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Achieving the co-assembly of more than one component represents an important challenge in the drive to create functional self-assembled nanomaterials. Multicomponent nanomaterials comprised of several discrete, spatially sorted domains of components with high degrees of internal order are particularly important for applications such as optoelectronics. In this work, single-walled carbon nanotubes (SWNTs) were threaded through the inner channel of nanotubes formed by the bolaamphiphilic self-assembly of a naphthalenediimide-lysine (NDI-Bola) monomer. The self-assembly process was driven by electrostatic interactions, as indicated by ζ -potential measurements, and cation–π interactions between the surface of the SWNT and the positively charged, NDI-Bola nanotube interior. To increase the threading efficiency, the NDI-Bola nanotubes were fragmented into shortened segments with lengths of <100 nm via sonication-induced shear, prior to co-assembly with the SWNTs. The threading process created an initial composite nanostructure in which the SWNTs were threaded by multiple, shortened segments of the NDI-Bola nanotube that progressively re-elongated along the SWNT surface into a continuous radial coating around the SWNT. The resultant composite structure displayed NDI-Bola wall thicknesses twice that of the parent nanotube, reflecting a bilayer wall structure, as compared to the monolayer structure of the parent NDI-Bola nanotube. As a final, co-axial outer layer, poly( p -phenyleneethynylene) (PPE-SO 3 Na, M W = 5.76 × 10 4 , PDI – 1.11) was wrapped around the SWNT/NDI-Bola composite resulting in a three-component (SWNT/NDI-Bola/PPE-SO 3 Na) composite nanostructure.
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Hydrogel Composition Effects on Performance as Single-Walled Carbon Nanotube Purification Media
Hydrogel microsphere media allows for postsynthetic purification of single-walled carbon nanotubes (SWNTs), affording characterization and application of their unique (n,m) chirality-dependent properties. This work reports the characterization of five hydrogel resins, Sephacryl S-100, S-200, S-300, S-400, and S-500, and the implementation of each as a SWNT purification medium. The physiochemical properties of each resin were explored spectroscopically through elemental analyses and with both light and electron microscopy. Both surface porosity and hydrogel swelling ratio were found to increase as the concentration of component allyl dextran (aDEX) decreased, each with an increasing Sephacryl S-number. Conversely, invariant properties included a hydrogel microsphere size distribution and concentrations of components methylenebisacrylamide and ammonium persulfate. When employed within gel-based SWNT purification schemes in overloading conditions, Sephacryl formulations of larger S-number adsorbed fewer SWNTs, but the chirality dependence of SWNT adsorption and elution was approximately consistent across all resins. In underloading conditions, approximately one-third of introduced SWNTs passed through each resin unabsorbed, while the resins showed varying chirality-dependent adsorption efficiencies. These observations collectively identify aDEX-rich gel regions as being responsible for SWNT purification, along with a SWNT-exclusive parameter other than chirality (speculated as length) that convolutes the effectiveness of gel-based single-chirality purification.
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- Award ID(s):
- 2107748
- PAR ID:
- 10599309
- Publisher / Repository:
- ACS Publications
- Date Published:
- Journal Name:
- The Journal of Physical Chemistry C
- Volume:
- 128
- Issue:
- 38
- ISSN:
- 1932-7447
- Page Range / eLocation ID:
- 15923 to 15936
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1021/acs.jpcc.4c03765
