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1. Photoelectron spectroscopy and thermochemistry of o -, m -, and p -methylenephenoxide anions

   https://doi.org/10.1039/C8CP05403G  

   Nelson, Daniel J.; Gichuhi, Wilson K.; Nichols, Charles M.; Bierbaum, Veronica M.; Lineberger, W. Carl; Lehman, Julia H. (October 2018, Physical Chemistry Chemical Physics)

   The anionic products following (H + H + ) abstraction from o -, m -, and p -methylphenol (cresol) are investigated using flowing afterglow-selected ion flow tube (FA-SIFT) mass spectrometry and anion photoelectron spectroscopy (PES). The PES of the multiple anion isomers formed in this reaction are reported, including those for the most abundant isomers, o -, m - and p -methylenephenoxide distonic radical anions. The electron affinity (EA) of the ground triplet electronic state of neutral m -methylenephenoxyl diradical was measured to be 2.227 ± 0.008 eV. However, the ground singlet electronic states of o - and p -methylenephenoxyl were found to be significantly stabilized by their resonance forms as a substituted cyclohexadienone, resulting in measured EAs of 1.217 ± 0.012 and 1.096 ± 0.007 eV, respectively. Upon electron photodetachment, the resulting neutral molecules were shown to have Franck–Condon active ring distortion vibrational modes with measured frequencies of 570 ± 180 and 450 ± 80 cm −1 for the ortho and para isomers, respectively. Photodetachment to excited electronic states was also investigated for all isomers, where similar vibrational modes were found to be Franck–Condon active, and singlet–triplet splittings are reported. The thermochemistry of these molecules was investigated using FA-SIFT combined with the acid bracketing technique to yield values of 341.4 ± 4.3, 349.1 ± 3.0, and 341.4 ± 4.3 kcal mol −1 for the o -, m -, and p -methylenephenol radicals, respectively. Construction of a thermodynamic cycle allowed for an experimental determination of the bond dissociation energy of the O–H bond of m -methylenephenol radical to be 86 ± 4 kcal mol −1 , while this bond is significantly weaker for the ortho and para isomers at 55 ± 5 and 52 ± 5 kcal mol −1 , respectively. Additional EAs and vibrational frequencies are reported for several methylphenyloxyl diradical isomers, the negative ions of which are also formed by the reaction of cresol with O − . 

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2. Evolution and future of urban ecological science: ecology in , of , and for the city

   https://doi.org/10.1002/ehs2.1229  

   Pickett, Steward T.; Cadenasso, Mary L.; Childers, Daniel L.; McDonnell, Mark J.; Zhou, Weiqi (July 2016, Ecosystem Health and Sustainability)
3. Stereoselective Synthesis of ( E )- and ( Z )-Isocyanoalkenes

   https://doi.org/10.1021/acs.orglett.2c03461  

   Tian, Huan; Holyoke, Caleb W.; Fleming, Fraser F. (December 2022, Organic Letters)
4. Relative hydrophilicities of cis and trans formamides

   https://doi.org/10.1073/pnas.1911331116  

   Li, Yong-Sheng; Escobar, Luis; Zhu, Yu-Jie; Cohen, Yoram; Ballester, Pablo; Rebek, Julius; Yu, Yang (October 2019, Proceedings of the National Academy of Sciences)

   Secondary formamides are widely encountered in biology and exist as mixtures of both cis and trans isomers. Here, we assess hydrophilicity differences between isomeric formamides through direct competition experiments. Formamides bearing long aliphatic chains were sequestered in a water-soluble molecular container having a hydrophobic cavity with an end open to the aqueous medium. NMR spectroscopic experiments reveal a modest preference (<1 kcal/mol) for aqueous solvation of the trans formamide terminals over the cis isomers. With diformamides, the supramolecular approach allows staging of intramolecular competition between short-lived species with subtle differences in hydrophobic properties. 

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5. Electronic Spectroscopy of cis - and trans - meta -Vinylbenzyl Radicals

   https://doi.org/10.1021/acs.jpca.1c04496  

   Ross, Sederra D.; Flores, Jonathan; Hewett, Daniel M.; Reilly, Neil J. (July 2021, The Journal of Physical Chemistry A)