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Abstract As appreciation for nonclassical hydrogen bonds has progressively increased, so have efforts to characterize these interesting interactions. Whereas several kinds of C−H hydrogen bonds have been well‐studied, much less is known about the R3N+−C−H⋅⋅⋅X variety. Herein, we present crystallographic and spectroscopic evidence for the existence of these interactions, with special relevance to Selectfluor chemistry. Of particular note is the propensity for Lewis bases to engage in nonclassical hydrogen bonding over halogen bonding with the electrophilic F atom of Selectfluor. Further, the first examples of1H NMR experiments detailing R3N+−C−H⋅⋅⋅X (X=O, N) hydrogen bonds are described.
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This content will become publicly available on April 10, 2026
Surface engineering of Pt nanocatalysts with transition metal oleates for selective catalysis: a case study on the hydrogenation of α,β-unsaturated aldehydes
The adsorption of transition metal oleates on Pt nanoparticle surfaces creates a negative charge, promoting selective hydrogenation of CO bonds over CC bonds in nonpolar solvents, ensuring reactant solubility and improving catalytic efficiency.
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- Award ID(s):
- 2045662
- PAR ID:
- 10659450
- Publisher / Repository:
- RSC
- Date Published:
- Journal Name:
- Nanoscale
- Volume:
- 17
- Issue:
- 15
- ISSN:
- 2040-3364
- Page Range / eLocation ID:
- 9391 to 9400
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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