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1. Relevance of the Nuclear Structure of the Stable Ge Isotopes to the Neutrino-less Double-Beta Decay of ⁷⁶ Ge

   https://doi.org/10.1051/epjconf/202023204011  

   Yates, S. W.; Peters, E. E.; Crider, B. P.; Mukhopadhyay, S.; Ramirez, A. P.; Mitchell, A.J.; Pavetich, S.; Koll, D. (January 2020, EPJ Web of Conferences)

   Gamma-ray detection following the inelastic neutron scattering reaction on isotopically enriched material was used to study the nuclear structure of 74 Ge. From these measurements, low-lying, low-spin excited states were characterized, new states and their decays were identified, level lifetimes were measured with the Doppler-shift attenuation method (DSAM), multipole mixing ratios were established, and transition probabilities were determined. New structural features in 74 Ge were identified, and the reanalysis of older 76 Ge data led to the placement of the 2 + member of the intruder band. In addition, a number of previously placed states in 74 Ge were shown not to exist. A procedure for future work, which will lead to meaningful data for constraining calculations of the neutrinoless double-beta decay matrix element, is suggested. 

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2. Photodriven Elimination of Chlorine From Germanium and Platinum in a Dinuclear Pt ^II →Ge ^IV Complex

   https://doi.org/10.1002/anie.202107485  

   Karimi, Mohammadjavad; Tabei, Elham S.; Fayad, Remi; Saber, Mohamed R.; Danilov, Evgeny O.; Jones, Cameron; Castellano, Felix N.; Gabbaï, François P. (September 2021, Angewandte Chemie International Edition)

   Abstract Searching for a connection between the two‐electron redox behavior of Group‐14 elements and their possible use as platforms for the photoreductive elimination of chlorine, we have studied the photochemistry of [(o‐(Ph₂P)C₆H₄)₂Ge^IVCl₂]Pt^IICl₂and [(o‐(Ph₂P)C₆H₄)₂ClGe^III]Pt^IIICl₃, two newly isolated isomeric complexes. These studies show that, in the presence of a chlorine trap, both isomers convert cleanly into the platinum germyl complex [(o‐(Ph₂P)C₆H₄)₂ClGe^III]Pt^ICl with quantum yields of 1.7 % and 3.2 % for the Ge^IV–Pt^IIand Ge^III–Pt^IIIisomers, respectively. Conversion of the Ge^IV–Pt^IIisomer into the platinum germyl complex is a rare example of a light‐induced transition‐metal/main‐group‐element bond‐forming process. Finally, transient‐absorption‐spectroscopy studies carried out on the Ge^III–Pt^IIIisomer point to a ligand arene–Cl^.charge‐transfer complex as an intermediate. 

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3. Unveiling New States in ⁹⁸ Zr: Insights from β -decay and γ-γ Angular-Correlation Studies

   https://doi.org/10.1051/epjconf/202532901012  

   Mashtakov, K R; Garrett, P E; Olaizola, B; Andreoiu, C; Ball, G C; Bender, P; Bildstein, V; Chester, A; Cross, D S; Dawkins, H; et al (January 2025, EPJ Web of Conferences)

   Jentschel, M (Ed.)

   The nuclear structure of the⁹⁸Zr nucleus was studied through theβ⁻decay of⁹⁸Y_g.s.at the TRIUMF-ISAC facility. The use of the 8π γ-ray spectrometer with its ancillary detectors SCEPTAR and PACES enabled γ-γ and γ-e⁻coincidence measurements as well as γ-γ angular correlations. The level spin assignments and transition mixing ratios obtained in this study were in good agreement with previous results. Furthermore, 12 previously unknown states in the low-energy region of⁹⁸Zr were identified, including the 0⁺₅and 0⁺₆levels at 2418 and 2749 keV, respectively. The 2⁺and I=1 natures for multiple newly observed and previously known (but not firmly assigned) states have been established. Additionally, the previously assumed pureE2 character of the 2⁺₂→ 2⁺₁367.8-keV transition was confirmed. 

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4. Ho ³⁺ doped low-phonon single crystals and chalcogenide glasses for mid-IR source application

   https://doi.org/10.1364/OME.487911  

   Brown, Ei_Ei; Fleischman, Zackery_D; McKay, Jason; Merkle, Larry; Hommerich, Uwe; Palosz, Witold; Trivedi, Sudhir; Dubinskii, Mark (April 2023, Optical Materials Express)

   A comparative study was conducted to investigate the 3.9 µm mid-IR emission properties of Ho³⁺doped NaYF₄and CsCdCl₃crystals as well as Ho³⁺doped Ga₂Ge₅S₁₃glass. Following optical excitation at ∼890 nm, all the studied materials exhibited broad mid-IR emissions centered at ∼3.9 µm at room temperature. The mid-IR emission at 3.9 µm, originating from the⁵I₅→⁵I₆transition, showed long emission lifetime values of ∼16.5 ms and ∼1.61 ms for Ho³⁺doped CsCdCl₃crystal and Ga₂Ge₅S₁₃glass, respectively. Conversely, the Ho³⁺doped NaYF₄crystal exhibited a relatively short lifetime of ∼120 µs. Temperature dependent decay time measurements were performed for the⁵I₅excited state for all three samples. The results showed that the emission lifetimes of Ho³⁺:CsCdCl₃and Ho³⁺:Ga₂Ge₅S₁₃were nearly temperature independent over the range studied, while significant emission quenching of the⁵I₅level was observed in Ho³⁺:NaYF₄. The temperature dependence of the multi-phonon relaxation rate for 3.9 µm mid-IR emission in Ho³⁺:NaYF₄crystal was determined. The room temperature stimulated emission cross-sections for all three samples were calculated using the Füchtbauer-Landenburg equation. Furthermore, the results of Judd-Ofelt analysis are presented and discussed. 

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5. New Constraints for Supernova Models from Presolar Silicon Carbide X Grains with Very High ²⁶ Al/ ²⁷ Al Ratios

   https://doi.org/10.3847/2041-8213/acb157  

   Hoppe, Peter; Leitner, Jan; Pignatari, Marco; Amari, Sachiko (February 2023, The Astrophysical Journal Letters)

   Abstract We report C, N, Mg-Al, Si, and S isotope data of six 1–3μm-sized SiC grains of Type X from the Murchison CM2 chondrite, believed to have formed in the ejecta of core-collapse supernova (CCSN) explosions. Their C, N, and Si isotopic compositions are fully compatible with previously studied X grains. Magnesium is essentially monoisotopic²⁶Mg which gives clear evidence for the decay of radioactive²⁶Al. Inferred initial²⁶Al/²⁷Al ratios are between 0.6 and 0.78 which is at the upper end of previously observed ratios of X grains. Contamination with terrestrial or solar system Al apparently is low or absent, which makes the X grains from this study particularly interesting and useful for a quantitative comparison of Al isotope data with predictions from supernova models. The consistently high²⁶Al/²⁷Al ratios observed here may suggest that the lower²⁶Al/²⁷Al ratios of many X grains from the literature are the result of significant Al contamination and in part also of an improper quantification of²⁶Al. The real dispersion of²⁶Al/²⁷Al ratios in X grains needs to be explored by future studies. The high observed²⁶Al/²⁷Al ratios in this work provide a crucial constraint for the production of²⁶Al in CCSN models. We explored different CCSN models, including both “classical” and H ingestion CCSN models. It is found that the classical models cannot account for the high²⁶Al/²⁷Al ratios observed here; in contrast, H ingestion models are able to reproduce the²⁶Al/²⁷Al ratios along with C, N, and Si isotopic ratios reasonably well. 

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