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Azidoalkyation is an efficient strategy for the conversion of unsaturated precursors into nitrogen-containing structural motifs. Herein, we describe a convenient and highly regioselective iron-catalyzed 1,2-azidoalkylation of 1,3-dienes that employs TMSN3... 

We study the problem of fair k-median where each cluster is required to have a fair representation of individuals from different groups. In the fair representation k-median problem, we are given a set of points X in a metric space. Each point x ∈ X belongs to one of ℓ groups. Further, we are given fair representation parameters αj and β_j for each group j ∈ [ℓ]. We say that a k-clustering C_1, ⋅⋅⋅, C_k fairly represents all groups if the number of points from group j in cluster C_i is between α_j |C_i| and β_j |C_i| for every j ∈ [ℓ] and i ∈ [k]. The goal is to find a set of k centers and an assignment such that the clustering defined by fairly represents all groups and minimizes the ℓ_1-objective ∑_{x ∈ X} d(x, ϕ(x)). We present an O(log k)-approximation algorithm that runs in time n^{O(ℓ)}. Note that the known algorithms for the problem either (i) violate the fairness constraints by an additive term or (ii) run in time that is exponential in both k and ℓ. We also consider an important special case of the problem where and for all j ∈ [ℓ]. For this special case, we present an O(log k)-approximation algorithm that runs in time.