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Title: State selectivity in core ionization of methane
A clear experimental signature of the population of the lowest triplet state T 1 3 of the methane dication is identified in a photoionization experiment. This state is populated only in valence ionization and is absent when the dication is formed by core ionization followed by Auger-Meitner decay. For valence ionization, the total internal energy of the CH 3 + fragment, formed during the deprotonation of CH 4 2 + , is evaluated. Notably, the distribution of this internal energy peaks at the same value regardless of the initially populated electronic state of CH 4 2 + . We find that excited electronic states of CH 3 + are predominantly populated with significant rovibrational excitation. Published by the American Physical Society2025  more » « less
Award ID(s):
2208017
PAR ID:
10620978
Author(s) / Creator(s):
; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; more » ; « less
Publisher / Repository:
American Physical Society
Date Published:
Journal Name:
Physical Review Research
Volume:
7
Issue:
2
ISSN:
2643-1564
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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