More Like this

1. SZ–X-Ray Surface Brightness Fluctuations in the SPT-XMM Clusters

   https://doi.org/10.3847/1538-4357/adcd74  

   Romero, Charles E; Gaspari, Massimo; Schellenberger, Gerrit; Benson, Bradford A; Bleem, Lindsey E; Bulbul, Esra; Forman, William; Kraft, Ralph; Nulsen, Paul; Reichardt, Christian L; et al (May 2025, The Astrophysical Journal)

   Abstract The hot plasma in galaxy clusters, the intracluster medium, is expected to be shaped by subsonic turbulent motions, which are key for heating, cooling, and transport mechanisms. The turbulent motions contribute to the nonthermal pressure, which, if not accounted for, consequently imparts a hydrostatic mass bias. Accessing information about turbulent motions is thus of major astrophysical and cosmological interest. Characteristics of turbulent motions can be indirectly accessed through surface brightness fluctuations. This study expands on our pilot investigations of surface brightness fluctuations in the Sunyaev–Zel’dovich and in X-ray data by examining, for the first time, a large sample of 60 clusters using both SPT-SZ and XMM-Newton data and spans the redshift range 0.2 < z < 1.5, thus constraining the respective pressure and density fluctuations within 0.6R₅₀₀. We deem density fluctuations to be of sufficient quality for 32 clusters, finding mild correlations between the peak of the amplitude spectra of density fluctuations and various dynamical parameters. We infer turbulent velocities from density fluctuations with an average Mach number ${\mathcal{M}}_{\text{3D}}=0.52\pm 0.14$, in agreement with numerical simulations. For clusters with inferred turbulent Mach numbers from fluctuations in both pressure, ${\mathcal{M}}_{\text{P}}$, and density, ${\mathcal{M}}_{\rho }$, we find broad agreement between ${\mathcal{M}}_{\text{P}}$and ${\mathcal{M}}_{\rho }$. Our results suggest either a bimodal or a skewed unimodal Mach number distribution, with the majority of clusters being turbulence-dominated (subsonic) while the remainder are shock-dominated (supersonic). 

   more » « less
2. Cosmic-Ray Drag and Damping of Compressive Turbulence

   https://doi.org/10.3847/1538-4357/aceef9  

   Bustard, Chad; Oh, S. Peng (September 2023, The Astrophysical Journal)

   Abstract While it is well known that cosmic rays (CRs) can gain energy from turbulence via second-order Fermi acceleration, how this energy transfer affects the turbulent cascade remains largely unexplored. Here, we show that damping and steepening of the compressive turbulent power spectrum are expected once the damping time $t_{\mathrm{damp}}\sim \rho v^2/{\dot{E}}_{\mathrm{CR}}\propto E_{\mathrm{CR}}^{-1}$becomes comparable to the turbulent cascade time. Magnetohydrodynamic simulations of stirred compressive turbulence in a gas-CR fluid with diffusive CR transport show clear imprints of CR-induced damping, saturating at ${\dot{E}}_{\mathrm{CR}}\sim \widetilde{ϵ}$, where $\widetilde{ϵ}$is the turbulent energy input rate. In that case, almost all of the energy in large-scale motions is absorbed by CRs and does not cascade down to grid scale. Through a Hodge–Helmholtz decomposition, we confirm that purely compressive forcing can generate significant solenoidal motions, and we find preferential CR damping of the compressive component in simulations with diffusion and streaming, rendering small-scale turbulence largely solenoidal, with implications for thermal instability and proposed resonant scattering ofE≳ 300 GeV CRs by fast modes. When CR transport is streaming dominated, CRs also damp large-scale motions, with kinetic energy reduced by up to 1 order of magnitude in realisticE_CR∼E_gscenarios, but turbulence (with a reduced amplitude) still cascades down to small scales with the same power spectrum. Such large-scale damping implies that turbulent velocities obtained from the observed velocity dispersion may significantly underestimate turbulent forcing rates, i.e., $\widetilde{ϵ}\gg \rho v^3/L$. 

   more » « less
3. Stabilizing Ti ₃ C ₂ T _x MXene flakes in air by removing confined water

   https://doi.org/10.1073/pnas.2400084121  

   Fang, Hui; Thakur, Anupma; Zahmatkeshsaredorahi, Amirhossein; Fang, Zhenyao; Rad, Vahid; Shamsabadi, Ahmad A; Pereyra, Claudia; Soroush, Masoud; Rappe, Andrew M; Xu, Xiaoji G; et al (July 2024, Proceedings of the National Academy of Sciences)

