Achiral metasurfaces with near-field optical chirality have attracted great attention in molecular sensing and chiral emission control. Here, the circular dichroism (CD) response of an achiral metasurface induced by spatially selective coupling with polymethyl methacrylate (PMMA) molecules is demonstrated. A designed achiral metasurface with a V-shaped resonator exhibits large optical chirality with a strongly dissymmetric distribution under circular polarization. By introducing a PMMA molecule layer on top of the metasurface, which covers the area with large optical chirality, CD in absorption of 0.38 and a dissymmetric factor of optical chiralitygcof 0.16 are obtained. Furthermore, an analysis of the coupled harmonic oscillator model reveals stronger coupling strength between the PMMA layer and the metasurface under RCP incidence, compared to the LCP case. Moreover, it is shown that the far-field CD response of the metasurface is linearly correlated with the dissymmetric near-field optical chirality distribution. The demonstrated results present the potential for advancing applications in chiral molecule vibrational sensing, thermal emission control, and infrared chiral imaging.
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This content will become publicly available on November 5, 2025
Probing Raman enhancements for a colloidal metasurface with optical gap distances in the quantum regime
Metasurface-enhanced Raman spectroscopy is used to characterize theclassical,crossover, andquantumregimes of a colloidal metasurface as a function of gap distance.
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- Award ID(s):
- 2011924
- PAR ID:
- 10589243
- Publisher / Repository:
- RSC
- Date Published:
- Journal Name:
- RSC Applied Interfaces
- Volume:
- 1
- Issue:
- 6
- ISSN:
- 2755-3701
- Page Range / eLocation ID:
- 1410 to 1418
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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