and more. Here, a breathable, light‐weighted, biocompatible engineered stretchable paper is reported via coaxial nonwoven microfibers for unconventional bioelectronic substrates. The stretchable papers allow intimate bioconformability without adhesive through coaxial electrospinning of a cellulose acetate polymer (sheath) and a silicone elastomer (core). The fabricated cellulose‐silicone fibers exhibit a greater percent strain than commercially available paper while retaining hydrophilicity, biocompatibility, combustibility, disposable, and other natural characteristics of paper. Moreover, the nonwoven stretchable cellulose‐silicone fibrous mat can adapt conventional printing and fabrication process for paper‐based electronics, an essential aspect of advanced bioelectronic manufacturing.
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This content will become publicly available on February 27, 2026
Fabrication of Stretchable and Conductive Liquid Metal Microfibers through Coaxial Emulsion Electrospinning
Liquid metal fibers are increasingly used in soft multifunctional materials and soft electronics due to their superb stretchability, high conductivity, and lightweight. This work presents a systematic study of the electrospinning process of liquid metal microfibers. Compared to other methods that usually produce fibers thicker than 100 μm, electrospinning is a facile and low‐cost method of producing liquid metal fibers in the range of 10–100 μm. Specifically, core‐sheath liquid metal microfibers are fabricated with a highly conductive liquid metal core and a super‐stretchable thermoplastic elastomer sheath. This manufacturing process uses a liquid metal emulsion as the core solution, which circumvents manufacturing failures caused by the high surface tension of liquid metals. The influence of key processing parameters such as core flow rate, sheath flow rate, and applied voltage on the fiber diameter and morphology is studied by experiments. The mechanical and electrical properties of the as‐fabricated liquid metal microfibers, mats, and yarns are tested and discussed.
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- Award ID(s):
- 2143297
- PAR ID:
- 10577120
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Advanced Engineering Materials
- ISSN:
- 1438-1656
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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