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Abstract. We describe a “virtual mineral separation” method for measuring the cosmogenic 3He concentration in pyroxene in mafic rocks that consist mainly of plagioclase and pyroxene, without physically separating the minerals. This approach is significantly faster and more cost-effective than the conventional method, which requires physical separation and purification of pyroxene grains by time-consuming and labor-intensive crushing, acid cleaning, magnetic separation, HF etching, and handpicking under a microscope. The premise of the method is that helium diffusivity is much higher in plagioclase than in pyroxene, so controlled preheating of a mixed whole-rock sample can degas 3He from plagioclase while retaining all 3He in pyroxene. A second heating step releases all 3He from pyroxene for measurement. To then obtain a 3He concentration in pyroxene rather than the whole rock, we determine the pyroxene weight fraction in the sample using X-ray computed tomography (CT). A comparison of 3He concentrations in pyroxene measured using virtual mineral separation with those measured in the same samples by physical mineral separation in previous work shows no evidence of systematic bias between the methods. Virtual mineral separation greatly simplifies the workflow for 3He exposure-dating of mafic rocks, reduces time, effort, and cost, and permits measurements on very small samples. This enables new emerging applications of exposure dating, such as quantifying stochastic surface processes, ecosystem studies, and potential subglacial bedrock exposure dating. 

Abstract. We report new cosmogenic 21Ne in quartz exposure ages from 18 samples on three distinct moraines deposited in the Lost Creek drainage, approximately 3–7 km down-valley from Lassen Peak in Lassen Volcanic National Park. Although measuring 21Ne in quartz is generally straightforward, accurate 21Ne exposure dating of deposits of late Pleistocene is rarely possible due to the significant quantities of non-cosmogenic 21Ne present in most lithologies. Young quartz-bearing volcanic rocks have been observed to be an exception. We take advantage of moraine boulders sourced from the ∼ 28 ka dacite of Lassen Peak to generate a chronology of alpine deglaciation in Lassen Volcanic National Park. Ages from three distinct moraines are in stratigraphic order at 22.1 ± 3.8, 20.2 ± 2.4, and 15.3 ± 3.8 ka and generally agree with other terminal and some recessional moraine ages across the Cascade Range and Sierra Nevada of the western United States. To date, these are among the youngest surfaces ever dated using cosmogenic 21Ne and provide a cost-effective proof-of-concept approach to dating moraines where applicable. 

Abstract. In this study, we investigate the diffusivity of cosmogenic 3He in a variety of plagioclase and pyroxene compositions, and its application to paleothermometry and exposure dating in these minerals, through stepwise degassing experiments. While cosmogenic 3He has been utilized for exposure dating in pyroxene for decades due to its retentivity, plagioclase, often found along with pyroxene in mafic rocks, is generally less retentive of cosmogenic noble gas. However, the diffusivity of 3He in either plagioclase or pyroxene has not yet been measured quantitatively. A challenge in measuring diffusion kinetics by step-degassing experiments in poorly retentive minerals is the fact that significant amounts of He can be lost prior to the experiment. To address this issue, we apply a forward “multiple diffusion domain” (MDD) inversion model that includes model predictions of initial gas loss during irradiation and storage of the samples to account for this observation and add constraints to the diffusion parameters. We find that 3He diffusivity in plagioclase appears to be highly variable. This variability can be explained by the MDD inversion models' inability to constrain the diffusion parameters when significant gas has been lost during irradiation and/or prolonged storage prior to experiment analysis, resulting in an overestimation of 3He retentivity. Plagioclase samples that were kept frozen after irradiation, to limit this initial gas loss, yielded the most reliable estimate of diffusion kinetics. We find that 3He in plagioclase is diffusively lost at Earth's surface temperatures on a timescale of 100 years and is therefore unsuitable for surface temperature paleothermometry. On the contrary, we find cosmogenic 3He in pyroxene to be retentive at Earth's surface temperatures on a 1-million-year timescale. 

Abstract. Measurements of multiple cosmogenic nuclides in a single sample are valuable for various applications of cosmogenic nuclide exposure dating and allow for correcting exposure ages for surface weathering and erosion and establishing exposure–burial history. Here we provide advances in the measurement of cosmogenic 10Be in pyroxene and constraints on the production rate that provide new opportunities for measurements of multi-nuclide systems, such as 10Be/3He, in pyroxene-bearing samples. We extracted and measured cosmogenic 10Be in pyroxene from two sets of Ferrar Dolerite samples collected from the Transantarctic Mountains in Antarctica. One set of samples has 10Be concentrations close to saturation, which allows for the production rate calibration of 10Be in pyroxene by assuming production–decay equilibrium. The other set of samples, which has a more recent exposure history, is used to determine if a rapid fusion method can be successfully applied to samples with Holocene to Last Glacial Maximum exposure ages. From measured 10Be concentrations in the near-saturation sample set we find the production rate of 10Be in pyroxene to be 3.74 ± 0.10 atoms g−1 yr−1, which is consistent with 10Be/3He paired nuclide ratios from samples assumed to have simple exposure. Given the high 10Be concentration measured in this sample set, a sample mass of ∼ 0.5 g of pyroxene is sufficient for the extraction of cosmogenic 10Be from pyroxene using a rapid fusion method. However, for the set of samples that have low 10Be concentrations, measured concentrations were higher than expected. We attribute spuriously high 10Be concentrations to failure in removing all meteoric 10Be and/or a highly variable and poorly quantified procedural blank background correction. 

