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The early Martian atmosphere had 0.25 to 4 bar of CO2but thinned rapidly around 3.5 billion years ago. The fate of that carbon remains poorly constrained. The hydrothermal alteration of ultramafic rocks, rich in Fe(II) and Mg, forms both abiotic methane, serpentine, and high-surface-area smectite clays. Given the abundance of ultramafic rocks and smectite in the Martian upper crust and the growing evidence of organic carbon in Martian sedimentary rocks, we quantify the effects of ultramafic alteration on the carbon cycle of early Mars. We calculate the capacity of Noachian-age clays to store organic carbon. Up to 1.7 bar of CO2can plausibly be adsorbed on clay surfaces. Coupling abiotic methanogenesis with best estimates of Mars’ δ13C history predicts a reservoir of 0.6 to 1.3 bar of CO2equivalent. Such a reservoir could be used as an energy source for long-term missions. Our results further illustrate the control of water-rock reactions on the atmospheric evolution of planets.
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This content will become publicly available on August 1, 2026
Clay Chemistry of the Thacker Pass Deposit, Nevada: Implications for the Formation of High-Grade Volcano-Sedimentary Lithium Resources
Abstract Volcano-sedimentary lithium (Li) deposits are a potential source of battery-grade Li, although the important factors controlling Li enrichment in these systems remain unclear. At Thacker Pass in Nevada, high-grade mineralization overprinted intracaldera lacustrine claystone made of authigenic Li-rich smectite with bulk grades of ~3,000 ppm Li, converting it to illitic claystone with grades of ~6,000 ppm Li. Some attribute this enrichment to burial diagenesis, whereas others propose lacustrine Li enrichment through leaching and climate-driven evapoconcentration enhanced by postdepositional hydrothermal alteration. To better understand Li enrichment in volcano-sedimentary systems, claystones from throughout Thacker Pass were analyzed using powder X-ray diffraction (PXRD), electron microprobe (EPMA), laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS), and stable isotope (clay δ18O, δ17O, and δ2H and carbonate δ13C and δ18O) methods. Compositional data suggest that illitization is required to achieve clay Li grades above ~0.9 wt % in Mg silicate clays because of a charge-coupled substitution that requires filling interlayer vacancies with K. Clay chemical trends and computational modeling exercises also suggest that F may be important in the formation of Li-rich clays by lowering kinetic barriers to clay precursor growth and illitization. The results are incompatible with diagenetic smectite/illite formation but are consistent with a model wherein authigenic smectite was subjected to hydrothermal alteration in the presence of a K-, Li-, and F-rich fluid that permeated the stratigraphy through a network of normal faults associated with caldera resurgence. These results also enhance our understanding of Li clay formation in other volcano-sedimentary systems.
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- PAR ID:
- 10647916
- Publisher / Repository:
- Society of Economic Geologists
- Date Published:
- Journal Name:
- Economic Geology
- Volume:
- 120
- Issue:
- 5
- ISSN:
- 0361-0128
- Page Range / eLocation ID:
- 1047 to 1070
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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