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Deuterium fractionation provides a window into the thermal history of volatiles in the solar system and protoplanetary disks. While evidence of active molecular deuteration has been observed toward a handful of disks, it remains unclear whether this chemistry affects the composition of forming planetesimals due to limited observational constraints on the radial and vertical distribution of deuterated molecules. To shed light on this question, we introduce new Atacama Large Millimeter/submillimeter Array observations of DCO⁺and DCNJ= 2–1 at an angular resolution of 0.″5 (30 au) and combine them with archival data of higher energy transitions toward the protoplanetary disk around TW Hya. We carry out a radial excitation analysis assuming both LTE and non-LTE to localize the physical conditions traced by DCO⁺and DCN emission in the disk, thus assessing deuterium fractionation efficiencies and pathways at different disk locations. We find similar disk-averaged column densities of 1.9 × 10¹²and 9.8 × 10¹¹cm⁻²for DCO⁺and DCN, with typical kinetic temperatures for both molecules of 20–30 K, indicating a common origin near the comet- and planet-forming midplane. The observed DCO⁺/DCN abundance ratio, combined with recent modeling results, provide tentative evidence of a gas-phase C/O enhancement within <40 au. Observations of DCO⁺and DCN in othermore »disks, as well as HCN and HCO⁺, will be necessary to place the trends exhibited by TW Hya in context, and fully constrain the main deuteration mechanisms in disks.

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Gas mass is a fundamental quantity of protoplanetary disks that directly relates to their ability to form planets. Because we are unable to observe the bulk H₂content of disks directly, we rely on indirect tracers to provide quantitative mass estimates. Current estimates for the gas masses of the observed disk population in the Lupus star-forming region are based on measurements of isotopologues of CO. However, without additional constraints, the degeneracy between H₂mass and the elemental composition of the gas leads to large uncertainties in such estimates. Here, we explore the gas compositions of seven disks from the Lupus sample representing a range of CO-to-dust ratios. With Band 6 and 7 ALMA observations, we measure line emission for HCO⁺, HCN, and N₂H⁺. We find a tentative correlation among the line fluxes for these three molecular species across the sample, but no correlation with¹³CO or submillimeter continuum fluxes. For the three disks where N₂H⁺is detected, we find that a combination of high disk gas masses and subinterstellar C/H and O/H are needed to reproduce the observed values. We find increases of ∼10–100× previous mass estimates are required to match the observed line fluxes. This work highlights how multimolecular studies are essentialmore »for constraining the physical and chemical properties of the gas in populations of protoplanetary disks, and that CO isotopologues alone are not sufficient for determining the mass of many observed disks.

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Abstract We report the discovery of a circumplanetary disk (CPD) candidate embedded in the circumstellar disk of the T Tauri star AS 209 at a radial distance of about 200 au (on-sky separation of 1.″4 from the star at a position angle of 161°), isolated via 13 CO J = 2−1 emission. This is the first instance of CPD detection via gaseous emission capable of tracing the overall CPD mass. The CPD is spatially unresolved with a 117 × 82 mas beam and manifests as a point source in 13 CO, indicating that its diameter is ≲14 au. The CPD is embedded within an annular gap in the circumstellar disk previously identified using 12 CO and near-infrared scattered-light observations and is associated with localized velocity perturbations in 12 CO. The coincidence of these features suggests that they have a common origin: an embedded giant planet. We use the 13 CO intensity to constrain the CPD gas temperature and mass. We find that the CPD temperature is ≳35 K, higher than the circumstellar disk temperature at the radial location of the CPD, 22 K, suggesting that heating sources localized to the CPD must be present. The CPD gas mass is ≳0.095more »M Jup ≃ 30 M ⊕ adopting a standard 13 CO abundance. From the nondetection of millimeter continuum emission at the location of the CPD (3 σ flux density ≲26.4 μ Jy), we infer that the CPD dust mass is ≲0.027 M ⊕ ≃ 2.2 lunar masses, indicating a low dust-to-gas mass ratio of ≲9 × 10 −4 . We discuss the formation mechanism of the CPD-hosting giant planet on a wide orbit in the framework of gravitational instability and pebble accretion.« less

Abstract UV photochemistry in the surface layers of protoplanetary disks dramatically alters their composition relative to previous stages of star formation. The abundance ratio CN/HCN has long been proposed to trace the UV field in various astrophysical objects; however, to date the relationship between CN, HCN, and the UV field in disks remains ambiguous. As part of the ALMA Large Program MAPS (Molecules with ALMA at Planet-forming Scales), we present observations of CN N = 1–0 transitions at 0.″3 resolution toward five disk systems. All disks show bright CN emission within ∼50–150 au, along with a diffuse emission shelf extending up to 600 au. In all sources we find that the CN/HCN column density ratio increases with disk radius from about unity to 100, likely tracing increased UV penetration that enhances selective HCN photodissociation in the outer disk. Additionally, multiple millimeter dust gaps and rings coincide with peaks and troughs, respectively, in the CN/HCN ratio, implying that some millimeter substructures are accompanied by changes to the UV penetration in more elevated disk layers. That the CN/HCN ratio is generally high (>1) points to a robust photochemistry shaping disk chemical compositions and also means that CN is the dominant carrier ofmore »the prebiotically interesting nitrile group at most disk radii. We also find that the local column densities of CN and HCN are positively correlated despite emitting from vertically stratified disk regions, indicating that different disk layers are chemically linked. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.« less