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Assembling different shaped particles into ordered microstructures is an open challenge in creating multifunctional particle-based materials and devices. Here, we report the two-dimensional (2D) AC electric field mediated assembly of different shaped colloidal particles into amorphous, liquid crystalline, and crystalline microstructures. Particle shapes investigated include disks, ellipses, squares, and rectangles, which show how systematic variations in anisotropy and corner curvature determine the number and type of resulting microstructures. AC electric fields induce dipolar interactions to control particle positional and orientational order. Microstructural states are determined via particle tracking to compute order parameters, which agree with computer simulations and show how particle packing and dipolar interactions together produce each structure. Results demonstrate how choice of particle shape and field conditions enable kinetically viable routes to assemble nematic, tetratic, and smectic liquid crystal structures as well as crystals with stretched 4- and 6-fold symmetry. Results show it is possible to assemble all corresponding hard particle phases, but also show how dipolar interactions influence and produce additional microstructures. Our findings provide design rules for the assembly of diverse microstructures of different shaped particles in AC electric fields, which could enable scalable and reconfigurable particle-based materials, displays, and printing technologies.
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High-Density and Well-Aligned Hierarchical Structures of Colloids Assembled under Orthogonal Magnetic and Electric Fields
Colloids can be used either as model systems for directed assembly or as the necessary building blocks for making functional materials. Previous work primarily focused on assembling colloids under a single external field, where controlling particle−particle interactions is limited. This work presents results under a combination of electric and magnetic fields. When these two fields are orthogonally applied, we can independently tune the magnitude and direction of the dipolar attraction and repulsion between the particles. As a result, we obtain well-aligned, highly dense, but individually separated linear chains at intermediate particle concentrations. Both the inter- and intrachain spacings can be tuned by adjusting the particle concentration and relative strengths of both fields. At high particle concentrations and by tuning the electric field frequency, the individual microspheres can assemble into colloidal oligomers such as trimers, tetramers, heptamers, and nonamers in response to the electric field due to the synergy between dipolar and electrohydrodynamic interactions. These oligomers, in turn, serve as building blocks for making hierarchical structures with finer architectures upon superimposing a one-dimensional (1D) magnetic field. In addition to experiments, Monte Carlo (MC) simulations have been performed on colloids confined near the electrode, interacting through a Stockmayer-like potential. They faithfully reproduce key observations in the experiments. Our work demonstrates the potential of using orthogonal electric and magnetic fields to assemble diversified types of highly aligned structures for applications in high-strength composites, optical materials, or structured battery electrodes.
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- PAR ID:
- 10563822
- Publisher / Repository:
- American Chemical Society
- Date Published:
- Journal Name:
- ACS Nano
- ISSN:
- 1936-0851
- Subject(s) / Keyword(s):
- directed assembly, electric field, magnetic field, hierarchical structures, dipolar interaction
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1021/acsnano.4c11957
