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1. On the stratospheric chemistry of midlatitude wildfire smoke

   https://doi.org/10.1073/pnas.2117325119  

   Solomon, Susan; Dube, Kimberlee; Stone, Kane; Yu, Pengfei; Kinnison, Doug; Toon, Owen B.; Strahan, Susan E.; Rosenlof, Karen H.; Portmann, Robert; Davis, Sean; et al (March 2022, Proceedings of the National Academy of Sciences)

   Massive Australian wildfires lofted smoke directly into the stratosphere in the austral summer of 2019/20. The smoke led to increases in optical extinction throughout the midlatitudes of the southern hemisphere that rivalled substantial volcanic perturbations. Previous studies have assumed that the smoke became coated with sulfuric acid and water and would deplete the ozone layer through heterogeneous chemistry on those surfaces, as is routinely observed following volcanic enhancements of the stratospheric sulfate layer. Here, observations of extinction and reactive nitrogen species from multiple independent satellites that sampled the smoke region are compared to one another and to model calculations. The data display a strong decrease in reactive nitrogen concentrations with increased aerosol extinction in the stratosphere, which is a known fingerprint for key heterogeneous chemistry on sulfate/H 2 O particles (specifically the hydrolysis of N 2 O 5 to form HNO 3 ). This chemical shift affects not only reactive nitrogen but also chlorine and reactive hydrogen species and is expected to cause midlatitude ozone layer depletion. Comparison of the model ozone to observations suggests that N 2 O 5 hydrolysis contributed to reduced ozone, but additional chemical and/or dynamical processes are also important. These findings suggest that if wildfire smoke injection into the stratosphere increases sufficiently in frequency and magnitude as the world warms due to climate change, ozone recovery under the Montreal Protocol could be impeded, at least sporadically. Modeled austral midlatitude total ozone loss was about 1% in March 2020, which is significant compared to expected ozone recovery of about 1% per decade. 

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2. Residual impacts of a wildland urban interface fire on urban particulate matter and dust: a study from the Marshall Fire

   https://doi.org/10.1007/s11869-023-01376-3  

   Silberstein, Jonathan M.; Mael, Liora E.; Frischmon, Caroline R.; Rieves, Emma S.; Coffey, Evan R.; Das, Trupti; Dresser, William; Hatch, Avery C.; Nath, Jyotishree; Pliszka, Helena O.; et al (January 2023, Air Quality, Atmosphere & Health)

   The impacts of wildfires along the wildland urban interface (WUI) on atmospheric particulate concentrations and composition are an understudied source of air pollution exposure. To assess the residual impacts of the 2021 Marshall Fire (Colorado), a wildfire that predominantly burned homes and other human-made materials, on homes within the fire perimeter that escaped the fire, we performed a combination of fine particulate matter (PM2.5) filter sampling and chemical analysis, indoor dust collection and chemical analysis, community scale PurpleAir PM2.5 analysis, and indoor particle number concentration measurements. Following the fire, the chemical speciation of dust collected in smoke-affected homes in the burned zone showed elevated concentrations of the biomass burning marker levoglucosan (medianlevo = 4147 ng g−1), EPA priority toxic polycyclic aromatic hydrocarbons (median Σ16PAH = 1859.3 ng g−1), and metals (median Σ20Metals = 34.6 mg g−1) when compared to samples collected in homes outside of the burn zone 6 months after the fire. As indoor dust particles are often resuspended and can become airborne, the enhanced concentration of hazardous metals and organics within dust samples may pose a threat to human health. Indoor airborne particulate organic carbon (median = 1.91 μg m−3), particulate elemental carbon (median = .02 μg m−3), and quantified semi-volatile organic species in PM2.5 were found in concentrations comparable to ambient air in urban areas across the USA. Particle number and size distribution analysis at a heavily instrumented supersite home located immediately next to the burned area showed indoor particulates in low concentrations (below 10 μg m−3) across various sizes of PM (12 nm–20 μm), but were elevated by resuspension from human activity, including cleaning. 

