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1. Mantle oxidation by sulfur drives the formation of giant gold deposits in subduction zones

   He, D-Y; Qui, K-F; Simon, AC; Deng, J; Pokrovski, GS; Yu, H-C; Connolly, JAD; Li, S-S; Turner, S; Wang, Q-F; et al (December 2024, PNAS Proceedings of the National Academy of Sciences of the United States of America.)

   Oxidation of the sub-arc mantle driven by slab-derived fluids has been hypothesized to contribute to the formation of gold deposits in magmatic arc environments that host the majority of metal resources on Earth. However, the mechanism by which the infiltration of slab-derived fluids into the mantle wedge changes its oxidation state and affects Au enrichment remains poorly understood. Here, we present the results of a numerical model that demonstrates that slab-derived fluids introduce large amounts of sulfate (S6+) into the overlying mantle wedge that increase its oxygen fugacity by up to 3 to 4 log units relative to the pristine mantle. Our model predicts that as much as 1 wt.% of the total dissolved sulfur in slab-derived fluids reacting with mantle rocks is present as the trisulfur radical ion, S3–. This sulfur ligand stabilizes the aqueous Au(HS)S3– complex, which can transport Au concentrations of several grams per cubic meter of fluid. Such concentrations are more than three orders of magnitude higher than the average abundance of Au in the mantle. Our data thus demonstrate that an aqueous fluid phase can extract 10 to 100 times more Au than in a fluid-absent rock-melt system during mantle partial melting at redox conditions close to the sulfide-sulfate boundary. We conclude that oxidation by slab-derived fluids is the primary cause of Au mobility and enrichment in the mantle wedge and that aqueous fluid-assisted mantle melting is a prerequisite for formation of Au-rich magmatic hydrothermal and orogenic gold systems in subduction zone settings. 

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2. Tyrrhenian Continent–Ocean Transition

   https://doi.org/10.14379/iodp.proc.402.2025  

   Zitellini, N; Malinverno, A; Estes, ER (April 2025, International Ocean Discovery Program)

   In the classical view of tectonic rifting, divergent lithospheric plates cause the asthenospheric mantle to ascend, decompress, and melt, eventually producing new magmatic crust. This view has been updated by drilling results that found exhumed mantle at the continent–ocean transition (COT), leading to the definition of magma-poor rifted margins. Obtaining geologic samples from COTs to directly constrain the diversity of rifting processes is a challenge because the igneous crust and mantle rocks are typically buried under a thick sediment cover. The Tyrrhenian Sea provides an optimal location to test COT formation models by drilling because it has a comparatively thin sediment cover, allows for studying a conjugate pair of COT margins in a single drilling expedition, and has been mapped in unprecedented detail with recent geophysical measurements. The key objective of International Ocean Discovery Program Expedition 402 was to determine the nature of the geologic basement in the central Vavilov Basin, where exhumed mantle peridotites were expected, and in the conjugate margins to the west (Cornaglia Terrace) and east (Campania Terrace). In the Vavilov Basin, Sites U1614 and U1616 recovered an exceptional variety of mantle rocks, including lherzolites, harzburgites, plagioclase-bearing lherzolites and harzburgites, dunites, and minor amounts of pyroxenites and magmatic intrusions. The mantle peridotites are significantly hydrated and weathered, resulting in the formation of serpentine and carbonate veins. In contrast, Site U1612 recovered at the sediment/basement interface an unconsolidated breccia with clasts of basalt, peridotite, and granite, followed by variably deformed mylonitic gneisses that transition downhole to granitoid quartz-diorite rocks. On the western Tyrrhenian margin (Cornaglia Terrace), Site U1613 sampled a sediment sequence dating back to the Messinian (Late Miocene), resting on much older sedimentary rocks akin to the Triassic–Paleozoic successions outcropping in Sardinia, supporting the hypothesis that the margin consists of extended continental crust. On the conjugate margin to the east (Campania Terrace), Site U1617 did not reach the basement but recovered a complete sequence of Messinian evaporites, including halite. The samples and data collected during Expedition 402 provide an extensive new data set to determine the heterogeneity of the mantle, the nature and history of melt production and impregnation, and the extent and evolution of mantle serpentinization and carbonation; to constrain the geometry and timing of the deformation that led to mantle exhumation; to study the fluid-rock interactions between seawater, sediment, and mantle peridotites; and to constrain geodynamic models of rifting and COT formation. 

