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6061 aluminum composites with 0.5 and 1 vol. % graphene nanoplatelets as well as 1 and 2 vol. % activated nanocarbon were manufactured by a powder metallurgy method. Scanning electron microscopy and Raman spectroscopy were used to study the morphology, structure, and distribution of nanocarbon reinforcements in the composite samples. Density Functional Theory (DFT) calculations were performed to understand the aluminum-carbon bonding and the effects of hybridized networks of carbon atoms on nanocarbon aluminum matrix composites. Scanning electron microscopy showed the good distribution and low agglomeration tendencies of nanoparticles in the composites. The formation of secondary phases at the materials interface was not detected in the hot-pressed composites. Raman spectroscopy showed structural changes in the reinforced composites after the manufacturing process. The results from Density Functional Theory calculations suggest that it is thermodynamically possible to form carbon rings in the aluminum matrix, which may be responsible for the improved mechanical strength. Our results also suggest that these carbon networks are graphene-like, which also agrees with the Raman spectroscopy data. Micro-Vickers hardness and compressive tests were used to determine the mechanical properties of the samples. Composites presented enhanced hardness, yield and ultimate strength compared to the 6061 aluminum alloy with no nanocarbon reinforcement. Ductility was also affected, as shown by the reduction in elongation and by the number of dimples in the fractured surfaces of the materials.
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Atomic composition/configuration dependent bulk moduli of Al–C composites
Embedding carbon in metals has long been known to enhance the mechanical properties of metal carbon composites. We report the possibility of growing Al–C composites by the hot isostatic pressing method, with carbon embedded into an Al lattice in graphitic form without the formation of Al4C3. Raman spectroscopy confirms the formation of sp2-hybridized carbon clusters in the aluminum lattice. The bulk moduli of the samples were measured to be between 60 and 100 GPa. From the results of first principles density functional theory calculations, we show that the formation of sp2-hybridized carbon clusters is more stable than having isolated C scatterers in aluminum. Our results show that the extended network of C clusters shows a higher bulk modulus while isolated scattering centers could lower the bulk modulus. We explain this behavior with the analysis of total charge distribution. Localization of charge density decreases materials’ ability to respond to external stress, thus showing a reduced bulk modulus. Some defect configuration may reduce the symmetry while others keep the symmetry of the host configuration even for the same chemical composition of Al–C composites.
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- Award ID(s):
- 2138459
- PAR ID:
- 10597321
- Publisher / Repository:
- American Institute of Physics
- Date Published:
- Journal Name:
- AIP Advances
- Volume:
- 12
- Issue:
- 11
- ISSN:
- 2158-3226
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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