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Abstract We report evidence of a finite density of states at the Fermi level at the surface of epitaxial thin films of the narrow bandgap Mott insulator Sr3Ir2O7(001). The Brillouin zone critical points for Sr3Ir2O7(001) thin films have been determined by a comparison of the band mapping from angle-resolved photoemission spectroscopy and low energy electron diffraction. Angle-resolved x-ray photoemission studies reveal the surface termination of Sr3Ir2O7(001) is Sr–O. The absence of dispersion with photon energy, or changing wave vector along the surface normal, indicates the two-dimensional character of the bands contributing to the density of states close to the Fermi level for Sr3Ir2O7(001) thin films. Thus, the finite density of states at the Fermi level is attributed to surface states or surface resonances. The appearance of a finite density of states at the Fermi level is consistent with the increased conductivity with decreasing film thickness for ultrathin Sr3Ir2O7(001) films.
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This content will become publicly available on March 14, 2026
The anomalous temperature dependent low energy electron diffraction intensity at epitaxial Sr 3 Ir 2 O 7 thin film surfaces
Abstract We report on the temperature dependent low energy electron diffraction (LEED) studies of 12 nm epitaxial Sr3Ir2O7(001) thin films. The Debye temperature has been extracted from the temperature-dependence of LEED intensity at elevated temperatures and different electron kinetic energies. For the most surface sensitive LEED, obtained at the lowest electron kinetic energies, the extracted surface Debye temperature is 270 ± 22 K, which is much lower than the 488 ± 40 K Debye temperature obtained using higher electron kinetic energies. Surprisingly, the LEED diffraction intensity, at the lowest electron kinetic energies, increases rather than decreases, with increasing sample temperatures up to about 440 K. This anomalous behavior has been attributed to the reduction of the lattice vibrational amplitudes along the surface normal. This damping of the normal mode vibrations with increasing temperature results from the enhanced electronic screening via thermally activated carriers. This scenario is corroborated by the transport measurement, showing that Sr3Ir2O7is a narrow band Mott insulator with a band gap of about 32 meV. We have identified criteria for finding anomalous scattering behavior in other transition metal oxide systems.
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- Award ID(s):
- 2044049
- PAR ID:
- 10636316
- Publisher / Repository:
- IOP Science
- Date Published:
- Journal Name:
- Journal of Physics: Condensed Matter
- Volume:
- 37
- Issue:
- 16
- ISSN:
- 0953-8984
- Page Range / eLocation ID:
- 165402
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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