Materials composed of spin-1 antiferromagnetic (AFM) chains are known to adopt complex ground states that are sensitive to the single-ion-anisotropy (SIA) energy ( ), and intrachain ( ) and interchain ( ) exchange energy scales. While theoretical and experimental studies have extended this model to include various other energy scales, the effect of the lack of a common SIA axis is not well explored. Here we investigate the magnetic properties of , a chain compound where the tilting of Ni octahedra leads to a twofold alternation of the easy-axis directions along the chain. Muon-spin relaxation measurements indicate a transition to long-range order at and the magnetic structure is initially determined to be antiferromagnetic and collinear using elastic neutron diffraction experiments. Inelastic neutron scattering measurements were used to find , and a rhombic anisotropy energy . Mean-field modeling reveals that the ground state structure hosts spin canting of , which is not detectable above the noise floor of the elastic neutron diffraction data. Monte Carlo simulation of the powder-averaged magnetization, , is then used to confirm these Hamiltonian parameters, while single-crystal simulations provide insight into features observed in the data. Published by the American Physical Society2025
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This content will become publicly available on February 1, 2026
Room-temperature quantum sensing with photoexcited triplet electrons in organic crystals
Quantum sensors have notably advanced high-sensitivity magnetic field detection. Here, we report quantum sensors constructed from polarized spin-triplet electrons in photoexcited organic chromophores, specifically focusing on pentacene-doped para-terphenyl . We demonstrate essential quantum sensing properties at room temperature (RT): optically generated electronic polarization and state-dependent fluorescence contrast by leveraging differential pumping and relaxation rates between triplet and ground states. We measure high optically detected magnetic resonance contrast of the triplet states at RT, along with long coherence times under spin echo and Carr-Purcell-Meiboom-Gill (CPMG) sequences, and , respectively, limited only by the triplet lifetimes. The material offers several advantages for quantum sensing, including the ability to grow large (cm scale) crystals at low cost, absence of paramagnetic impurities, and electronic diamagnetism when not optically illuminated. Utilizing pentacene as a representative of a broader class of spin triplet- polarizable organic molecules, this paper highlights the potential for quantum sensing in chemical systems.
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- Award ID(s):
- 2326838
- PAR ID:
- 10635181
- Publisher / Repository:
- APS
- Date Published:
- Journal Name:
- Physical Review Research
- Volume:
- 7
- Issue:
- 1
- ISSN:
- 2643-1564
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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