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Abstract Microswimmers are self‐propelled particles that navigate fluid environments, offering significant potential for applications in environmental pollutant decomposition, biosensing, and targeted drug delivery. Their performance relies on engineered catalytic surfaces. Gold nanoclusters (AuNCs), with atomically precise structures, tunable optical properties, and high surface area‐to‐volume ratio, provide a new optimal catalyst for enhancing microswimmer propulsion. Unlike bulk gold or nanoparticles, AuNCs may deliver tunable photocatalytic activity and increased catalytic specificity, making them ideal co‐catalysts for hybrid microswimmers. For the first time, this study combines AuNCs with TiO2/Cr2O3Janus microswimmers, combining the unique properties of both materials. This hybrid system capitalizes on the tuned optical properties of AuNCs and their role as co‐catalysts with TiO2, driving enhanced photocatalytic performance under ultraviolet (UV) excitation. Using motion analysis, it is shown that the AuNC‐microswimmers exhibit significantly greater propulsion and mean squared displacement (MSD) as compared to controls. These findings suggest that the integration of nanoclusters with semiconductor materials enables state of the art, light‐switchable microswimmers. These AuNC‐microswimmer systems may thus offer new opportunities for environmental catalysis and other applications, providing precise control over catalytic and motile behaviors at the microscale.
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Detection of Hybrid Optical Anapoles in Dielectric Microspheres
Abstract Nonradiating optical anapoles are special configurations of charge‐current distributions that do not radiate. It was theoretically predicted that, for microspheres, electric and magnetic dipolar coefficients can simultaneously vanish by engineering the incident light, leading to the excitation of nonradiatinghybridoptical anapoles. In this work, the experimental detection of hybrid optical anapoles in dielectric microspheres (TiO2) is reported using dual detection optical spectroscopy, developed to enable sequential measurement of forward and backward scattering under tightly‐focused Gaussian beam (TFGB) illumination. The results show that the excitation of TiO2microspheres (diameter,d≈1 µm) under TFGB illumination leads to the appearance of scattering minima in both the forward and backward directions within specific wavelength ranges. These scattering minima are found to be due to vanishing electric and magnetic dipolar coefficients associated with hybrid optical anapoles. The ability to confine electromagnetic fields associated with hybrid optical anapoles can give rise to several novel optical phenomena and applications.
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- PAR ID:
- 10632157
- Publisher / Repository:
- John Wiley & Sons, Inc
- Date Published:
- Journal Name:
- Advanced Optical Materials
- ISSN:
- 2195-1071
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript
- Journal Article:
- https://doi.org/10.1002/adom.202501315