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3. Phase Relations of a Depleted Peridotite Fluxed by a CO ₂ ‐H ₂ O Fluid—Implications for the Stability of Partial Melts Versus Volatile‐Bearing Mineral Phases in the Cratonic Mantle

   https://doi.org/10.1029/2019JB017653  

   Saha, Sriparna; Dasgupta, Rajdeep (October 2019, Journal of Geophysical Research: Solid Earth)

   Abstract We present phase‐equilibria experiments of a K‐bearing, depleted peridotite (Mg# 92) fluxed with a mixed CO₂‐H₂O fluid (0.5 wt.% CO₂and 0.94 wt.% H₂O in the bulk) to gain insight into the stability of volatile‐bearing partial melts versus volatile‐bearing mineral phases in a depleted peridotite system. Experiments were performed at 850–1150 °C and 2–4 GPa using a piston‐cylinder and a multianvil apparatus. Olivine, orthopyroxene, clinopyroxene, and spinel/garnet are present at all experimental conditions. Textural confirmation of partial melt is made at temperatures as low as 1000 °C at 2 GPa, 950 °C at 3 GPa, and 1000 °C at 4 GPa marking the onset of melting at 900–1000 °C at 2 GPa, 850–950 °C at 3 GPa, and 950–1000 °C at 3 GPa. Phlogopite and magnesite breakdown at 900–1000 °C at 2 GPa, 950–1000 °C at 3 GPa, and 1000–1050 °C at 4 GPa. Comparison with previously published experiments in depleted peridotite system with identical CO₂‐H₂O content introduced via a silicic melt show that introduction of CO₂‐H₂O as fluid lowers the temperature of phlogopite breakdown by 150–200 °C at 2–4 GPa and stabilizes partial melts at lower temperatures. Our study thus, shows that the volatile‐bearing phase present in the cratonic mantle is controlled by bulk composition and is affected by the process of volatile addition during craton formation in a subduction zone. In addition, volatile introduction via melt versus aqueous fluid, leads to different proportion of anhydrous phases such as olivine and orthopyroxene. Considering the agent of metasomatism is thus critical to evaluate how the bulk composition of depleted peridotite is modified, leading to potential stability of volatile‐bearing phases as the cause of anomalously low shear wave velocity in mantle domains such as mid lithospheric discontinuities beneath continents. 

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4. High‐Resolution Magnetic‐Geochemical Mapping of the Serpentinized and Carbonated Atlin Ophiolite, British Columbia: Toward Establishing Magnetometry as a Monitoring Tool for In Situ Mineral Carbonation

   https://doi.org/10.1029/2022GC010730  

   Tominaga, Masako; Beinlich, Andreas; Lima, Eduardo A.; Pruett, Paiden; Vento, Noah R.; Weiss, Benjamin P. (April 2023, Geochemistry, Geophysics, Geosystems)

   Abstract We address in situ serpentinization and mineral carbonation processes in oceanic lithosphere using integrated field magnetic measurements, rock magnetic analyses, superconducting quantum interference device (SQUID) microscopy, microtextural observations, and energy dispersive spectroscopy phase mapping. A representative suite of ultramafic rock samples were collected, within the Atlin ophiolite, along a 100‐m long transect across a continuous outcrop of mantle harzburgite with several alteration fronts: serpentinite, soapstone (magnesite + talc), and listvenite (magnesite + quartz). Strong correlations between changes in magnetic signal strengths and amount of alteration are shown with distinctive contrasts between serpentinite, transitional soapstone, and listvenite that are linked to the formation and breakdown of magnetite. While previous observations of the Linnajavri ultramafic complex indicated that the breakdown of magnetite occurred during listvenite formation from the precursor soapstone (Tominaga et al., 2017,https://doi.org/10.1038/s41467-017-01610-4), results from our study suggest that magnetite destabilization already occurred during the replacement of serpentinite by soapstone (i.e., at lower fluid CO₂concentrations). This difference is attributed to fracture‐controlled flow of sulfur‐bearing alteration fluid at Atlin, causing reductive magnetite dissolution in thin soapstone zones separating serpentinite from sulfide‐mineralized listvenite. We argue that magnetite growth or breakdown in soapstone provides insight into the mode of fluid flow and the composition, which control the scale and extent of carbonation. This conclusion enables us to use magnetometry as a viable tool for monitoring the reaction progress from serpentinite to carbonate‐bearing assemblages in space and time with a caution that the three‐dimensionality of magnetic sources impacts the scalability of measurements. 

