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At ambient conditions, the high-entropy alloy superconductor R⁢e0.6⁢(NbTiZrHf)0.4 exhibits exceptional mechanical properties among high-entropy alloys, with its hexagonal phase achieving nanoindentation hardness of 18.5 GPa. We report on a unique pressure-induced structural transformation from a hexagonal phase to a body-centered cubic (BCC) phase, revealed by synchrotron x-ray diffraction measurements up to 70 GPa. This first-order transition, accompanied by a 6.1% volume collapse, occurs at 44 GPa and results in a BCC structure with random site occupancy by the five constituent elements, which is remarkably retained upon decompression to ambient conditions. The transformation proceeds via a martensiticlike, diffusionless mechanism without elemental segregation, enabled by pressure-induced electronic redistribution and atomic-scale disorder. These findings demonstrate a rare case of metastable phase retention in a chemically complex alloy and offer new insights into structure-stability relationships under pressure. 

We present scanning electrochemical cell microscopy (SECCM) studies of Ag nucleation and growth on carbon and indium tin oxide (ITO) electrodes. 

Molecular case studies (MCSs) provide educational opportunities to explore biomolecular structure and function using data from public bioinformatics resources. The conceptual basis for the design of MCSs has yet to be fully discussed in the literature, so we present molecular storytelling as a conceptual framework for teaching with case studies. Whether the case study aims to understand the biology of a specific disease and design its treatments or track the evolution of a biosynthetic pathway, vast amounts of structural and functional data, freely available in public bioinformatics resources, can facilitate rich explorations in atomic detail. To help biology and chemistry educators use these resources for instruction, a community of scholars collaborated to create the Molecular CaseNet. This community uses storytelling to explore biomolecular structure and function while teaching biology and chemistry. In this article, we define the structure of an MCS and present an example. Then, we articulate the evolution of a conceptual framework for developing and using MCSs. Finally, we related our framework to the development of technological, pedagogical, and content knowledge (TPCK) for educators in the Molecular CaseNet. The report conceptualizes an interdisciplinary framework for teaching about the molecular world and informs lesson design and education research. 

Abstract Long-period radio transients are an emerging class of extreme astrophysical events of which only three are known. These objects emit highly polarized, coherent pulses of typically a few tens of seconds duration, and minutes to approximately hour-long periods. Although magnetic white dwarfs and magnetars, either isolated or in binary systems, have been invoked to explain these objects, a consensus has not emerged. Here we report on the discovery of ASKAP J193505.1+214841.0 (henceforth ASKAP J1935+2148) with a period of 53.8 minutes showing 3 distinct emission states—a bright pulse state with highly linearly polarized pulses with widths of 10–50 seconds; a weak pulse state that is about 26 times fainter than the bright state with highly circularly polarized pulses of widths of approximately 370 milliseconds; and a quiescent or quenched state with no pulses. The first two states have been observed to progressively evolve over the course of 8 months with the quenched state interspersed between them suggesting physical changes in the region producing the emission. A constraint on the radius of the source for the observed period rules out an isolated magnetic white-dwarf origin. Unlike other long-period sources, ASKAP 1935+2148 shows marked variations in emission modes reminiscent of neutron stars. However, its radio properties challenge our current understanding of neutron-star emission and evolution. 

Abstract Identification and follow-up observations of the host galaxies of fast radio bursts (FRBs) not only help us understand the environments in which the FRB progenitors reside, but also provide a unique way of probing the cosmological parameters using the dispersion measures (DMs) of FRBs and distances to their origin. A fundamental requirement is an accurate distance measurement to the FRB host galaxy, but for some sources viewed through the Galactic plane, optical/near-infrared spectroscopic redshifts are extremely difficult to obtain due to dust extinction. Here we report the first radio-based spectroscopic redshift measurement for an FRB host galaxy, through detection of its neutral hydrogen (Hi) 21 cm emission using MeerKAT observations. We obtain an Hi–based redshift ofz= 0.0357 ± 0.0001 for the host galaxy of FRB 20230718A, an apparently nonrepeating FRB detected in the Commensal Real-time ASKAP Fast Transients survey and localized at a Galactic latitude of –0.°367. Our observations also reveal that the FRB host galaxy is interacting with a nearby companion, which is evident from the detection of an Hibridge connecting the two galaxies. A subsequent optical spectroscopic observation confirmed an FRB host galaxy redshift of 0.0359 ± 0.0004. This result demonstrates the value of Hito obtain redshifts of FRBs at low Galactic latitudes and redshifts. Such nearby FRBs whose DMs are dominated by the Milky Way can be used to characterize these components and thus better calibrate the remaining cosmological contribution to dispersion for more distant FRBs that provide a strong lever arm to examine the Macquart relation between cosmological DM and redshift. 

