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In this study, we examine the performance of a multi-scale model for large-eddy simulation (LES) of tur- bulent combustion. The model referred to as RRLES performs the closure of the filtered reaction-rate term in the species transport equation while performing LES by using the linear eddy mixing (LEM) model. The RRLES model uses a multi-scale strategy to obtain the filtered reaction rate of the species and has been shown to address some of the challenges associated with the well-established LEMLES approach. The orig- inally proposed RRLES strategy used a multilevel adaptive mesh refinement (AMR) framework, which was extended to use a single grid-based strategy to enable the application to complex geometries. Additionally, a local dual-resolution grid strategy has also been developed and can potentially be used with different grid topologies, without the need for the AMR. We assess the accuracy and efficiency of the single and dual-grid RRLES approaches by considering a freely propagating turbulent premixed flame under two different initial conditions corresponding to the thin reaction zone (TRZ) and the broken/distributed reaction zone (B/DRZ) regimes. 

Building insulation materials can affect indoor air by (i) releasing primary volatile organic compounds (VOCs) from building enclosure cavities to the interior space, (ii) mitigating exposure to outdoor pollutants through reactive deposition (of oxidants, e.g. , ozone) or filtration (of particles) in infiltration air, and (iii) generating secondary VOCs and other gas-phase byproducts resulting from oxidant reactions. This study reports primary VOC emission fluxes, ozone (O 3 ) reaction probabilities ( γ ), and O 3 reaction byproduct yields for eight common, commercially available insulation materials. Fluxes of primary VOCs from the materials, measured in a continuous flow reactor using proton transfer reaction-time of flight-mass spectrometry, ranged from 3 (polystyrene with thermal backing) to 61 (cellulose) μmol m −2 h −1 (with total VOC mass emission rates estimated to be between ∼0.3 and ∼3.3 mg m −2 h −1 ). Major primary VOC fluxes from cellulose were tentatively identified as compounds likely associated with cellulose chemical and thermal decomposition products. Ozone-material γ ranged from ∼1 × 10 −6 to ∼30 × 10 −6 . Polystyrene with thermal backing and polyisocyanurate had the lowest γ , while cellulose and fiberglass had the highest. In the presence of O 3 , total observed volatile byproduct yields ranged from 0.25 (polystyrene) to 0.85 (recycled denim) moles of VOCs produced per mole of O 3 consumed, or equivalent to secondary fluxes that range from 0.71 (polystyrene) to 10 (recycled denim) μmol m −2 h −1 . Major emitted products in the presence of O 3 were generally different from primary emissions and were characterized by yields of aldehydes and acetone. This work provides new data that can be used to evaluate and eventually model the impact of “hidden” materials ( i.e. , those present inside wall cavities) on indoor air quality. The data may also guide building enclosure material selection, especially for buildings in areas of high outdoor O 3 .