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5. Expedition 399 Preliminary Report: Building Blocks of Life, Atlantis Massif

   https://doi.org/10.14379/iodp.pr.399.2024  

   McCaig, A.; Lang, S.Q.; Blum, P. (March 2024, Preliminary report)

   International Ocean Discovery Program (IODP) Expedition 399 collected new cores from the Atlantis Massif (30°N; Mid-Atlantic Ridge), an oceanic core complex that hosts the Lost City hydrothermal field (LCHF). Studies of the Atlantis Massif and the LCHF have transformed our understanding of tectonic, magmatic, hydrothermal, and microbial processes at slow-spreading ridges. The Atlantis Massif was the site of four previous expeditions (Integrated Ocean Drilling Program Expeditions 304, 305, and 340T and IODP Expedition 357) and numerous dredging and submersible expeditions. The deepest IODP hole in young (<2 My) oceanic lithosphere, Hole U1309D, was drilled ~5 km north of the LCHF and reached 1415 meters below seafloor (mbsf) through a series of primitive gabbroic rocks. A series of 17 shallow (<16.4 mbsf) holes were also drilled at 9 sites across the south wall of the massif during Expedition 357, recovering heterogeneous rock types including hydrothermally altered peridotites, gabbroic, and basaltic rocks. The hydrologic regime differs between the two locations, with a low permeability conductive regime in Hole U1309D and a high (and possibly deep-reaching) permeability regime along the southern wall. Expedition 399 targeted Hole U1309D and the southern wall area to collect new data on ancient processes during deformation and alteration of detachment fault rocks. The recovered rocks and fluids are providing new insights into past and ongoing water-rock interactions, processes of mantle partial melting and gabbro emplacement, deformation over a range of temperatures, abiotic organic synthesis reactions, and the extent and diversity of life in the subseafloor in an actively serpentinizing system. We sampled fluids and measured temperature in Hole U1309D before deepening it to 1498 mbsf. The thermal structure was very similar to that measured during Expedition 340T, and lithologies were comparable to those found previously in Hole U1309D. A significant zone of cataclasis and alteration was found at 1451–1474 mbsf. A new Hole U1601C (proposed Site AMDH-02A) was drilled on the southern ridge close to Expedition 357 Hole M0069A, where both deformed and undeformed serpentinites had previously been recovered. Rapid drilling rates achieved a total depth of 1267.8 mbsf through predominantly ultramafic (68%) and gabbroic (32%) rocks, far surpassing the previous drilling record in a peridotite-dominated system of 201 m. Recovery was excellent overall (71%) but particularly high in peridotite-dominated sections where recovery regularly exceeded 90%. The recovery of sizable sections of largely intact material will provide robust constraints on the architecture and composition of the oceanic mantle lithosphere. The deepest portions of the newly drilled borehole may be beyond the known limits of life, providing the means to assess the role of biological activity across the transition from a biotic to an abiotic regime. Borehole fluids from both holes were collected using both the Kuster Flow-Through Sampler and the new Multi-Temperature Fluid Sampler. Wireline logging in Hole U1601C provided information on downhole density and resistivity, imaged structural features, and documented fracture orientations. A reentry system was installed in Hole U1601C, and both it and Hole U1309D were left open for future deep drilling, fluid sampling, and potential borehole observatories. 

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