   MXenes have demonstrated potential for various applications owing to their tunable surface chemistry and metallic conductivity. However, high temperatures can accelerate MXene film oxidation in air. Understanding the mechanisms of MXene oxidation at elevated temperatures, which is still limited, is critical in improving their thermal stability for high-temperature applications. Here, we demonstrate that Ti ${}_3$C ${}_2$T ${}_x$MXene monoflakes have exceptional thermal stability at temperatures up to 600 ${}^{°}$C in air, while multiflakes readily oxidize in air at 300 ${}^{°}$C. Density functional theory calculations indicate that confined water between Ti ${}_3$C ${}_2$T ${}_x$flakes has higher removal energy than surface water and can thus persist to higher temperatures, leading to oxidation. We demonstrate that the amount of confined water correlates with the degree of oxidation in stacked flakes. Confined water can be fully removed by vacuum annealing Ti ${}_3$C ${}_2$T ${}_x$films at 600 ${}^{°}$C, resulting in substantial stability improvement in multiflake films (can withstand 600 ${}^{°}$C in air). These findings provide fundamental insights into the kinetics of confined water and its role in Ti ${}_3$C ${}_2$T ${}_x$oxidation. This work enables the use of stable monoflake MXenes in high-temperature applications and provides guidelines for proper vacuum annealing of multiflake films to enhance their stability. 

   more » « less
4. Development of broad modulus profile upon polymer–polymer interface formation between immiscible glassy–rubbery domains

   https://doi.org/10.1073/pnas.2312533120  

   Gagnon, Yannic J; Burton, Justin C; Roth, Connie B (January 2024, Proceedings of the National Academy of Sciences)

   Interfaces of glassy materials such as thin films, blends, and composites create strong unidirectional gradients to the local heterogeneous dynamics that can be used to elucidate the length scales and mechanisms associated with the dynamic heterogeneity of glasses. We focus on bilayer films of two different polymers with very different glass transition temperatures ( $T_{\text{g}}$) where previous work has demonstrated a long-range (∼200 nm) profile in local $T_{\text{g}}\left(z\right)$is established between immiscible glassy and rubbery polymer domains when the polymer–polymer interface is formed to equilibrium. Here, we demonstrate that an equally long-ranged gradient in local modulus $\tilde{G}\left(z\right)$is established when the polymer–polymer interface ( $\approx$5 nm) is formed between domains of glassy polystyrene (PS) and rubbery poly(butadiene) (PB), consistent with previous reports of a broad $T_{\text{g}}\left(z\right)$profile in this system. A continuum physics model for the shear wave propagation caused by a quartz crystal microbalance across a PB/PS bilayer film is used to measure the viscoelastic properties of the bilayer during the evolution of the PB/PS interface showing the development of a broad gradient in local modulus $\tilde{G}\left(z\right)$spanning $\approx$180 nm between the glassy and rubbery domains of PS and PB. We suggest these broad profiles in $T_{\text{g}}\left(z\right)$and $\tilde{G}\left(z\right)$arise from a coupling of the spectrum of vibrational modes across the polymer–polymer interface as a result of acoustic impedance matching of sound waves with $\lambda \sim 5$nm during interface broadening that can then trigger density fluctuations in the neighboring domain. 

   more » « less
5. Structural phase purification of bulk HfO ₂ :Y through pressure cycling

   https://doi.org/10.1073/pnas.2312571121  

   Musfeldt, J. L.; Singh, Sobhit; Fan, Shiyu; Gu, Yanhong; Xu, Xianghan; Cheong, S.-W.; Liu, Z.; Vanderbilt, David; Rabe, Karin M. (January 2024, Proceedings of the National Academy of Sciences)

   We combine synchrotron-based infrared absorption and Raman scattering spectroscopies with diamond anvil cell techniques and first-principles calculations to explore the properties of hafnia under compression. We find that pressure drives HfO ${}_2$:7%Y from the mixed monoclinic ( $P{2}_1/c$) $+$antipolar orthorhombic ( $\mathit{Pbca}$) phase to pure antipolar orthorhombic ( $\mathit{Pbca}$) phase at approximately 6.3 GPa. This transformation is irreversible, meaning that upon release, the material is kinetically trapped in the $\mathit{Pbca}$metastable state at 300 K. Compression also drives polar orthorhombic ( $Pca{2}_1$) hafnia into the tetragonal ( $P{4}_2/nmc$) phase, although the latter is not metastable upon release. These results are unified by an analysis of the energy landscape. The fact that pressure allows us to stabilize targeted metastable structures with less Y stabilizer is important to preserving the flat phonon band physics of pure HfO ${}_2$. 

   more » « less