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Abstract We measure the Einstein radius of the single-lens microlensing event KMT-2022-BLG-2397 to beθE= 24.8 ± 3.6μas, placing it at the upper shore of the Einstein Desert, 9 ≲θE/μas ≲ 25, between free-floating planets (FFPs) and bulge brown dwarfs (BDs). In contrast to the six BD (25 ≲θE≲ 50) events presented by Gould et al. (2022), which all had giant-star source stars, KMT-2022-BLG-2397 has a dwarf-star source, with angular radiusθast∼ 0.9μas. This prompts us to study the relative utility of dwarf and giant sources for characterizing FFPs and BDs from finite-source point-lens (FSPL) microlensing events. We find “dwarfs” (including main-sequence stars and subgiants) are likely to yield twice as manyθEmeasurements for BDs and a comparable (but more difficult to quantify) improvement for FFPs. We show that neither current nor planned experiments will yield complete mass measurements of isolated bulge BDs, nor will any other planned experiment yield as manyθEmeasurements for these objects as the Korea Microlensing Telescope (KMT). Thus, the currently anticipated 10 yr KMT survey will remain the best way to study bulge BDs for several decades to come.
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In situ monitoring of CO 2 sorption on polyethylenimine dynamics through broadband dielectric spectroscopy
Abstract Chemical reactions between carbon dioxide (CO) and amine have been extensively characterized, however, their influence on the dynamics of polyamines remains largely unexplored. In this work, we compare the dynamics of polyethylenimine (PEI) before and after CO absorption through broadband dielectric spectroscopy (BDS). The molecular processes of bulk PEI are very different from those of thin film PEI, highlighting an interesting interface and nano‐confinement effect. Detailed analyses show CO absorption slows down the PEI dynamics, which is consistent with an elevated glass transition temperature of PEI upon CO absorption from differential scanning calorimetry measurements. Furtherin situkinetic measurements demonstrate nonmonotonic changes in relaxation times or dielectric amplitudes of some relaxation processes during CO sorption or desorption, suggesting an intriguing interplay between CO chemisorption and the dynamics of PEI. These results demonstrate that BDS is a powerful platform to resolve the temporal dynamics changes of polyamines for CO capture.
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- PAR ID:
- 10641553
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- AIChE Journal
- Volume:
- 71
- Issue:
- 1
- ISSN:
- 0001-1541
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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