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3. Sensitivity of Regional WRF‐Chem Air Quality and Weather Simulations to Biomass‐Burning Emission Data Sets: A Case Study of the Impact of Canadian Wildfire on the US

   https://doi.org/10.1029/2025JD043944  

   Wu, Sicheng; Kumar, Rajesh; Li, Peiyuan; Kotamarthi, Rao; Collis, Scott; Shams, Shima; Sharma, Ashish (November 2025, Journal of Geophysical Research: Atmospheres)

   Abstract This study focuses on the period from June 26 to 29, 2023, when record‐breaking Canadian wildfires severely impacted air quality in the Midwest United States. Using the Weather Research and Forecasting Model with Chemistry (WRF‐Chem) and four biomass‐burning data sets (Fire Inventory from NCAR version 1, Fire Inventory from NCAR version 2.5, Quick Fire Emissions Data set [QFED], and Regional ABI‐VIIRS Emission), we analyzed aerosol transport from Canada to the US and assessed the model's accuracy in predicting , , and aerosol weather feedback. Model simulations were compared with ground‐based and remote sensing observations as well as field measurements from the Community Research on Climate and Urban Science (CROCUS) project. Our findings show that the movement of a low‐pressure system from the Great Lakes to the Atlantic, combined with the high‐pressure system over the Atlantic, caused the transport of aerosols from Canadian wildfires to the US. Results show WRF‐Chem significantly underestimated key atmospheric components: aerosol optical depth (AOD) by over 50%, by 65%–90% and peak concentrations by 50%–55% across four biomass burning data sets. Additionally, CO and concentrations were underpredicted. The substantial underestimation of led to an overestimation of temperature by up to 3.6C primarily due to excessive downward shortwave radiation, which resulted from the underestimation of direct aerosol effects and an increase in sensible heat flux. Among the biomass‐burning data sets, QFED produced the most accurate AOD and predictions due to improved wildfire emission estimates, leading to a 1.0 to 1.5C reduction in temperature overestimation during the daytime. These findings underscore the need for improving wildfire emission estimates for trace gases and aerosols to enhance air quality and weather feedback predictions. 

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4. Good wildfires in western U.S. forests (2010-2020)

   https://doi.org/10.1101/2024.12.06.627082  

   Balch, Jennifer K; McIntosh, Tyler L; Illangakoon, Nayani T; Cummins, Karen; Varner, J Morgan; Hansen, Winslow D; Marquis, Kate Dargan; Raymond, Crystal L; Harvey, Brian J; Platt, Rutherford V (December 2024, bioRxiv)

   Abstract Wildfires are integral for western US forests that have evolved with fire. Here we define “good wildfire” as areas that burn in an ecologically beneficial way, with a severity and return interval analogous to their historical fire regimes prior to European settlement. When severities match what an ecosystem historically experienced they can regulate forest structure while promoting regeneration, even in a warming climate¹. We quantified the amount of forested area (i.e., deciduous, conifer, or mixed forest types) burned with a severity and frequency matching its regime, and compared that to the area of prescribed burns in forests (2010-2020). Of forests that burned in the western US, 49% of the area burned as low-moderate severity good wildfire. High severity good wildfire (in systems that historically experienced this type of fire) represented an additional 9% of forest area burned, bringing the total area of good wildfire to 58% of forested area burned. The low-moderate severity good wildfires burned 3.1 million forest ha (N = 18,061 events), more than double the 1.4 million ha of prescribed burning (N = 24,817 events on federal land) over the same period. Knowing that fires are likely going to increase in frequency and area with warming², our key challenge will be promoting good wildfire while still protecting lives and property. 

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5. Stratospheric chlorine processing after the 2020 Australian wildfires derived from satellite data

   https://doi.org/10.1073/pnas.2213910120  

   Wang, Peidong; Solomon, Susan; Stone, Kane (March 2023, Proceedings of the National Academy of Sciences)

   The 2019 to 2020 Australian summer wildfires injected an amount of organic gases and particles into the stratosphere unprecedented in the satellite record since 2002, causing large unexpected changes in HCl and ClONO 2 . These fires provided a novel opportunity to evaluate heterogeneous reactions on organic aerosols in the context of stratospheric chlorine and ozone depletion chemistry. It has long been known that heterogeneous chlorine (Cl) activation occurs on the polar stratospheric clouds (PSCs; liquid and solid particles containing water, sulfuric acid, and in some cases nitric acid) that are found in the stratosphere, but these are only effective for ozone depletion chemistry at temperatures below about 195 K (i.e., largely in the polar regions during winter). Here, we develop an approach to quantitatively assess atmospheric evidence for these reactions using satellite data for both the polar (65 to 90°S) and the midlatitude (40 to 55°S) regions. We show that heterogeneous reactions apparently even happened at temperatures at 220 K during austral autumn on the organic aerosols present in 2020 in both regions, in contrast to earlier years. Further, increased variability in HCl was also found after the wildfires, suggesting diverse chemical properties among the 2020 aerosols. We also confirm the expectation based upon laboratory studies that heterogeneous Cl activation has a strong dependence upon water vapor partial pressure and hence atmospheric altitude, becoming much faster close to the tropopause. Our analysis improves the understanding of heterogeneous reactions that are important for stratospheric ozone chemistry under both background and wildfire conditions. 

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