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Comparative evaporation rate testing in a dark environment, commonly used to characterize a reduced vaporization enthalpy in interfacial solar evaporators, requires the assumption of equal energy input between cases. However, this assumption is not generally valid, leading to misleading characterization results. Interfacial evaporators yield larger evaporation rates in dark conditions due to enlarged liquid-vapor surface areas, resulting in increased evaporative cooling and larger environmental temperature differentials. Theoretical and experimental evidence is provided, which shows that these temperature differences invalidate the equal energy input assumption. The results indicate that differences in evaporation rates correspond to energy input variations, without requiring enthalpy to be reduced below theoretical values. These findings offer alternative explanations for previous claims of reduced vaporization enthalpy and contradict enthalpy-related conclusions drawn from differential scanning calorimetry. We conclude that postulating a reduced vaporization enthalpy using the dark environment method is inaccurate and that re-evaluation of vaporization enthalpy reduction is required. 

Passive radiative cooling materials are widely recognized as attractive innovations for reducing emissions and expanding life-saving cooling access. Despite immense research attention, the adoption of such technologies is limited largely due to a lack of scalability and cost compatibility with market needs. While paint and coating-based approaches offer a more sensible solution, many demonstrations suffer from issues such as a low solar reflectance performance or a lack of material sustainability due to the use of harmful solvents. In this work, we demonstrate a passive radiative cooling paint which achieves an extremely high solar reflectance value of 98% using a completely water-based formulation. Material sustainability is promoted by incorporating size-dispersed calcium phosphate biomaterials, which offer broadband solar reflectance, as well as a self-crosslinking water-based binder, providing water resistance and durability without introducing harmful materials. Common industry pigments are integrated within the binder for comparison, illustrating the benefit of finely-tuned particle size distributions for broadband solar reflectance, even in low-refractive-index materials such as calcium phosphates. With scalability, outdoor durability, and eco-friendly materials, this demonstrated paint offers a practical passive radiative cooling approach without exacerbating other environmental issues. 

Passive daytime radiative cooling (PDRC) is a promising energy-saving cooling method to cool objects without energy consumption. Although numerous PDRC materials and structures have been proposed to achieve sub-ambient temperatures, the technique faces unprecedented challenges brought on by complicated and expensive fabrication. Herein, inspired by traditional Chinese oil-paper umbrellas, we develop a self-cleaning and self-cooling oil-foam composite (OFC) made of recycled polystyrene foam and tung oil to simultaneously achieve efficient passive radiative cooling and enhanced thermal dissipation of objects. The OFCs show high solar reflectance (0.90) and high mid-infrared thermal emittance (0.89) during the atmospheric transparent window, contributing to a sub-ambient temperature drop of ∼5.4 °C and cooling power of 86 W m −2 under direct solar irradiance. Additionally, the worldwide market of recycled packaging plastics can provide low-cost raw materials, further eliminating the release of plastics into the environment. The OFC offers an energy-efficient, cost-effective and environmentally friendly candidate for building cooling applications and provides a value-added path for plastic recycling. 

Configured with a rapid evaporation rate and a high photothermal conversion efficiency, solar-driven interfacial evaporation displays considerable promise for seawater desalination. Inspired by the versatility and deployability of origami-based structures, we demonstrate a portable waterbomb origami pattern-based tower-like structure, named an “origami tower”, as a convertible photothermal evaporator floating on water for efficient solar-driven interfacial desalination. The origami tower has predictable deformability, featuring reversible radial expansion and contraction radially accompanied by small changes in the axial direction. The reversible adjustability of the origami tower offers convenience for transportation and storage, while the quick expansion into its tower shape provides rapid deployment capabilities. Benefiting from an enlarged evaporation surface, excellent light trapping ability, and heat localization, the origami-tower photothermal evaporator yields an evaporation rate of 2.67 kg m −2 h −1 under one sun illumination. This reversible 3D origami-based photothermal evaporator opens a new avenue for building a portable and efficient solar thermal desalination system. 

This study introduces a movable piston-like structure that provides a simple and cost-effective avenue for dynamically tuning thermal radiation. This structure leverages two materials with dissimilar optical responses—graphite and aluminum—to modulate from a state of high reflectance to a state of high absorptance. A cavity is created in the graphite to house an aluminum cylinder, which is displaced to actuate the device. In its raised state, the large aluminum surface area promotes a highly reflective response, while in its lowered state, the expanded graphite surface area and blackbody cavity-like interactions significantly enhance absorptance. By optimizing the area ratio, reflectance tunability of over 30% is achieved for nearly the entire ultraviolet, visible, and near-infrared wavelength regions. Furthermore, a theoretical analysis postulates wavelength-dependent effectivenesses as high as 0.70 for this method, indicating that tunabilities approaching 70% can be achieved by exploiting near-ideal absorbers and reflectors. The analog nature of this control method allows for an infinitely variable optical response between the upper and lower bounds of the device. These valuable characteristics would enable this material structure to serve practical applications, such as reducing cost and energy requirements for environmental temperature management operations. 

Water scarcity and waste mismanagement are global crises that threaten the health of populations worldwide and a sustainable future. In order to help mitigate both these issues, a solar desalination device composed entirely of fallen leaves and guar – both natural materials – has been developed and demonstrated herein. This sustainable desalinator realizes an evaporation rate of 2.53 kg m −2 h −1 under 1 sun irradiance, and achieves consistent performance over an extended exposure period. Furthermore, it functions efficiently under a variety of solar intensities and in high salinity environments, and can produce water at salinities well within the acceptable levels for human consumption. Such strong performance in a large variety of environmental conditions is made possible by its excellent solar absorption, superb and rapid water absorption, low thermal conductivity, and considerable salt rejection abilities. Composed primarily of biowaste material and boasting a simple fabrication process, this leaf-guar desalinator provides a low-cost and sustainable avenue for alleviating water scarcity and supporting a green path forward.