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Halogens (F, Cl, Br, I) are primary components of volcanic gas emissions and play an essential role in continental arc magmatic environments due to their solubility in fluids that generate metallic ore deposits. Despite their ubiquity, the behavior and budget of halogens in continental arc environments are poorly constrained. We investigated the plutonic and volcanic halogen budgets in intermediate-to-felsic igneous rocks (56–77 wt% SiO2) from the Sierra Nevada (California) - a Mesozoic continental arc where plutonic and volcanic outcrops can be correlated via their geographic, compositional, and geochronologic framework. We measured the halogen concentrations of bulk rock powders and their leachates via ion chromatography (F, Cl) and ICP-MS (Br, I). Halogen concentrations in our rock powders range between 107–727 μg/g F, 13–316 μg/g Cl, 2–323 ng/g Br, and 1–69 ng/g I. In contrast, leachates yielded 3–4 orders of magnitude less Cl and F, one order of magnitude less I, and similar amounts of Br compared to their corresponding bulk rocks. Preliminary data show no significant differences between volcanic and plutonic samples, suggesting that halogen concentrations in these rocks are insensitive to shallow fractionation. Although F and I exhibit no correlation with major element compositions, Cl and Br display negative trends with increasing SiO2 and K2O, and positive trends with increasing Fe2O3T, MnO, MgO, CaO, and TiO2, suggesting mafic minerals as important hosts of structurally bound halogens. Overall, Sierran plutonic rocks display low halogen contents (max. F, Cl = 727, 315 μg/g), consistent with biotite- and apatite-bearing granitoids reported in [1]. This work suggests that halogens do not preferentially enrich in shallow plutonic or volcanic portions of a continental arc system and that mafic mineral phases likely serve as primary reservoirs of these elements in intermediate-to-felsic igneous rocks. These hypotheses will be further investigated in future work through in-situ analysis of halogen concentrations in crystals. [1] Teiber, Marks, Wenzel, Siebel, Altherr & Markl (2014), Chemical Geology, vol. 374–375, pp. 92–109, doi: 10.1016/j.chemgeo.2014.03.006
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This content will become publicly available on November 1, 2025
Halogen enrichment on the continental surface: a perspective from loess
Halogen (F, Cl, Br, and I) concentrations for 129 loess samples from worldwide localities yield geometric means of 517 ± 53 μg/g F, 150 ± 20 μg/g Cl, 1.58 ± 0.16 μg/g Br, 1.16 ± 0.11 μg/g I (2 standard errors). These concentrations, notably for Br and I, are substantially higher than previous estimates for the average upper continental crystalline bedrocks, with enrichment factors of 1.3 +0.7/−0.4 (F), 1.8 +2.4/−0.8 (Cl), 3.8 +1.3/−1.0 (Br), and 39 +71/−16 (I) (95%confidence), documenting enrichment of halogens on the continental surface. These surface halogens are likely sourced from the oceans and may be influenced by climate fluctuations. Halogen ratios (Br/Cl, I/Cl, and Br/I) in loess are similar to those of organic-rich soils/sediments from both terrigenous and marine settings, suggesting that terrigenous and marine organic matter have indistinguishable halogen ratios. The Br/I ratios differ from those in the fine grained matrix of glacial diamictites, indicating that another process (beyond biological influence) is responsible for fractionating halogens in the upper continental crust. Using a mixing model, we calculate that over 80–90 % of loess originates from crystalline bedrocks, while the remainder (<10–20 %) derives from the halogen- and organic-rich sedimentary cover or other sources (e.g., marine aerosols).
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- Award ID(s):
- 2321367
- PAR ID:
- 10598030
- Publisher / Repository:
- European Association of Geochemistry
- Date Published:
- Journal Name:
- Geochemical Perspectives Letters
- Volume:
- 32
- ISSN:
- 2410-339X
- Page Range / eLocation ID:
- 52 to 57
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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