Cosmogenic isotopes of helium and neon are produced at the Earth’s surface and exhibit a wide range of thermal sensitivities in common minerals. We can take advantage of this range of thermal sensitivities to reconstruct past near surface thermal conditions using cosmogenic noble gas observations. For example, cosmogenic noble gases have been used to study past ambient temperatures, changes in snow cover duration, and wildfire histories. Interpreting cosmogenic noble gas observations requires a model of both production and diffusion that predicts cosmogenic noble gas concentrations for different thermal histories. Additionally, models that characterize the diffusion kinetics of helium or neon in a particular mineral sample are often needed, as laboratory-based diffusion experiments demonstrate that helium and neon diffusion kinetics are sample specific and often complex. At present, various codes are available that can carry out pieces of the modeling, but they are generally not interoperable and are often highly specific to a particular past application, limiting the codes’ use for future applications. Here we present progress on creating a general forward modeling framework for inferring thermal histories using cosmogenic noble gas observations, structured around the concept of proxy system modeling. We will describe the architecture of this model framework as well as provide examples of applying it to new and existing cosmogenic noble gas datasets. 

Measurements of cosmic-ray-produced beryllium-10, neon-21, and helium-3 in quartz in a soil profile from a forested landscape in the Oregon Coast Range show that the cosmogenic noble gases 21Ne and 3He are depleted relative to 10Be in the shallow subsurface. The noble gases are mobile in mineral grains via thermally activated diffusion and 10Be is not, implying that noble gas depletion is the result of surface heating by wildfires and subsequent mixing of partially degassed quartz downward into the soil. Cosmogenic noble gas depletion by wildfire heating of soils is a potential means of estimating wildfire intensity and/or frequency over pre-observational timescales. 

The McMurdo Dry Valleys are an ice-free region along the coast of the Transantarctic Mountains that display well-preserved polar desert morphologic features, particularly at high elevations. The extent of these well-preserved features suggests that cold-desert conditions have been present for millions of years. This is thought to be because average summer air temperatures in much of the McMurdo Dry Valleys remain below -3ºC, preventing significant amounts of liquid water from forming and in turn keeping erosion rates low. Recent climate simulations suggest that these freezing temperatures persist during summer months at high elevations in the McMurdo Dry Valleys, even during past warm periods characterized by significant ice sheet recession. Surfaces at lower elevations in the McMurdo Dry Valleys, subject to warmer temperatures during warm periods and interglacials, are thought to experience overall faster erosion rates compared to high elevation outcrops. Here, we examine the relationships between elevation, temperature, and apparent surface exposure age for outcrops of the Beacon Sandstone in the McMurdo Dry Valleys. We use a compilation of cosmogenic nuclide measurements available in the ICE-D database to evaluate the correlation between apparent surface exposure age and elevation for outcrops of the Beacon Sandstone across the McMurdo Dry Valleys. At or near a number of the cosmogenic nuclide sites, local summertime ground and air surface temperature data are available from weather stations. We use these weather station data to document how ground temperatures, which ultimately control the availability of liquid water and therefore rates of surface processes, correspond with the apparent exposure ages and site elevations of Beacon Sandstone outcrops. In addition, we investigate whether field observations indicating a relationship between the coloration and surface appearance of Beacon Sandstone outcrops and the surface weathering/erosion rate can be quantified using satellite remote sensing data and the spectral properties of the outcrops. Tying all of these results together, we assess the role of temperature and other physical parameters on the rates of surface processes in the McMurdo Dry Valleys during the last few million ice-free years. 

The persistence and size of the Greenland Ice Sheet (GrIS) through the Pleistocene is uncertain. This is important because reconstructing changes in the GrIS determines its contribution to sea level rise during prior warm climate periods and informs future projections. To understand better the history of Greenland’s ice, we analyzed glacial till collected in 1993 from below 3 km of ice at Summit, Greenland. The till contains plant fragments, wood, insect parts, fungi, and cosmogenic nuclides showing that the bed of the GrIS at Summit is a long-lived, stable land surface preserving a record of deposition, exposure, and interglacial ecosystems. Knowing that central Greenland was tundra-covered during the Pleistocene informs the understanding of Arctic biosphere response to deglaciation. 

We apply geologic evidence from ice-free areas in Antarctica to evaluate model simulations of ice sheet response to warm climates. This is important because such simulations are used to predict ice sheet behaviour in future warm climates, but geologic evidence of smaller-than-present past ice sheets is buried under the present ice sheet and therefore generally unavailable for model benchmarking. We leverage an alternative accessible geologic dataset for this purpose: cosmogenic-nuclide concentrations in bedrock surfaces of interior nunataks. These data produce a frequency distribution of ice thickness over multimillion-year periods, which is also simulated by ice sheet modelling. End-member transient models, parameterized with strong and weak marine ice sheet instability processes and ocean temperature forcings, simulate large and small sea-level impacts during warm periods and also predict contrasting and distinct frequency distributions of ice thickness. We identify regions of Antarctica where predicted frequency distributions reveal differences in end-member ice sheet behaviour. We then demonstrate that a single comprehensive dataset from one bedrock site in West Antarctica is sufficiently detailed to show that the data are consistent only with a weak marine ice sheet instability end-member, but other less extensive datasets are insufficient and/or ambiguous. Finally, we highlight locations where collecting additional data could constrain the amplitude of past and therefore future response to warm climates.