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Abstract Visible light‐induced Pd catalysis has emerged as a promising subfield of photocatalysis. The hybrid nature of Pd radical species has enabled a wide array of radical‐based transformations otherwise challenging or unknown via conventional Pd chemistry. In parallel to the ongoing pursuit of alternative, readily available radical precursors, notable discoveries have demonstrated that photoexcitation can alter not only oxidative addition but also other elementary steps. This Minireview highlights the recent progress in this area.
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This content will become publicly available on April 11, 2026
A 3–D Printed Millifluidic Reactor for Continuous Flow Photocatalysis in the Teaching Laboratory
An experiment designed to teach principles of continuous flow technologies for photocatalysis is 10 described as a part of a two-week summer camp program for high school students. Students learned about green chemistry, photocatalysis, flow chemistry, and the role of 3–D printing for the design and production of custom millifluidic reactors. Students examined reactor designs which differed in terms of residence times and mixing capabilities. Such evaluation was based on the combination of blue and yellow dyes, followed by running a photocatalytic thiol-ene reaction on gram-scale.
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- Award ID(s):
- 2154668
- PAR ID:
- 10582764
- Publisher / Repository:
- ChemRxiv
- Date Published:
- Format(s):
- Medium: X
- Institution:
- University of Michigan
- Sponsoring Org:
- National Science Foundation
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