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We analyzed the deuterium composition of individual plant-waxes in lake sediments from 28 watersheds that span a range of precipitation D/H, vegetation types and climates. The apparent isotopic fractionation (εa) between plant-wax n-alkanes and precipitation differs with watershed ecosystem type and structure, and decreases with increasing regional aridity as measured by enrichment of 2H and 18O associated with evaporation of lake waters. The most negative εa values represent signatures least affected by aridity; these values were −125 ± 5‰ for tropical evergreen and dry forests, −130‰ for a temperate broadleaf forest, −120 ± 9‰ for the high-altitude tropical páramo (herbs, shrubs and grasses), and −98 ± 6‰ for North American montane gymnosperm forests. Minimum εa values reflect ecosystem-dependent differences in leaf water enrichment and soil evaporation. Slopes of lipid/lake water isotopic enrichments differ slightly with ecosystem structure (i.e. open shrublands versus forests) and overall are quite small (slopes = 0–2), indicating low sensitivity of lipid δD variations to aridity compared with coexisting lake waters. This finding provides an approach for reconstructing ancient precipitation signatures based on plant-wax δD measurements and independent proxies for lake water changes with regional aridity. To illustrate this approach, we employ paired plant-wax δD and carbonate-δ18O measurements on lake sediments to estimate the isotopic composition of Miocene precipitation on the Tibetan plateau.
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Constraints on the salinity–oxygen isotope relationship in the central tropical Pacific Ocean
Uncertainties surround the relationship between salinity and the stable isotopic composition of seawater, largely due to a dearth of modern seawater isotope data. Here we report 191 new, paired measurements of salinity and seawater oxygen isotopes (δ18Osw) taken from the central tropical Pacific in May 2012, from the surface to 4600 m depth. We observe significant correlations between δ18Osw and salinity across the study region, with slopes ranging from 0.23 to 0.31‰/psu for the mixed layer, and 0.35–0.42‰/psu for waters between the mixed layer and 500 m depth. When considering δ18Osw–salinity across averages of individual water masses in the region, slopes range from 0.21 to 0.40‰/psu, albeit with appreciable scatter. Surface salinity and δ18Osw data corresponding to the North Equatorial Countercurrent are significantly higher than previously observed, which we attribute to a weak westerly current and dry conditions in the region during the May 2012 cruise. Subsurface (80–500 m) salinity values from 2012 are significantly lower than corresponding values from pre-existing regional data, highlighting a different latitudinal sampling distribution, while subsurface δ18Osw is not significantly different. Thus, in May 2012, δ18Osw in this region could not be used to distinguish between subsurface water masses of different salinities. Unlike other regions where the surface ‘freshwater endmember’ is close to the δ18O value of regional precipitation, the freshwater endmember implied by our dataset (− 10.38‰) is consistent with a strong evaporative influence. Paired δ18O–δD values of precipitation and surface seawaters have similar slopes (5.0, 5.1), and relatively low intercepts (1.4, 0.8) indicating isotopic variability in both reservoirs is also partly controlled by evaporation.
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- Award ID(s):
- 1158886
- PAR ID:
- 10616623
- Publisher / Repository:
- Marine Chemistry
- Date Published:
- Journal Name:
- Marine Chemistry
- Volume:
- 161
- Issue:
- C
- ISSN:
- 0304-4203
- Page Range / eLocation ID:
- 26-33
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1016/j.marchem.2014.02.001
