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1. Smooth, homogeneous, high-purity Nb ₃ Sn superconducting RF resonant cavity by seed-free electrochemical synthesis

   https://doi.org/10.1088/1361-6668/acf5ab  

   Sun, Zeming; Baraissov, Zhaslan; Porter, Ryan D.; Shpani, Liana; Shao, Yu-Tsun; Oseroff, Thomas; Thompson, Michael O.; Muller, David A.; Liepe, Matthias U. (September 2023, Superconductor Science and Technology)

   Abstract Workbench-size particle accelerators, enabled by Nb₃Sn-based superconducting radio-frequency (SRF) cavities, hold the potential of driving scientific discovery by offering a widely accessible and affordable source of high-energy electrons and x-rays. Thin-film Nb₃Sn RF superconductors with high quality factors, high operation temperatures, and high-field potentials are critical for these devices. However, surface roughness, non-stoichiometry, and impurities in Nb₃Sn deposited by conventional Sn-vapor diffusion prevent them from reaching their theoretical capabilities. Here we demonstrate a seed-free electrochemical synthesis that pushes the limit of chemical and physical properties in Nb₃Sn. Utilization of electrochemical Sn pre-deposits reduces the roughness of converted Nb₃Sn by five times compared to typical vapor-diffused Nb₃Sn. Quantitative mappings using chemical and atomic probes confirm improved stoichiometry and minimized impurity concentrations in electrochemically synthesized Nb₃Sn. We have successfully applied this Nb₃Sn to the large-scale 1.3 GHz SRF cavity and demonstrated ultra-low BCS surface resistances at multiple operation temperatures, notably lower than vapor-diffused cavities. Our smooth, homogeneous, high-purity Nb₃Sn provides the route toward high efficiency and high fields for SRF applications under helium-free cryogenic operations. 

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2. Impact of submicron ${\mathrm{Nb}}_3\mathrm{Sn}$ stoichiometric surface defects on high-field superconducting radiofrequency cavity performance

   https://doi.org/10.1103/PhysRevResearch.6.043133  

   Willson, Sarah A; Harbick, Aiden V; Shpani, Liana; Do, Van; Lew-Kiedrowska, Helena; Liepe, Matthias U; Transtrum, Mark K; Sibener, S J (November 2024, Physical Review Research)

   ${\mathrm{Nb}}_3\mathrm{Sn}$film coatings have the potential to drastically improve the accelerating performance of Nb superconducting radiofrequency (SRF) cavities in next-generation linear particle accelerators. Unfortunately, persistent ${\mathrm{Nb}}_3\mathrm{Sn}$stoichiometric material defects formed during fabrication limit the cryogenic operating temperature and accelerating gradient by nucleating magnetic vortices that lead to premature cavity quenching. The SRF community currently lacks a predictive model that can explain the impact of chemical and morphological properties of ${\mathrm{Nb}}_3\mathrm{Sn}$defects on vortex nucleation and maximum accelerating gradients. Both experimental and theoretical studies of the material and superconducting properties of the first 100 nm of ${\mathrm{Nb}}_3\mathrm{Sn}$surfaces are complicated by significant variations in the volume distribution and topography of stoichiometric defects. This work contains a coordinated experimental study with supporting simulations to identify how the observed chemical composition and morphology of certain Sn-rich and Sn-deficient surface defects can impact the SRF performance. ${\mathrm{Nb}}_3\mathrm{Sn}$films were prepared with varying degrees of stoichiometric defects, and the film surface morphologies were characterized. Both Sn-rich and Sn-deficient regions were identified in these samples. For Sn-rich defects, we focus on elemental Sn islands that are partially embedded into the ${\mathrm{Nb}}_3\mathrm{Sn}$film. Using finite element simulations of the time-dependent Ginzburg-Landau equations, we estimate vortex nucleation field thresholds at Sn islands of varying size, geometry, and embedment. We find that these islands can lead to significant SRF performance degradation that could not have been predicted from the ensemble stoichiometry alone. For Sn-deficient ${\mathrm{Nb}}_3\mathrm{Sn}$surfaces, we experimentally identify a periodic nanoscale surface corrugation that likely forms because of extensive Sn loss from the surface. Simulation results show that the surface corrugations contribute to the already substantial drop in the vortex nucleation field of Sn-deficient ${\mathrm{Nb}}_3\mathrm{Sn}$surfaces. This work provides a systematic approach for future studies to further detail the relationship between experimental ${\mathrm{Nb}}_3\mathrm{Sn}$growth conditions, stoichiometric defects, geometry, and vortex nucleation. These findings have technical implications that will help guide improvements to ${\mathrm{Nb}}_3\mathrm{Sn}$fabrication procedures. Our outlined experiment-informed theoretical methods can assist future studies in making additional key insights about ${\mathrm{Nb}}_3\mathrm{Sn}$stoichiometric defects that will help build the next generation of SRF cavities and support related superconducting materials development efforts. Published by the American Physical Society2024 

