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Title: Simple amination of polystyrene via radical sp3 C–H imination
We report the mild functionalization of polystyrene with primary amines and other nitrogen groups through sp3 C–H imination. This process significantly increases hydrophilicity without deterioration of molecular weight or thermal properties, and provides a handle for further covalent modification. This work will enable the upcycling and diversification of commodity polyolefins.  more » « less
Award ID(s):
2337696
PAR ID:
10648347
Author(s) / Creator(s):
 ;  ;  
Publisher / Repository:
The Royal Society of Chemistry
Date Published:
Journal Name:
Polymer Chemistry
Volume:
15
Issue:
48
ISSN:
1759-9954
Page Range / eLocation ID:
4947 to 4951
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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