Two-dimensional semiconductors (2DSCs) are attractive materials for a variety of applications in electronics, photovoltaics, and catalysis. Despite their promise, it is often unclear how the performance of 2DSCs is influenced by structural defects present in these materials such as atomic vacancies or step-edges. A better fundamental understanding of how such structural features influence the generation and transport of charge carriers in 2DSCs will be critical in the pursuit of improved practical devices moving forward. In this Opinion, we highlight how electrochemistry can be leveraged to reveal fascinating insights into the behavior of 2DSCs. Recent advancements in techniques for mapping the rate of photoelectrochemical processes at 2DSCs are outlined and salient experiments employing these techniques are discussed. We conclude with sharing our perspective on opportunities within this field moving forward. 

White-tailed deer (Odocoileus virginianus) hunting is an important economic activity associated with the management of forests and rangelands in the USA, with over $12.9 billion dollars of related annual expenditures. Reducing tree cover through thinning and prescribed fire both have the potential to increase the quantity and quality of deer forage. We evaluated the long-term impacts of eight different combinations of fire return intervals and tree harvest on forage productivity and protein content of the forage. Based on management regime, study units ranged from savanna to closed-canopy forest. Aboveground net primary production (ANPP) of six functional groups (grass, panicum, forb, legume, woody, sedge) of understory vegetation was measured in October 2019 and 2020 using destructive sampling. Samples for foliar crude protein (CP) concentration were collected in spring, summer, and fall of 2020. Total understory ANPP ranged from 2.9 to 466.3 g m− 2 and was up to 566% greater in savanna systems maintained by frequent fire (return interval of three years or less) than in non-burned forest treatments. Annual burning resulted in ANPP dominated by herbaceous plants composed mostly of firetolerant grasses (e.g., Andropogon gerardii, Schizachyrium scoparium). Longer fire return intervals or no fire resulted in roughly equal ANPP from understory woody and herbaceous species. Crude protein concentrations were up to 45.7% greater in the woodland and forest units than in the savanna units for seven of the eleven species sampled. The greater CP in the forests was most noticeable in the summer when deer needs for quality forage are substantial. Increased protein concentrations of understory species in the forests, but greater ANPP in the savannas indicate that managing for a mix of savanna and woodland could be ideal for balancing forage quantity with increased forage protein. 

ABSTRACT Localization of fast radio bursts (FRBs) to arcsecond and subarcsecond precision maximizes their potential as cosmological probes. To that end, FRB detection instruments are deploying triggered complex-voltage capture systems to localize FRBs, identify their host galaxy, and measure a redshift. Here, we report the discovery and localization of two FRBs (20220717A and 20220905A) that were captured by the transient buffer system deployed by the MeerTRAP instrument at the MeerKAT telescope in South Africa. We were able to localize the FRBs to precision of $$\sim$$1 arcsecond that allowed us to unambiguously identify the host galaxy for FRB 20220717A (posterior probability $$\sim$$0.97). FRB 20220905A lies in a crowded region of the sky with a tentative identification of a host galaxy but the faintness and the difficulty in obtaining an optical spectrum preclude a conclusive association. The bursts show low linear polarization fractions (10–17 per cent) that conform to the large diversity in the polarization fraction observed in apparently non-repeating FRBs akin to single pulses from neutron stars. We also show that the host galaxy of FRB 20220717A contributes roughly 15 per cent of the total dispersion measure (DM), indicating that it is located in a plasma-rich part of the host galaxy which can explain the large rotation measure. The scattering in FRB 20220717A can be mostly attributed to the host galaxy and the intervening medium and is consistent with what is seen in the wider FRB population. 

Well-ordered nanoparticle arrays are attractive platforms for a variety of analytical applications, but the fabrication of such arrays is generally challenging. Here, it is demonstrated that scanning electrochemical cell microscopy (SECCM) can be used as a powerful, instantly reconfigurable tool for the fabrication of ordered nanoparticle arrays. Using SECCM, Ag nanoparticle arrays were straightforwardly fabricated via electrodeposition at the interface between a substrate electrode and an electrolyte-filled pipet. By dynamically monitoring the currents flowing in an SECCM cell, individual nucleation and growth events could be detected and controlled to yield individual nanoparticles of controlled size. Characterization of the resulting arrays demonstrate that this SECCM-based approach enables spatial control of nanoparticle location comparable with the terminal diameter of the pipet employed and straightforward control over the volume of material deposited at each site within an array. These results provide further evidence for the utility of probe-based electrochemical techniques such as SECCM as tools for surface modification in addition to analysis.