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3. Direct current magnetic Hall probe technique for measurement of field penetration in thin film superconductors for superconducting radio frequency resonators

   https://doi.org/10.1063/5.0083309  

   Senevirathne, I. H.; Gurevich, A.; Delayen, J. R. (May 2022, Review of Scientific Instruments)

   Superconducting Radio Frequency (SRF) cavities used in particle accelerators are typically formed from or coated with superconducting materials. Currently, high purity niobium is the material of choice for SRF cavities that have been optimized to operate near their theoretical field limits. This brings about the need for significant R & D efforts to develop next generation superconducting materials that could outperform Nb and keep up with the demands of new accelerator facilities. To achieve high quality factors and accelerating gradients, the cavity material should be able to remain in the superconducting Meissner state under a high RF magnetic field without penetration of quantized magnetic vortices through the cavity wall. Therefore, the magnetic field at which vortices penetrate a superconductor is one of the key parameters of merit of SRF cavities. Techniques to measure the onset of magnetic field penetration on thin film samples need to be developed to mitigate the issues with the conventional magnetometry measurements that are strongly influenced by the film orientation and shape and edge effects. In this work, we report the development of an experimental setup to measure the field of full flux penetration through films and multi-layered superconductors. Our system combines a small superconducting solenoid that can generate a magnetic field of up to 500 mT at the sample surface and three Hall probes to detect the full flux penetration through the superconductor. This setup can be used to study alternative materials that could potentially outperform niobium, as well as superconductor–insulator–superconductor (SIS) multilayer coatings on niobium. 

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4. Analysis of thermal grooving effects on vortex penetration in vapor-diffused Nb ₃ Sn

   https://doi.org/10.1088/1361-6668/ad9416  

   Lechner, Eric M; Trofimova, Olga; Angle, Jonathan W; DiGuilio, Madison C; Pudasaini, Uttar (November 2024, Superconductor Science and Technology)

   Abstract While Nb₃Sn theoretically offers better superconducting radio-frequency (RF) cavity performance (Q₀and $E_{\mathrm{acc}}$) to Nb at any given temperature, peak RF magnetic fields consistently fall short of the ∼400 mT prediction. The relatively rough topography of vapor-diffused Nb₃Sn is widely conjectured to be one of the factors that limit the attainable performance of Nb₃Sn-coated Nb cavities prepared via Sn vapor diffusion. Here we investigate the effect of coating duration on the topography of vapor-diffused Nb₃Sn on Nb and calculate the associated magnetic field enhancement and superheating field suppression factors using atomic force microscopy topographies. It is shown that the thermally grooved grain boundaries are major defects which may contribute to a substantial decrease in the achievable accelerating field. The severity of these grooves increases with total coating duration due to the deepening of thermal grooves during the coating process. 

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5. MEASUREMENT OF THE MAGNETIC FIELD PENETRATION INTO SUPERCONDUCTING THIN FILMS

   https://doi.org/10.18429/JACoW-SRF2019-THP050  

   I. H. Senevirathne, G. Ciovati (November 2019, 19th Int. Conf. on RF Superconductivity, SRF2019, Dresden, Germany)

   The magnetic field at which first flux penetrates is a fundamental parameter characterizing superconducting materials for SRF cavities. Therefore, an accurate technique is needed to measure the penetration of the magnetic field directly. The conventional magnetometers are inconvenient for thin superconducting film measurements because these measurements are strongly influenced by orientation, edge and shape effects. In order to measure the onset of field penetration in bulk, thin films and multi-layered superconductors, we have designed, built and calibrated a system combining a small superconducting solenoid capable of generating surface magnetic field higher than 500 mT and Hall probe to detect the first entry of vortices. This setup can be used to study various promising alternative materials to Nb, especially SIS multilayer coatings on Nb that have been recently proposed to delay the vortex penetration in Nb surface. In this paper, the system will be described, and calibration will be presented. 

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