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Title: Ferrimagnetism and half-metallicity in Cr-substituted Mn 4–x Cr x Al 11
Abstract Single crystals of disordered Mn4–xCrxAl11have been synthesized via the flux method. EDS on several crystals of various sizes and shapes revealed an average molar ratio of 17:9:74 for Mn:Cr:Al, while x-ray diffraction on three different crystals yield compositions Mn2.26Cr1.74Al11(Mn4–xCrxAl11,x= 1.74), Mn0.83Cr3.17Al11, and Mn1.07Cr2.93Al11. This compound crystallizes in space group P 1 ¯ , isostructural with both Mn4Al11and Cr4Al11. Magnetic measurements on several crystals show that this disordered compound is ferrimagnetic with a low effective moment of μ eff 1.012 ± 0.004 μ B / f . u . and a non-reachable transition temperature. Density functional theory calculations display opening of a bandgap in the spin-up channel near the Fermi level with increasing Cr content, an indication of half-metallicity.  more » « less
Award ID(s):
2047251 2328830
PAR ID:
10595924
Author(s) / Creator(s):
; ; ; ;
Publisher / Repository:
IOP Science
Date Published:
Journal Name:
Journal of Physics: Condensed Matter
Volume:
37
Issue:
23
ISSN:
0953-8984
Page Range / eLocation ID:
235704
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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